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91.
High‐density polyethylene/expanded graphite nanocomposites produced by polymerization‐filling technique using an industrial heterogeneous catalyst 下载免费PDF全文
Kátia Z. C da Cruz Adriana C. A. Casagrande Osvaldo L. Casagrande Jr 《Journal of polymer science. Part A, Polymer chemistry》2017,55(7):1260-1267
High‐density polyethylene nanocomposites with different expanded graphite (EG) contents (0.34–1.80 wt %) were prepared by polymerization‐filling technique using an industrial heterogeneous catalyst ( cat K ), and characterized using a range techniques: melting flow index (MFI), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and transmission electron microscopy (TEM). The MFI data showed that EG acts as a plasticizer decreasing melt viscosity in comparison to neat HDPE produced exclusively by cat K . DSC results showed that EG nucleated the HDPE crystallization as established by the increased crystallization temperature, and the degree of crystallinity. HDPE/EG nanocomposites displayed a significant improvement in the flexural (increased from 1458 to 1831 MPa), and storage modulus (increased from 122 to 1627 MPa) at only 1.80 wt % EG content. TEM images confirmed a homogeneous distribution of EG into the polymer matrix with the presence of dispersed, intercalated and aggregated EG nanofillers. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 55, 1260–1267 相似文献
92.
Adriana Lídia Santana Cristiano Giacomelli Paula Nunes Oliveira Alfredo Tibúrcio Nunes Pires José Roberto Bertolino Almir Spinelli 《Journal of Polymer Science.Polymer Physics》2009,47(2):215-225
The effect of poly(2‐vinyl pyridine) (P2VP) and poly(4‐vinyl pyridine) (P4VP) isomers on the growth of surface films on copper substrates was studied by electrochemical, spectroscopic, thermogravimentric, and microscopic methods. In acid environment (3% v/v acetic acid) and in the presence of KSCN, electrochemically generated copper cations reacted rapidly with SCN? and P2VP or P4VP, yielding coordination compounds, which deposited onto copper surfaces as films. The characteristics of such polymer–metal complexes (films) were markedly isomer‐dependent. Cu(I)/P2VP/SCN? complexes with monovalent cations and sulfur‐coordinated thiocyanate were obtained in the presence of P2VP, whereas the formation of Cu(II)/P4VP/SCN? complexes with divalent cations and nitrogen‐coordinated thiocyanate was observed in the presence of P4VP. Interestingly, similar physical–chemical properties (electronic structure, stoichiometry, and thermal behavior) were observed for materials synthesized by electrochemical and chemical methods. These results suggest, therefore, that control over the surface properties of copper substrates can be achieved using electrosynthesized films based on different PVP isomers. Besides acting as effective protective barriers against aggressive media and thus reducing the metal dissolution (corrosion) kinetics, these materials are potentially attractive for other applications in which surface properties are paramount, such as in catalysis. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 215–225, 2009 相似文献
93.
Adriana Boschetti‐de‐Fierro Daniel Fierro Julio Albuerne Sérgio S. Funari Volker Abetz 《Journal of Polymer Science.Polymer Physics》2007,45(23):3197-3206
The bulk morphology of poly(1,4‐butadiene)–block–polystyrene–block–poly (ethylene oxide) (PB‐b‐PS‐b‐PEO) and polyethylene–block–polystyrene–block–poly (ethylene oxide) (PE‐b‐PS‐b‐PEO) triblock terpolymers is analyzed under a thermal protocol. This allows the investigation of the morphology during the occurrence of thermal transitions, such as crystallization and melting, which is a neat way of studying the competition between microphase separation and crystallization for the morphology formation. Only one of the studied systems presented a morphological transition upon melting of the PEO and the PE blocks, attributed to the crystallization of the PE block in finite interconnected domains. All the other systems presented no morphological transitions during the thermal scan. The results prove that the crystallization only disrupt the microphases generated in the molten state under very specific circumstances for these block copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3197–3206, 2007 相似文献
94.
A simple and efficient synthesis of polystyrene-supported proline and prolinamide has been carried out. Polystyrene-supported proline has been used as organocatalyst in the asymmetric aldol reaction between cyclohexanone and substituted benzaldehydes in water without any additive. High yields, diastereoselectivities and ee values have been observed. The versatility of this resin was demonstrated in the α-selenenylation of aldehydes. Both proline and prolinamide resins gave high yields. Recycling studies showed that the proline resin gave better results than prolinamide resin. 相似文献
95.
Patrizia Cafarelli Adriana De Stefanis Giorgio Perez Anthony A.G. Tomlinson 《Reaction Kinetics and Catalysis Letters》2005,86(1):163-169
Summary Pillared clays have been monitored for catalytic destruction of halocarbons. In comparison with HZSM-5 zeolites, the catalysts tested give higher chlorohydrocarbons destruction with polymers formation. Fluorochlorohydro-carbons are destroyed as well. 相似文献
96.
97.
