Inhibition of a palladium(II) catalyst upon formation of a di‐μ‐chloro complex: di‐μ‐chloro‐bis­[1,2‐bis­(di­phenyl­phosphino)­ethane‐P,P′]dipalladium(II) bis­(tetra­fluoro­borate) bis­(deutero­chloro­form) solvate

The title compound was formed upon slow evaporation of a solution of the solvated dicationic complex bis­(aceto­nitrile)­bis­[1,2‐bis­(di­phenyl‐phosphino)­ethane]­palladium(II) bis(tetra­fluoro­borate) in deuterated chloro­form. The dinucleur palladium complex forms triclinic crystals and there is an inversion center between the Pd atoms. Compared to the corresponding monomeric compound, the Cl—Pd—Cl angles decrease upon briding from 94.19 (7) to 86.96 (4)°.     

Synthesis and Photophysical Properties of Fluorescein Esters as Potential Organic Semiconductor Materials

Journal of Fluorescence - Fluorescein (1), a known fluorescent tracer in microscopy with high photophysical properties, was esterified to have fluorescein ethyl ester (2) and O-ethyl-fluorescein...     

Computational analysis of entropy generation in mixed convection flow past a vertical wavy cone

Journal of Thermal Analysis and Calorimetry - The problem of entropy generation in mixed convection flow of incompressible viscous fluid along an isothermal vertical wavy cone is investigated...     

A study of cylindrically symmetric solutions in $$f(R, \phi,X)$$ theory of gravity

The European Physical Journal C - Much theoretical effort and automatization are required to confront new physics models with experimental data for many types of particle reactions at future...     

Influence of yttrium doping on the photocatalytic activity of bismuth oxybromide for ciprofloxacin degradation using indoor fluorescent light illumination

Research on Chemical Intermediates - In this work, a series of Y-doped BiOBr photocatalysts with different yttrium contents were successfully synthesized through a facile ethylene glycol-assisted...     

Synthesis of biologically active nickelocenyl–amino acid conjugates using 1,3-dipolar cycloaddition click reactions

Russian Journal of General Chemistry - Herein we present the study of synthesis of novel bio-organometallic conjugates using 1,3-dipolar cycloaddition click reactions. Amino acid azides such as...     

The influence of porosity on the elastic response of homogeneous and structural composite media

Continuum theories of composites are employed to analyze the influence of inclusions and porosity on the elastic response of both homogeneous and laminated composite media. The general model analyzed consists of a periodic array of two perfectly bonded laminates; one of which consists of an elastic homogeneous material while the other is made up of a periodic array of cylindrical elastic inclusions that are distributed in another elastic matrix material. Several specific models are deduced as special cases. In all cases, porosity is simulated in the limit as the properties of the inclusions identically vanish. It is demonstrated that porosity plays a major role in the geometric dispersion of such media; in particular, it increases the arrival and rise times (spreading) of a propagating transient pulse. For the special case of elastic inclusions in a homogeneous matrix media, the present results correlate very well with existing experimental data and other approximate analyses.     

Direct fabrication of graphene/zinc oxide composite film and its characterizations

Graphene-based composites represent a new class of materials with potential for many applications. Graphene can be attached to a metal, a semiconductor, or any polymer for enhancing properties. In this work, a new mixed dispersion approach for graphene-based composite has taken on. Graphene flakes (<4 layers) and a well-known semiconductor zinc oxide (ZnO) (<50 nm particle size) have dispersed in N-methyl-pyrrolidone. We deposited graphene/ZnO composite thin film by a simple, low-cost, environmentally friendly and non-vacuum electrohydrodynamic atomization process on silicone substrate. Experiments have been carried out by changing flow rate and applied potential while keeping stand-off distance and substrate velocity constant, to discover the optimum conditions for obtaining a high-quality thin film. It has been explored that high-quality thin composite film is obtained at optimum flow rate of 300 μl/h at 6.3 kV applied potential after curing for 2 h at 300 °C. Graphene/ZnO thin composite film has been characterized using Field emission scanning electron microscopy, Ultra-violet Visible near Infra Red spectroscopy, X-ray diffraction, Raman Spectroscopy and 3D-Nanomap. For electrical behavior analysis, a simple diode Indium tin oxide/(poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS)/polydioctylfluorene-benzothiadiazole(F8BT)/(Graphene/ZnO) has fabricated. It is observed that at voltage of 0.3 V, the current in organic structure is at low value of 1.20 × 10^?3 Amp/cm² and after that as further voltage was applied, the device current increased by the order of 110 and reaches up to 1.32 × 10^?1 Amp/cm² at voltage 2 V.