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971.
We deal with nonlinear T-periodic differential systems depending on a small parameter. The unperturbed system has an invariant manifold of periodic solutions. We provide the expressions of the bifurcation functions up to second order in the small parameter in order that their simple zeros are initial values of the periodic solutions that persist after the perturbation. In the end two applications are done. The key tool for proving the main result is the Lyapunov-Schmidt reduction method applied to the T-Poincaré-Andronov mapping. 相似文献
972.
Adriana Mejía Castaño Susan Montgomery Sonia Natale Maria D. Vega Chelsea Walton 《Journal of Pure and Applied Algebra》2018,222(7):1643-1669
Let p and q be distinct prime numbers. We study the Galois objects and cocycle deformations of the noncommutative, noncocommutative, semisimple Hopf algebras of odd dimension and of dimension . We obtain that the non-isomorphic self-dual semisimple Hopf algebras of dimension classified by Masuoka have no non-trivial cocycle deformations, extending his previous results for the 8-dimensional Kac–Paljutkin Hopf algebra. This is done as a consequence of the classification of categorical Morita equivalence classes among semisimple Hopf algebras of odd dimension , established by the third-named author in an appendix. 相似文献
973.
Ionization potentials of small molecules are calculated by the MS Xα and LCAO Xα methods. The results are compared with the experimental values and the results of previous accurate calculations. The Xα method proves to be rather accurate and potentially superior to the HF method. Indication is found of a possible failure of the method in the fluoromethanes. The limitation of the MS Xα method is discussed. 相似文献
974.
Di Venosa G Fukuda H Perotti C Batlle A Casas A 《Journal of photochemistry and photobiology. B, Biology》2004,75(3):157-163
Photodynamic therapy using 5-aminolevulinic acid (ALA)-induced protoporphyrin IX is a recent approach to detect and treat some malignancies. The use of lipophilic derivatives of ALA has been exploited in the last years to enhance ALA penetration. In this paper, we describe the application of the Mauzerall and Granick's method [J. Biol. Chem. 219 (1956) 435] to the quantification of ALA derivatives. We also describe the employment of reusable ion-exchange chromatographic columns for separating mixtures of ALA and ALA derivatives present in biological samples. The relation between 555 nm absorbance and ALA or ALA derivative concentration was linear up to 100 nmol/ml and the limit of detection of ALA and ALA derivatives was 1 nmol per ml. We employed a Dowex 50 X8 hydrogen form resin to separate ALA from the derivatives. Whereas 90+/-4% of the total ALA was eluted using sodium acetate, only 3-9% of the ALA derivatives was recovered. Only upon exposure of the resin to a high HCl concentration, the ALA derivatives were completely released. We employed this new method for the separation of ALA from ALA derivatives in cells exposed to different ALA compounds. 相似文献
975.
Adriana B. Pierini Mario G. Cardozo Aida A. Montiel Sem M. Albonico Maria T. Pizzorno 《Journal of heterocyclic chemistry》1989,26(4):1003-1008
We report a 1,3-dipolar cycloaddition reaction between a oxazolium 5-oxide derivative with chloroacrylonitrile or ethyl propiolate as dipolarophiles, in order to obtain substituted pyrrolizidines. Experimentally we found that the reaction is regiospecific with chloroacrylonitrile and regioselective with ethyl propiolate. The secondary attractive orbital interactions from the Frontier Molecular Orbital Theory, the differences in stability of the possible biradical intermediaries postulated for the reaction and some hindrance effects, explain the regioselectivity observed experimentally. 相似文献
976.
A degradation study of two phenoxy acid [(2,4-dichlorophenoxy) propanoic acid and (2,4,5-trichlorophenoxy) acetic acid] and two phenylurea (diuron and monolinuron) herbicides, spiked at 50 ppb in water, was performed. Some samples were subjected to neutral and basic hydrolysis; other samples were subjected to photolysis using either sunlight or a xenon arc lamp. After degradation, the water samples were preconcentrated using solid-phase extraction (SPE) with Carbopack B columns and analysed by a micellar electrokinetic capillary chromatography (MECC) system with UV detection at 210 nm. Phenoxyacetic acids were not degraded neither by hydrolysis nor by sunlight photolysis, but they were photodegraded when they were exposed to a xenon arc lamp, with half-lives around 300 min. Phenylurea herbicides were hydrolysed at the two-tested pH, with half-lives varying from 25 to 290 days. The main hydrolysis products were the corresponding chloroanilines. Diuron and monolinuron were also degraded when they were exposed to sunlight and xenon arc lamp. The main photodegradation pathway for diuron corresponded to dehalogenation, while for monolinuron dealkylation and hydroxylation were also postulated. The toxicity of the studied herbicides and their degradation products was evaluated by means of Microtox tests. The obtained results indicated that the toxicity of the degraded samples was higher than the toxicity of the herbicides. 相似文献
977.