Alessandra Russo Venera Cardile Adriana C.E. Graziano Carmen Formisano Marisa Canzoneri 《Natural product research》2015,29(17):1630-1640
The objectives of our research were to study the chemical composition and the in vitro anticancer effect of the essential oil of Salvia verbenaca growing in natural sites in comparison with those of cultivated (Sc) plants. The oil from wild (Sw) S. verbenaca presented hexadecanoic acid (23.1%) as the main constituent, while the oil from Sc plants contained high quantities of hexahydrofarnesyl acetone (9.7%), scarce in the natural oil (0.7%). The growth-inhibitory and proapoptotic effects of the essential oils from Sw and Sc S. verbenaca were evaluated in the human melanoma cell line M14, testing cell vitality, cell membrane integrity, genomic DNA fragmentation and caspase-3 activity. Both the essential oils were able to inhibit the growth of the cancer cells examined inducing also apoptotic cell death, but the essential oil from cultivated samples exhibited the major effects. 相似文献
98.
Combination of hollow‐fiber‐supported liquid membrane and dispersive liquid–liquid microextraction as a fast and sensitive technique for the extraction of pesticides from grape juice followed by high‐performance liquid chromatography 下载免费PDF全文
Vanessa Dutra Silva Vanessa Simão Adriana Neves Dias Jeferson Schneider Carletto Eduardo Carasek 《Journal of separation science》2015,38(11):1959-1968
The simultaneous use of a hollow‐fiber‐supported liquid membrane and dispersive liquid–liquid microextraction for the determination of pesticides directly in grape juice was investigated. The detection and quantification were performed by liquid chromatography with diode array detection. The optimum extraction condition was reached by filling the pores of the membrane wall with dodecanol and using hexane/acetone as extraction/dispersion solvents. Salt addition had a highly negative effect on the extraction efficiency and the optimum extraction time was 60 min. The volume of hexane/acetone mixture and the sample pH did not affect the signal at the levels studied. Therefore, an intermediate amount of these solvents (250 μL; 1:7.5 v/v) and pH 6 were selected. The optimum desorption condition was obtained with acetonitrile and 10 min of desorption time. The linear working range varied from 58 to 500 μg/L (parathion‐methyl), 62–500 μg/L (difenoconazole) and 107–500 μg/L (chlorpyrifos), with correlation coefficients ranging from 0.9980–0.9942. The limits of detection and quantification found were, respectively, 17 and 58 μg/L for parathion‐methyl, 19 and 62 μg/L for difenoconazole and 32 and 107 μg/L for chlorpyrifos. The relative standard deviation ranged between 3.5 and 11.2%. 相似文献
99.
Jos J. Campos‐Gaxiola Susana P. Arredondo Rea Ramn Corral Higuera Herbert Hpfl Adriana Cruz Enríquez 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(1):48-52
Two organic–inorganic hybrid compounds have been prepared by the combination of the 4‐[(E)‐2‐(pyridin‐1‐ium‐2‐yl)ethenyl]pyridinium cation with perhalometallate anions to give 4‐[(E)‐2‐(pyridin‐1‐ium‐2‐yl)ethenyl]pyridinium tetrachloridocobaltate(II), (C12H12N2)[CoCl4], (I), and 4‐[(E)‐2‐(pyridin‐1‐ium‐2‐yl)ethenyl]pyridinium tetrachloridozincate(II), (C12H12N2)[ZnCl4], (II). The compounds have been structurally characterized by single‐crystal X‐ray diffraction analysis, showing the formation of a three‐dimensional network through X—H...ClnM− (X = C, N+; n = 1, 2; M = CoII, ZnII) hydrogen‐bonding interactions and π–π stacking interactions. The title compounds were also characterized by FT–IR spectroscopy and thermogravimetric analysis (TGA). 相似文献
100.
Formulation of Aluminum Chloride Phthalocyanine in Pluronic™ P‐123 and F‐127 Block Copolymer Micelles: Photophysical properties and Photodynamic Inactivation of Microorganisms 下载免费PDF全文
Bruno Henrique Vilsinski Adriana Passarella Gerola Junior Adalberto Enumo Katieli da Silva Souza Campanholi Paulo Cesar de Souza Pereira Gustavo Braga Noboru Hioka Elza Kimura André Luiz Tessaro Wilker Caetano 《Photochemistry and photobiology》2015,91(3):518-525
Aluminum Chloride Phthalocyanine (AlPcCl) can be used as a photosensitizer (PS) for Photodynamic Inactivation of Microorganisms (PDI). The AlPcCl showed favorable characteristics for PDI due to high quantum yield of singlet oxygen (ΦΔ) and photostability. Physicochemical properties and photodynamic inactivation of AlPcCl incorporated in polymeric micelles of tri‐block copolymer (P‐123 and F‐127) against microorganisms Staphylococcus aureus, Escherichia coli and Candida albicans were investigated in this work. Previously, it was observed that the AlPcCl undergoes self‐aggregation in F‐127, while in P‐123 the PS is in a monomeric form suitable for PDI. Due to the self‐aggregation of AlPcCl in F‐127, this formulation did not show any effect on these microorganisms. On the other hand, AlPcCl formulated in P‐123 was effective against S. aureus and C. albicans and the death of microorganisms was dependent on the PS concentration and illumination time. Additionally, it was found that the values of PS concentration and illumination time to eradicate 90% of the initial population of microorganisms (IC90 and D90, respectively) were small for the AlPcCl in P‐123, showing the effectiveness of this formulation for PDI. 相似文献