Self-organized criticality in the olami-feder-christensen model

A system is in a self-organized critical state if the distribution of some measured events obeys a power law. The finite-size scaling of this distribution with the lattice size is usually enough to assume that the system displays self-organized criticality. This approach, however, can be misleading. In this paper we analyze the behavior of the branching rate sigma of the events to establish whether a system is in a critical state. We apply this method to the Olami-Feder-Christensen model to obtain evidence that, in contrast to previous results, the model is critical in the conservative regime only.     

Ionic and covalent copper(II)-based catalysts for Michael additions. The mechanism

Cu(SbF6)2-AdamBox and copper(II) bis-(5-tert-butylsalicylaldehydate) catalyze the Michael addition in neutral media. Mechanistic studies, based on UV-vis, IR, and electrospray ionization mass spectrometry (ESI-MS), suggest that copper enolates of the beta-dicarbonyl formed in situ are the active nucleophilic species.     

Organometallic chemistry of 15-membered tri-olefinic macrocycles: catalysis by palladium(0) complexes in carbon-carbon bond-forming reactions

15-Membered macrocycles (E,E,E)-1,6,11-tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes (1) are prepared from arenesulfonamides and trans-1,4-dibromo-2-butene. Macrocycles 1 coordinate palladium(0), platinum(0), and silver(I). The palladium complexes are useful and reutilizable catalysts or precatalysts in Suzuki cross-couplings, butadiene telomerizations, hydroarylation of alkynes, and in the Heck reaction. Structurally related macrocycles are also available by similar synthetic procedures.     

Salt effects on reactivity for the formation and dissociation of bis-(ethane-1,2-diamine)cobalt(III)-μ-pyrazinecarboxylato-pentacyanoferrate(II)

Dependences of rate constants on added salt concentrations have been established for approach to equilibrium for reaction of pyrazinecarboxylato-bis-1,2-diaminoethane-cobalt(III) with the pentacyanoferrate(II) complex [Fe(CN)₅L]^3– with L = MeCN. Added salt effects on dissociation of the binuclear bis-1,2-diaminoethanecobalt(III)(-pyrazine-carboxylato)pentacyanoferrate(II), [(en)₂Co(-pzCO₂)Fe(CN)₅]^–, produced in this reaction are compared with those on dissociation of other pentacyanoferrate(II) complexes. The activation volume for dissociation of this binuclear complex has been derived from the observed salt effects via the dependence of rate constants on surface tension and the thence-derived surface area of activation.     

Electrochemical analysis of nucleic acids at boron-doped diamond electrodes

Highly conductive boron-doped diamond (BDD) electrodes are well suited for performing electrochemical measurements of nucleic acids in aqueous solution under diffusion-only control. The advantageous properties of this electrodic material in this context include reproducibility and the small background currents observed at very positive potentials, along with its robustness under extreme conditions so offering promising capabilities in future applications involving thermal heating or ultrasonic treatment. tRNA, single and double stranded DNA and 2'-deoxyguanosine 5'-monophosphate (dGMP) have been studied and well defined peaks were observed in all cases, directly assignable to the electro-oxidation of deoxyguanosine monophosphate.     

Test for properness using residue calculus

We will consider global problems in the ringK[X ₁, …,X _n] on the polynomials with coefficients in a subfieldK ofC. LetP=(P ₁, …,P _n):K ⁿ →K ⁿ be a polynomial map such that (P ₁,…,P _n) is a quasi-regular sequence generating a proper ideal, the main thing we do is to use the algebraic residues theory (as described in [5]) as a computational tool to give some result to test when a map (P ₁, …,P _n) is a proper map by computing a finite number of residue symbols.     

Mild Selective Hydrolysis of Acetals in Carbohydrates

A simple and inexpensive methodology for the selective hydrolysis of acetals using hydrogen chloride as catalyst is described.     

Experimental evidence of a Rayleigh-plateau instability in free falling granular jets

A granular jet falling out of a funnel shaped container, subjected to small vertical vibrations, develops an instability farther downstream as may happen for ordinary liquid jets. Our results show that this instability is reminiscent of the Rayleigh-Plateau capillary instability leading to breakup of the jet at large scales. The first stages of this instability are captured in detail allowing a determination of the dispersion relation. Surface tensions measured in this unstable regime (of the order of mN/m) are in agreement with previously reported measurements carried out at much smaller scales. This instability and the breakup of the jet can be inhibited when the effect of the surrounding medium (air) is reduced by enclosing the jet in an evacuated chamber, showing that the effective surface tension measured is the result of a strong interaction with the surrounding air.     

Thermal compatibility between hydroquinone and retinoic acid in pharmaceutical formulations

Thermogravimetry (TG) and differential scanning calorimetry (DSC) are used in pharmaceutical studies for characterization of drugs, purity, compatibility of formulations, identification of polymorphism, evaluation of stability, and thermal decomposition of drugs and pharmaceutical formulations. Hydroquinone (HQ) and products containing HQ have been widely used as depigmentation agents for lightening the skin. Retinoids are compounds that have the basic core structure of vitamin A and its oxidized metabolites, or synthetic compounds that share similar mechanisms of action as naturally occurring retinoids. Depigmentants and excipients were analyzed by TG and DSC. The dynamic thermogravimetric curves were obtained on a SHIMADZU thermobalance, model DTG-60, using an alumina crucible, at the heating rate of 10 °C min^?1, in the temperature range of 25–900 °C, under an atmosphere of nitrogen at 50 mL min^?1. The sample's mass was 10 ± 0.05 mg. The DSC curves were obtained using Shimadzu calorimeter, model DSC-60, using aluminum crucible, at the heating rate of 10 °C min^?1, in the temperature range of 25–400 °C. The thermogravimetric and calorimetric curves were analyzed using TASYS software SHIMADZU. In this study were found the interaction between retinoic acid (RA) and the following excipients: cetyl alcohol(CA), cetostearyl alcohol (CTA), glycerin(GLY), and dipropylene glycol (DPG), and that between HQ and the excipient, DPG. Therefore, additional studies are necessary to evaluate final formulations. Thermal analysis is an effective and reliable technique that can be used in the control of raw materials and pharmaceutical products, and for evaluating their employment potential in the development and characterization of products.     

Thermooptical detection in microchips: from macro- to micro-scale with enhanced analytical parameters

In this paper, we compared the methods of photothermal spectroscopy used in different spatial scales, namely thermal-lens spectrometry (TLS) and thermal-lens microscopy (TLM) to enhance the performance parameters in analytical procedures. All of the experimental results were confirmed by theoretical calculation. It was proven that the design for both TLM and TLS, despite a different scale for the effect, is governed by the same signal-generating and probing conditions (probe beam diameter at the sample should be equal to the diameter of the blooming thermal lens), and almost does not depend on the nature of the solvent. Theoretical and experimental instrumental error curves for thermal lensing were coincident. TLM obeys the same law of instrumental error as TLS and shows better repeatability for the same levels of thermal-lens signals or absorbances. TLS is more advantageous for studying low concentrations in bulk, while TLM shows much lower absolute LODs due to better repeatability for low amounts. The behavior of the thermal-lens signal with different flow rates was studied and optimum conditions, with the minimum contribution to total error, were found. These conditions are reproducible, are in agreement with the existing theory of the thermal response in thermal lensing, and do not significantly affect the design of the optimum scheme for setups. TLM showed low LODs in solvent extraction (down to 10(-8) M) and electrokinetic separation (10(-7) M), which were shown to be governed by discussed instrumental regularities, instead of by microchemistry.