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61.
Bogdan Tutunaru Adriana Samide Catalin Negrila 《Journal of Thermal Analysis and Calorimetry》2013,111(2):1149-1154
The influence of different ions NO3 ? and SO4 2? on the carbon steel corrosion in ammonium chloride was investigated using mass loss measurements and potentiodynamic polarization. Corrosion products were analyzed using X-ray photoelectron spectroscopy (XPS) and simultaneous thermal and differential scanning calorimetry (TG/DSC). XPS analysis shows that the main product of corrosion is a non-stoichiometric Fe3+ oxyhydroxide, consisting of a mixture of FeO(OH) and FeO(OH) containing inclusions of these anions, species such as Fe3+O(OH,Cl?); Fe3+O(OH,SO4 2?); and Fe3+O(OH,NO3 ?). TG/DSC confirms the decomposition of the rusty products formed by chemical corrosion, compounds like Fe3+ oxyhydroxides, with β-FeOOH as the major phase, crystal structure of which may contain Cl?, NO3 ?, and SO4 2?—e.g., akaganeite [Fe3+O(OH,A)]. 相似文献
62.
Adriana Aniceto Julia Montenegro Rafael da Silva Cadena Anderson Junger Teodoro 《Molecules (Basel, Switzerland)》2021,26(2)
Amazonian fruits are excellent sources of bioactive compounds and can be used in beverages to improve the nutritional and sensorial characteristics. The present study aimed to develop a blend of murici (Byrsonima Crassifolia (L.) Kunth) and taperebá (Spondias Mombin L.) through experimental design and investigating the nutritional and sensorial characteristics of fruits and beverages. The murici was highlighted as higher vitamin C content (58.88 mg · 100 g−1) compared to taperebá (25.93 mg · 100 g−1). The murici and taperebá are good sources of total phenolic compounds (taperebá 1304.15 ± 19.14 mgGAE · 100 g−1 and the murici of 307.52 ± 19.73 mg GAE · 100 g−1) and flavonoids (174.87 ± 1.76 μgQE/g and 129.46 ± 10.68 μgQE/g, murici and taperebá, respectively), when compared to other Brazilian fruits. The antioxidant capacity in different methods revealed that the taperebá had a higher average in the results, only in the ORAC method and did not present a significant difference (p > 0.05) in relation to the murici. The beverage development was performed using experimental design 23, showed through sensory analysis and surface response methodology that murici and high sugar content (between 12.5 and 14.2% of sugar) influenced in sensory acceptance. Our findings indicate that beverages with improved nutrition and a sensory acceptance can be prepared using taperebá and murici fruits. 相似文献
63.
Gheorghe Ilia Adriana Popa Smaranda Iliescu Alina Bora Gheorghe Dehelean Aurelia Pascariu 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1513-1519
Some mixed phosphites having two different alkyl chain were obtained as forerunners for mixed phosphates Mixed dialkyl phosphates were obtained in good yields (40-80%) by phase transfer catalysis in liquid-liquid sistem, starting from different dialkyl phosphites and aliphatic alcohols. The reaction conditions were optimized in order to obtain good yields in phosphites and phosphates respectively. Compounds were analyzed by IR, P 31 -NMR. 相似文献
64.
Background
Escherichia coli DNA topoisomerase I binds three Zn(II) with three tetracysteine motifs which, together with the 14 kDa C-terminal region, form a 30 kDa DNA binding domain (ZD domain). The 67 kDa N-terminal domain (Top67) has the active site tyrosine for DNA cleavage but cannot relax negatively supercoiled DNA. We analyzed the role of the ZD domain in the enzyme mechanism. 相似文献65.
Recently, a new and efficient method for total homocysteine (tHcy) quantitation in plasma using trap and release membrane introduction mass spectrometry (T&R-MIMS) with a versatile removable direct introduction membrane probe (DIMP) was described [R. Haddad, M. A. Mendes, N. F. Hoehr and M. N. Eberlin, Analyst, 2001, 126, 1212]. Herein we report on the use of the DIMP-T&R-MIMS technique for total cysteine (tCys) quantitation; hence combined tCys and tHcy quantitation in plasma or serum can be achieved. The method employs Cys and Hcy derivatization with ethyl chloroformate (after disulfide bond reduction with dithiothreitol and protein precipitation with trichloroacetic acid), preconcentration in a capillary silicone membrane, and their thermal desorption to the gas phase inside the ion source region of a mass spectrometer, at a point exactly between the two ionization filaments. Thermal desorption uses the uniform heat radiation provided by the two ionization filaments. The analytes are then ionized by electron ionization and both Cys and Hcy are quantitated by mass spectrometry using selected ion monitoring. For tCys quantitation, good linearity and reproducibility was observed for concentrations ranging from 5 to 350 microM, recovery was near 95%, and the limit of detection (LOD) was of 2 microM. This LOD is well below the mean Cys concentration in plasma, and serum samples from a large group of healthy people showed a mean tCys concentration of 132 +/- 45 microM. 相似文献
66.
