Click chemistry in materials synthesis. III. Metal‐adhesive polymers from Cu(I)‐catalyzed azide–alkyne cycloaddition

1,2,3‐Triazole‐based polymers generated from the Cu(I)‐catalyzed cycloaddition between multivalent azides and acetylenes are effective adhesive materials for metal surfaces. The adhesive capacities of candidate mixtures of azide and alkyne components were measured by a modified peel test, using a customized adhesive tester. A particularly effective tetravalent alkyne and trivalent azide combination was identified, giving exceptional strength that matches or exceeds the best commercial formulations. The addition of Cu catalyst was found to be important for the synthesis of stronger adhesive polymers when cured at room temperature. Heating also accelerated curing rates, but the maximum adhesive strengths achieved at both room temperature and high temperature were the same, suggesting that crosslinking reaches the same advanced point in all cases. Polytriazoles also form adhesives to aluminum, but copper is bound more effectively, presumably because active Cu(I) ions may be leached from the surface to promote crosslinking and adhesion. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5182–5189, 2007     

Two-step cascades of 117Sn(n, 2γ) reaction and problems of describing main nuclear properties below Bn

Main properties of the excited states of ¹¹⁸Sn manifesting themselves in cascade γ decay of its compound state are studied. As in heavier nuclei studied earlier, qualitative interpretation of the whole set of observed properties of the nucleus appears to be impossible without accounting for coexistence and interaction of quasiparticle and collective nuclear excitations and their considerable influence on the main parameters of the process under study. From Yadernaya Fizika, Vol. 67, No. 10, 2004, pp. 1845–1849. Original English Text Copyright ? 2004 by Khitrov, Panteleev, Sukhovoj, Honzátko, Tomandl. This article was submitted by the authors in English.     

A new technique for obtaining the activation energy distribution of a relaxing system

This paper describes a robust and fast fitting procedure applicable for relaxing processes that cannot be understood as a discrete sum of single processes but require an activation energy distribution. The method is based on a set of closed-form expressions that allow the computation of the relaxation parameters directly from the isochronal curves obtained experimentally. The usefulness of this method is checked by analyzing the isochronal curves given by a theoretical energy distribution and the magnetic disaccommodation spectra observed in yttrium iron garnet (YIG) samples. PACS 02.60.Ed; 75.60.Lr; 75.50.Gg     

Young's inequality in trace-class operators

 If a and b are trace-class operators, and if u is a partial isometry, then , where ∥⋅∥₁ denotes the norm in the trace class. The present paper characterises the cases of equality in this Young inequality, and the characterisation is examined in the context of both the operator and the Hilbert–Schmidt forms of Young's inequality. Received: 20 December 2001 / Revised version: 11 July 2002 / Published online: 10 February 2003 Mathematics Subject Classification (2000): 47A63, 15A60     

Measurability implies continuity for solutions of functional equations - even with few variables

Summary. We prove that - under certain conditions - measurable solutions $f$ of the functional equation $f(x)=h(x,y,f(g_{1}(x,y)),\ldots,f(g_{n}(x,y))),\quad(x,y)\in D \subset \mathbb{R}^{s} \times \mathbb{R}^{l}$ are continuous, even if $1\le l\le s$. As a tool we introduce new classes of functions which - roughly speaking - interpolate between continuous and Lebesgue measurable functions. Connection between these classes are also investigated.     

Asymptotic behaviour of the least squares estimator of the mean of AR(1) models

The aim of the paper is to investigate the limit behaviour of the least squares estimator of the shift parameter of nearly unstable, nearly stable, and nearly explosive AR(1) models. Both zero start and stationary cases are treated. Connection with the maximum likelihood estimator of the shift parameter of continuous time AR(1) processes is also discussed.     

Photo-orientation at liquid crystal—polymer interfaces

It is suggested that liquid crystal—polymer interfaces are coupled systems, in which the components mutually influence the orientational state of each other. The photo-orientation process at liquid crystal-polymer interfaces provides a striking example of such a coupling. Experiments show that the anisotropic structure generated by polarised light at a polymer surface is strongly affected by the phase of the liquid crystal covering the polymer. Photo-orientation is significantly more efficient when the liquid crystal is in the isotropic phase than when it exhibits orientational order. The observations are interpreted by assuming that in the smectic and nematic phases the liquid crystal stabilises to a large extent polymer chain-segments aligned parallel to the director, while it blocks the photo-induced formation of chain-segments in the perpendicular direction. Other situations, in which the coupling between the liquid crystal and the polymer can be important, are also discussed briefly.     

The Calogero–Bogoyavlenskii–Schiff Equation in 2+1 Dimensions

We use the classical and nonclassical methods to obtain symmetry reductions and exact solutions of the (2+1)-dimensional integrable Calogero–Bogoyavlenskii–Schiff equation. Although this (2+1)-dimensional equation arises in a nonlocal form, it can be written as a system of differential equations and, in potential form, as a fourth-order partial differential equation. The classical and nonclassical methods yield some exact solutions of the (2+1)-dimensional equation that involve several arbitrary functions and hence exhibit a rich variety of qualitative behavior.     

Universality and summability of trigonometric polynomials and trigonometric series

Periodica Mathematica Hungarica -