Miraglia N Basile A Pieri M Acampora A Malorni L De Giulio B Sannolo N 《Rapid communications in mass spectrometry : RCM》2002,16(9):840-847
Ion trap mass spectrometry has been shown to be particularly suitable for the structural analysis of high molecular weight peptides directly fragmented in the mass analyser without needing further sub-digestion reactions. Here we report the advantages of using multi-stage ion trap mass spectrometry in the structural characterisation of haemoglobin alkylated with epichlorohydrin and diepoxybutane. Alkylated globins were digested with trypsin and the peptide mixtures were analysed by MS(3). This technique allows the sequential fragmentation of peptides under analysis, giving rise to MS(3) product ion spectra with additional information with respect to MS(2) mass spectra. The results obtained complete the previously reported structural characterisation of alkylated haemoglobin, demonstrating the potential of ion trap mass spectrometry. 相似文献
978.
Adriana C. Ferreira Maria das G. A. Korn Sérgio L. C. Ferreira 《Mikrochimica acta》2004,146(3-4):271-278
In the present paper, a preconcentration procedure for manganese determination in seawater samples by flame atomic absorption spectrometry (FAAS) is proposed. It is based on the solid phase extraction of manganese(II) ions as a 4-(2-pyridylazo-resorcinol) (PAR) chelate using activated carbon as sorbent. Optimization of the experimental parameters (pH, activated carbon mass, PAR mass and shaking time) was carried out using a two-level full factorial design (24) and two Doehlert matrix designs. The results of the factorial design, considering the analysis of variance (ANOVA), demonstrate that all these factors and their interactions (pH × PAR mass; pH × activated carbon mass and activated carbon mass × shaking time) are statistically significant. Final optimization was carried out using Doehlert matrix designs considering the results of the factorial design. The validation process evaluated the following parameters: effect of other metal ions, calibration curve, precision, accuracy and robustness. The procedure allows manganese determination in seawater samples with limits of detection (3/S) and quantification (10/S) of 16ngL–1 and 53ngL–1 respectively, and a preconcentration factor of 152. The analysis of certified reference materials demonstrated that the proposed procedure can also be used for manganese determination in biological samples. The procedure is not affected by matrix interferences and could be satisfactorily applied in manganese determination in seawater samples. Manganese determination in surface seawater samples collected from the shore of Salvador city, Brazil, was performed, and concentrations ranging from 0.51 to 2.59µgL–1 were found. 相似文献
979.
Phenyl telluride anion was prepared in liquid ammonia by reaction of dipheyyl ditelluride with two equivalents of sodium metal under nitrogen. This anion reacts with haloarenes under irradiation to form aryl phenyl tellurides, probably by the photo-SRN1 mechanism of aromatic substitution. 相似文献
980.
Karl Eberhard Bessler Adriana Torres de Sousa Victor Marcelo Deflon Elke Niquet 《无机化学与普通化学杂志》2003,629(6):1091-1095
The silver cyanoguanidine complexes [Ag(cgn)2]F ( 1 ), [Ag(cgn)2][BF4] ( 2 ), [Ag(cgn)2][ClO4] ( 3 ) and [Ag(cgn)][NO3] ( 4 ) were obtained from aqueous solutions of the corresponding silver salts and cyanoguanidine. The crystal structures of 1 and 2 have been determined by single crystal X‐ray diffraction. 1 : Space group P1¯, Z = 2, cell constants at —65 °C: a =618.18(3), b = 761.49(8), c = 971.2(1) pm; α = 93.56(1), β = 97.439(8), γ = 97.376(9)β; R1 = 0.0218 2 : Space group P1¯, Z = 2, cell constants at —65 °C: a = 549.79(9), b = 958.17(17), c = 1121.04(12) pm; α = 90.026(13), β = 102.520(11), γ = 95.937(14)°; R1 = 0.0283. 相似文献