Effects of Adsorbed Polyaniline on Redox Processes on As(2)O(3) Surfaces

Polyaniline deposited on As(2)O(3) surface resulted in a new material, which was characterized by infrared spectoscopy, thermogravimetry, differential scanning calorimetry, scanning electron microscopy, X-ray diffraction, and cyclic voltammetry. The mass percentage of polymer deposited on oxide surface is approximately 13%. The scanning electron microscopy images as well as the X-ray diffraction patterns provided conclusive evidence that the oxide surface is coated by the polymer. The cyclic voltammograms of the polyaniline adsorbed on As(2)O(3) surface showed that the adsorbate exerts remarkable effects on redox processes on this oxide. The pure oxide exhibited two oxidation/reduction peaks at 0.25/-0.06 and 0.47/-0.25 V attributed tentatively to the processes As(2)O(3)(s)+6H(+)+6e(-)=2As(s)+3H(2)O and As(s)+3H(+)+3e(-)=AsH(3)(g), respectively. The polyaniline-coated sample exhibited a better-defined voltammogram in which the first oxidation peak of the oxide had its intensity increased about four times. Copyright 2000 Academic Press.     

Quantum structures due to fluctuations of the measurement situation

We analyze the meaning of the nonclassical aspects of quantum structures. We proceed by introducing a simple mechanistic macroscopic experimental situation that gives rise to quantum-like structures. We use this situation as a guiding example for our attempts to explain the origin of the nonclassical aspects of quantum structures. We see that the quantum probabilities can be introduced as a consequence of the presence of fluctuations on the experimental apparatuses, and show that the full quantum structure can be obtained in this way. We define the classical limit as the physical situation that arises when the fluctuations on the experiment apparatuses disappear. In the limit case we come to a classical structure, but in between we find structures that are neither quantum nor classical. In this sense, our approach not only gives an explanation for the nonclassical structure of quantum theory, but also makes it possible to define and study the structure describing the intermediate new situations. By investigating how the nonlocal quantum behavior disappears during the limiting process, we can explain theapparentlocality of the classical macroscopic world. We come to the conclusion that quantum structures are the ordinary structures of reality, and that our difficulties of becoming aware of this fact are due to prescientific prejudices, some of which we point out.     

Preparation,evaluation, and comparison of wide bore (320 μm) and narrow bore (50 μm) cyanosilicone-coated capillary columns for gas chromatography

The preparation of wide bore (320 μm) and narrow bore (50 μm) fused silica capillary columns is described for immobilized cyanopropyl substituted silicones containing 60 and 88% substitution. The effect of high temperature deactivation with cyanopropylcyclosiloxanes was studied with a special test mixture. Curing was achieved with dicumyl peroxide or azo-tert-butane. The columns were evaluated and compared in terms of efficiency, activity, polarity, and temperature stability. Different coating methods were compared for the narrow bore columns. The activity of the 60% cyanopropyl columns that had been immobilized with dicumyl peroxide was significantly larger than for azo-tert-butane immobilized columns. The polarity of polar columns appeared to depend greatly on column temperature and is completely different for wide and narrow bore columns.     

Ion-molecule reactions of 2-methoxyethanol with some amines, carboxylic acids and amino acids under chemical ionization conditions

2-Methoxyethanol chemical ionization of amines, carboxylic acids and amino acids has been found to produce numerous adduct ions. The most intense adduct ions for amines are [M + H](+) and [M + 77](+), for carboxylic acids [M + 27](+), [M + 59](+) and [M + 77](+), and for amino acids [M + H](+), [M + 13](+), [M + 27](+) and [M + 77](+). Either the adduct ion [M + H](+) or [M + 77](+) was the most abundant ion found for amino acids. The proton affinities of amino acids are noticed to control the formation of the [M + H](+) and [M + 77](+) ions. The relative abundance of [M + 13](+) and [M + 27](+) ions varied for different amino acids being most intense for phenylalanine and aspartic acid. Copyright 1999 John Wiley & Sons, Ltd.     

Status of electroweak phase transition and baryogenesis

I review recent progress on the electroweak phase transition and baryogenesis, focusing on the minimal supersymmetric Standard Model as the source of new physics.     

The Extended Bloch Representation of Entanglement and Measurement in Quantum Mechanics

The quantum formalism can be completed by assuming that density operators also represent genuine states. An ‘extended Bloch representation’ (EBR) then results, in which not only the states but also the measurement-interactions can be described. Consequently, the Born rule can be obtained as an expression that quantifies the lack of knowledge about the measurement-interaction that is each time actualized, during a measurement. Entanglement can also be consistently described in the EBR, as it remains compatible with the principle according to which a composite entity exists only if its components also exist, and therefore are in well-defined states.