Statistical Optimization for Succinic Acid Production from E. Coli in a Cost-Effective Medium

Response surface methodology (RSM) was employed for optimization of medium components and cultural parameters in cost effective cane molasses based medium for attaining high yield of succinic acid. The important factors obtained by “one-variable-at-a-time-approach” (cane molasses, corn steep liquor, sodium carbonate, and inoculum density) were further optimized by RSM. The optimum values of the parameters obtained through RSM (cane molasses 12.5%, corn steep liquor 7.5%, and sodium carbonate 25 mM) led to almost double yield of succinic acid (15.2 g/l in 36 h) as against “one-variable-at-a-time-approach” (7.1 g/l in 36 h) in 500-ml anaerobic bottles containing 300-ml cane molasses based medium. Subsequently, in 10-l bioreactor succinic acid production from Escherichia coli was further improved to 26.2 g/l in 30 h under conditions optimized through RSM. This fermentation-derived succinic acid will definitely help in replacing existing environmentally hazardous and cost-intensive chemical methods for the production of succinic acid.     

Time resolved spectroscopy in laser grade organic dyes

Time resolved spectroscopy is discussed along with the theoretical and experimental methods used to measure the fluorescence lifetimes in various laser grade organic dyes. The role of solvents and their viscosities in the fluorescence life time is also discussed. Different photophysical parameters have been obtained in rigid and non-rigid dye molecules.     

On the concept of solution for fractional differential equations with uncertainty

We consider a differential equation of fractional order with uncertainty and present the concept of solution. It extends, for example, the cases of first order ordinary differential equations and of differential equations with uncertainty. Some examples are presented.     

Positive and maximal positive solutions of singular mixed boundary value problem

The paper is concerned with existence results for positive solutions and maximal positive solutions of singular mixed boundary value problems. Nonlinearities h(t;x;y) in differential equations admit a time singularity at t=0 and/or at t=T and a strong singularity at x=0.     

Synthesis,crystal structure and optical properties of quasi-one-dimensional lead (II) iodide: C14H18N2Pb2I6

Quasi-one-dimensional lead (II) iodide compound, C₁₄H₁₈N₂Pb₂I₆, with unique crystal structure was synthesized and solved for the crystal structure. These novel inorganic-organic hybrids have high thermal stability of upto 300 °C and show excitonic and charge-transfer features in their optical properties. An attempt has been made to understand the structural and optical mechanisms between inorganic one-dimensional polymeric PbI nano ribbons and the guest organic moiety for future applications in nanoscaled electronic devices.     

Quiesent Crystallization Kinetics of Nucleated Metallocene and ZN Isotactic Polypropylenes

Crystallization kinetics and thermodynamic properties of nucleated isotactic polypropylene (PP) are analyzed using Hoffman—Lauritzen crystallization theory to determine the mechanistic effects of the nucleators. Calorimetric data provides quantitative comparisons between nucleating efficiences of the (Millad) and (NJSTAR) nucleator in Metallocene (M) and Ziegler—Natta (ZN) PP. The two types of PP without nucleators showed similar crystallization behavior though the T°_m for ZN-iPP was about 10°C higher than M-iPP. Both nucleators show significant improvement in crystallization rate in both types of PP. In addition, Millad outperforms NJSTAR. The magnitude of the kinetic response is,however, different and both the nucleators appear to function better in ZN than in Metallocene PP. nucleated PP shows predominantly the form. The amount of the form is thermal history dependent and changes with supercooling (T=T°_m–T_c). Similar equilibrium melting temperature (T°_m) in the nucleated and control PPs indicates the lack of any thermodynamic effect of the nucleator. All nucleated PPs show a much lower secondary nucleation rate constant, K_g.This revised version was published online in November 2005 with corrections to the Cover Date.     

The Existence of Positive Solutions to Neutral Differential Equations

In this paper, we shall consider a class of neutral differential equations of the form

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where τ (0, ∞), σ [0, ∞), Q(t) C([t₀, ∞), R ⁺ ), r(t) C([t₀, ∞), (0, ∞)) with r(t) nondecreasing on [t₀ − τ, ∞). We shall show that all positive solutions of ( * ) can be classified into four types, A, B, C, and D, and we shall obtain sufficient and necessary conditions for the existence of A-type, B-type, and D-type positive solutions of ( * ), respectively. A sufficient condition for the existence of C-type positive solutions of ( * ) is also given. Finally, we shall offer a sharp oscillation result for all solutions of ( * ). Our results generalize and improve those established in B. Yang and B. G. Zhang (Funkcial. Ekvac.39 (1996), 347–362).     

Electrical conduction mechanism in a polycrystalline Sb35Se65 sample

Localized state conduction through a variable-range hopping mechanism in the low-temperature region (～180–270 K) and thermally activated phonon-assisted tunneling in the higher-temperature region (～270–320 K) has been observed in a polycrystalline Sb₃₅Se₆₅ sample.