The 1:1 and 2:1 complexes between water and trans- and cis-isomers of nitrous acid have been isolated in argon matrices and studied using FTIR spectroscopy and DFT(B3LYP) calculations with a 6-311++G(2d,2p) basis set. The analysis of the experimental spectra indicate that 1:1 complexes trapped in solid argon involve very strong hydrogen bond in which acid acts as the proton donor and water as the proton acceptor. The perturbed OH stretches are −248, −228 cm−1 red shifted from their free-molecules values in complexes formed by trans- and cis-HONO isomers, respectively. The calculated spectral parameters for the two complexes are in good agreement with experimental data. The calculations also predict stability of two more 1:1 weakly bound complexes formed by each isomer. In these the water acts as the proton donor and one of the two oxygen atoms of the acid as the acceptor. The experimental spectra demonstrate also formation of 2:1 complex between water and trans-HONO isomer in an argon matrix. The performed calculations indicate that the complex involves a seven-membered ring in which OH group of HONO forms very strong hydrogen bond with the oxygen atom of one water molecule and nitrogen atom acts as a weak proton acceptor for the hydrogen atom of the second water molecule of the water dimer. The observed perturbations of the OH stretch of trans-HONO (750 cm−1 red shift) is much larger than that predicted by calculations (556 cm−1 red shift); this difference is attributed to strong solvation effect of argon matrix on very strong hydrogen bond. 相似文献
67.
Vivian?Regina?Trist?o Fernando?Felippe?de?Carvalho Cinthia?Zanini?Gomes Adriana?Regina?Miranda Cíntia?C.?Vequi-Suplicy Maria?Teresa?Lamy Nestor?Schor Maria?Helena?Bellini 《Journal of fluorescence》2010,20(3):665-669
The progression to end-stage renal failure is independent of the initial pathogenic mechanism. Metabolic acidosis is a common
consequence of chronic renal failure that results from inadequate ammonium excretion and decreased tubular bicarbonate reabsorption.
Protoporphyrin IX (PpIX) is the immediate metabolic precursor of the heme molecule. The purpose of this study was to evaluate
the levels of erythrocytes protoporphyrin IX at an animal model during progressive renal disease. A total of 36 eight-week-old
male Wistar rats were divided into six groups: Normal, 4 and 8 weeks after 5/6 nephrectomy (NX). Renal function was evaluated
by creatinine clearance and plasma creatinine levels. The autofluorescence of erythrocytes porphyrin of healthy and NX rats
was analyzed using fluorescence spectroscopy. Emission spectra were obtained by exciting the samples at 405 nm. Significant
differences between normal and NX rats autofluorescence shape occurred in the 600–700 nm spectral region. A correlation was
observed between emission band intensity at 635 nm and progression of renal disease. 相似文献
68.
Pairing correlations are studied numerically in a hole-doped spin-fermion model. Simulations performed on up to 12 x 12 clusters provide indications of D-wave superconductivity away from half-filling comparable to those of the 2D t-J model. The pairing correlations are the strongest in the direction perpendicular to the dynamic stripes that appear in the ground state at some densities. An optimal doping, where correlations are maximized, was observed at approximately 25% doping with an estimated T(c) approximately 100-200 K, in qualitative agreement with high-T(c) cuprates' phenomenology, while pairing correlations are suppressed by static stripe inhomogeneities. 相似文献
69.
The complex formation equilibria between titanium(IV) and fluoride ions have been studied at 25°C in 3 M(Na)Cl ionic medium by measuring, with an ion selective electrode for F?, the free HF concentration in acid Ti(IV) solutions. The [H+] was kept within 0.25 and I M where the predominant form of uncomplexed metal is the dihydroxotitanium(IV) ion, Ti(OH)2+2. The potentiometric data have been explained by assuming Ti(OH)2F+, TiF4 and HTiF?6, with equilibrium constants given in Table 3. Within the accuracy of the present e.m.f. study, ±0.2 mV, no evidence for intermediate complexes bearing 2, 3 and 5 F? was found.From a special series of measurements, carried out by replacing a large part of the Cl? with ClO?4, it is concluded that no appreciable amount of Ti(IV)Cl complexes is formed at the 3 M level employed as ionic medium. 相似文献
70.
Dombrowski C Lewellyn B Pesci AI Restrepo JM Kessler JO Goldstein RE 《Physical review letters》2005,95(18):184501
From algal suspensions to magma upwellings, one finds jets which exhibit complex symmetry-breaking instabilities as they are decelerated by their surroundings. We consider here a model system--a saline jet descending through a salinity gradient--which produces dynamics unlike those of standard momentum jets or plumes. The jet coils like a corkscrew within a conduit of viscously entrained fluid, whose upward recirculation braids the jet, and nearly confines transverse mixing to the narrow conduit. We show that the underlying jet structure and certain scaling relations follow from similarity solutions to the fluid equations and the physics of Kelvin-Helmholtz instabilities. 相似文献