Thermal stabilities of some benzaldehyde 2,4-dinitrophenylhydrazones

The thermal stability of some benzaldehyde 2,4-dinitrophenylhydrazones has been studied using DSC technique. The crystalline solids are thermally stable and start to decompose after melting. Non-isothermal DSC curves, recorded at several heating rates, were used to evaluate the melting properties and the kinetics of thermal decomposition. Both isoconversional and model fitting methods were used for the evaluation of the kinetic parameters. Based on the results of the model free method, a kinetic model was derived and the kinetic parameters were obtained by means of a multivariate non-linear regression. A good agreement between the experimental and fitted data was found.     

Assembly of a novel supramolecular synthon of calix[4]arene presenting four carboxylic acids

An extremely complex solid state structure described by two virtual channels and a 2-D square grid of hydrogen bonds is generated by four carboxylic acids groups of calix[4]arene tetrabutyroxycarboxylic acid.     

Exponential Dichotomy on the Real Line and Admissibility of Function Spaces

The purpose of this paper is to give characterizations for uniform exponential dichotomy of evolution families on the real line. We consider a general class of Banach function spaces denoted and we prove that if with and the pair is admissible for an evolution family then is uniformly exponentially dichotomic. By an example we show that the admissibility of the pair for an evolution family is not a sufficient condition for uniform exponential dichotomy. As applications, we deduce necessary and sufficient conditions for uniform exponential dichotomy of evolution families in terms of the admissibility of the pairs and with      

Structure formation of integral-asymmetric membranes of polystyrene-block-Poly(ethylene oxide)

For the first time the combination of solution casting and solvent–nonsolvent exchange (phase inversion) has been applied to generate asymmetric membranes with highly ordered hexagonally packed cylinders with perpendicular orientation composed of polystyrene-block-poly(ethylene oxide). The influence of parameters like solvent composition and evaporation time on the membrane formation is presented. The development is based on a study of the solution behavior by dynamic light scattering and the precipitation behavior of the cylinder forming diblock copolymer by turbidity measurements from different solvent and nonsolvent systems. The water flux properties, as an important membrane characteristic, show a time dependent behavior, due to swelling of the polyethylene oxide blocks. The morphologies of the membranes are imaged by scanning electron microscopy. © 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013     

Microstructures and growth characteristics of polyelectrolytes on silicon using layer-by-layer assembly

Growth processes of nanocomposite layers obtained by polyelectrolytes, poly(sodium 4-styrenesulfonate) (PSS) and poly(diallyldimethylammonium chloride) (PDADMAC), self-assembled on silicon surface using layer-by-layer (LbL) technique were investigated, and theoretical and experimental data are herein reported. Complementary microstructural and compositional analyses techniques (scanning electron microscopy, ellipsometry, X-ray reflectivity, zeta (ξ) potential measurements and attenuated total reflection infrared spectroscopy) were used for deep characterization of the multilayer structure formation. Electrophoretic zeta (ξ) potential measurements indicated that the surface charge was either positive or negative, depending on the polyelectrolyte used (PDADMAC or PSS). ATR-IR spectra confirmed the successfully silanization process and then, the building up of the nanocomposite layer. Morphological investigation and X-ray reflectivity demonstrated the growth process and cross-section size of the bilayers. Ellipsometric measurements were in very good agreement with SEM and XRR, showing once again the successful deposition of polyelectrolyte multilayers.      

Kinetic analysis of isothermal decomposition of 2,4-dinitrophenylhydrazine using differential scanning calorimetry

Differential scanning calorimetry was used to study the thermal decomposition of 2,4-dinitrophenylhydrazine (DNPH) in isothermal regime. The DSC curves were carried out at several constant temperatures lower than the melting temperature. The standard isoconversional analysis of the obtained curves suggests an autocatalytic decomposition mechanism. This mechanism is also supported by the temperature dependence of the observed induction periods.     

Input-output admissibility and exponential trichotomy of difference equations

We propose a new method for the study of the asymptotic behavior of difference equations in infinite-dimensional spaces, providing characterizations for the property of uniform exponential trichotomy. We deduce the structure of the stable, unstable and bounded subspace and prove the uniqueness of the projection families. We introduce a new admissibility concept with respect to a discrete input-output system and prove that this is a necessary and sufficient condition for the existence of uniform exponential trichotomy. Throughout the paper, there is no assumption on the coefficients and the obtained results are applicable to any class of difference equations.     

Biharmonic PNMC submanifolds in spheres

We obtain several rigidity results for biharmonic submanifolds in $\mathbb{S}^{n}$ with parallel normalized mean curvature vector fields. We classify biharmonic submanifolds in $\mathbb{S}^{n}$ with parallel normalized mean curvature vector fields and with at most two distinct principal curvatures. In particular, we determine all biharmonic surfaces with parallel normalized mean curvature vector fields in $\mathbb{S}^{n}$ . Then we investigate, for (not necessarily compact) proper-biharmonic submanifolds in $\mathbb{S}^{n}$ , their type in the sense of B.-Y. Chen. We prove that (i) a proper-biharmonic submanifold in $\mathbb{S}^{n}$ is of 1-type or 2-type if and only if it has constant mean curvature f=1 or f∈(0,1), respectively; and (ii) there are no proper-biharmonic 3-type submanifolds with parallel normalized mean curvature vector fields in $\mathbb{S}^{n}$ .     

Influence of the Substitution Degree on the Dilute Solution Properties of Cellulose Acetate

Modification of intrinsic viscosity, coil size, and preferential adsorption coefficients of cellulose acetate with various substitution degrees in single and mixed solvents was investigated at different temperatures. Miscibility is attained by specific competitive interactions between the solvent-solvent and solvent-polymer systems, which induce modification in the composition of solvent mixtures both inside and outside the polymer coil. The conformational properties in solutions were correlated with the preferential adsorption coefficients, known as depending on the interaction parameters of the polymer/solvent/solvent systems. The intermolecular interactions observed in the cellulose acetate solutions assure the main properties necessary for obtaining membranes with different applications.