We demonstrate strongly nondegenerate optical continuous-wave parametric oscillations in crystalline whispering gallery mode resonators fabricated from LiNbO3. The required phase matching is achieved by geometrical confinement of the modes in the resonator. 相似文献
We demonstrate efficient Raman lasing with CaF2 whispering-gallery-mode resonators. Continuous-wave emission threshold is shown to be possible below 1 microW with a 5mm cavity, which is to our knowledge orders of magnitude lower than in any other Raman source. Low-threshold lasing is made possible by the ultrahigh optical quality factor of the cavity, of the order of Q=5x10(10). Stokes components of up to the fifth order were observed at a pump power of 160 microW, and up to the eighth order at 1 mW. A lasing threshold of 15 microW was also observed in a 100 microm CaF2 microcavity. Potential applications are discussed. 相似文献
Advection equations with delay are appeared in the modeling of the dynamics of structured cell populations. In this article, we construct an efficient two-dimensional multistep collocation method for the numerical solution of a class of advection equations with delay. Equations with aftereffect and equations with both aftereffect and retardation of a state variable are considered. Computability of the algorithm and convergence properties of the proposed numerical method are analyzed for solutions in appropriate Sobolev spaces, and it is shown that the proposed scheme enjoys the spectral accuracy. Numerical examples are given and comparison with other existing methods in the literature is made to demonstrate the efficiency, superiority and high accuracy of the presented method. 相似文献
Heat transfer coefficients were measured and new correlations were developed for two-phase, two-component (air and water) heat transfer in a horizontal pipe for different flow patterns. Flow patterns were observed in a transparent circular pipe using an air–water mixture. Visual identification of the flow patterns was supplemented with photographic data, and the results were plotted on the flow regime map proposed by Taitel and Dukler and agreed quite well with each other. A two-phase heat transfer experimental setup was built for this study and a total of 150 two-phase heat transfer data with different flow patterns were obtained under a uniform wall heat flux boundary condition. For these data, the superficial Reynolds number ranged from 640 to 35,500 for the liquid and from 540 to 21,200 for the gas. Our previously developed robust two-phase heat transfer correlation for a vertical pipe with modified constants predicted the horizontal pipe air–water heat transfer experimental data with very good accuracy. Overall the proposed correlations predicted the data with a mean deviation of 1.0% and an rms deviation of 12%. 相似文献
A necessary condition for generation of bright soliton Kerr frequency combs in microresonators is to achieve anomalous group velocity dispersion (GVD) for the resonator modes. This condition is hard to implement in the visible as well as ultraviolet since the majority of optical materials are characterized with large normal GVD in these wavelength regions. We overcome this challenge by borrowing ideas from strongly dispersive coupled systems in solid state physics and optics. We show that photonic compound ring resonators can possess large anomalous GVD at any desirable wavelength, even if each individual resonator is characterized with normal GVD. Based on this concept, we design a mode‐locked frequency comb with thin‐film silicon nitride compound ring resonators in the vicinity of the rubidium D1 line (794.6 nm) and propose to use this optical comb as a flywheel for chip‐scale optical clocks.
Nickel zirconium phosphate nanoparticles were found to function as efficient catalysts for the selec-tive oxidation of a wide range of alcohols to their corresponding ketones and aldehydes using H2O2 as an oxidizing agent and without any organic solvents, phase transfer catalysts, or additives. The steric and electronic properties of various substrates had significant influence on the reaction con-ditions required to achieve acetylation. The results showed that this method can be applied for the chemoselective oxidation of benzyl alcohols in the presence of aliphatic alcohols. The catalyst used in the current study was characterized by ICP-OES, XRD, NH3-TPD, Py-FTIR, N2 adsorp-tion-desorption, SEM and TEM. These analyses revealed that the interlayer distance in the catalyst increased from 0.75 to 0.98 nm when Ni2+ was intercalated between the layers, whereas the crystal-linity of the material was reduced. The nanocatalyst could also be recovered and reused at least seven times without any discernible decrease in its catalytic activity. This new method for the oxi-dation of alcohols has several key advantages, including mild and environmentally friendly reaction conditions, short reaction time, excellent yields and a facile work-up. 相似文献
Magnetic solid-phase extraction based on Fe3O4/graphene oxide nanocomposites was investigated for the separation, preconcentration and determination of imatinib and doxorubicin in aqueous solutions. Synthesis of Fe3O4/graphene oxide was characterized by transmission electron microscopy, energy-dispersive X-ray analyzer and vibrating sample magnetometer. After optimizing the conditions, optimal experimental conditions including sample pH, the amount of the magnetic nanoparticles, the effect of salt concentration and other chemotherapy medications, eluent type and extraction time were studied and established. The method showed good linearity for the determination of doxorubicin and imatinib in the concentration range of 0.01–100 μg mL?1 in aqueous solutions with limit of detection 1.8 ng mL?1 for doxorubicin and 1.9 ng mL?1 for imatinib. The relative recoveries of doxorubicin and imatinib levels were 96.7 and 88.4%, respectively. The results indicate that the present procedure is a suitable method for extraction of imatinib and doxorubicin from environmental water samples. 相似文献
A simple and highly efficient method for synthesis of benzoxazoles, benzimidazoles, and oxazolo[4,5-b]pyridines is described. Condensation of orthoesters with o-substituted anilines or 2-amino-3-hydroxypyridine was performed in the presence of catalytic amounts of commercially available,
inexpensive, and moisture-stable 1,3-dibromo-5,5-dimethylhydantoin under solvent-free conditions. The corresponding heterocycles
were obtained in good to excellent yields. The main advantages of the present procedure are mild reaction conditions, short
reaction times, high yields of products, easy work-up, and absence of solvent. 相似文献
JPC – Journal of Planar Chromatography – Modern TLC - A novel liquid-phase microextraction method coupled with high-performance thin-layer chromatography (HPTLC) for preconcentration,... 相似文献