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71.
Adel F. Halasa Chad Jusinas Wen-Liang Hsu David J. Zanzig 《European Polymer Journal》2010,46(10):2013-2018
The present work is to the syntheses and characterization of random, low vinyl copolymers containing styrene and isoprene (SIR’s). The content of these SIR’s ranged from 10% styrene/90% isoprene to 60% styrene/40% isoprene, and all were soluble in hexane solvent. The anionic polymerization of these SIR’s was initiated by a catalyst system of various sodium dodecylbenzene sulfonate (SDBS) to n-butyllithium (n-BuLi) ratios. The SDBS allowed for styrene to become randomly incorporated onto the polyisoprene chain without any increase in the 3,4-unit of the isoprene. The glass transition temperature of the resulting polymers could be controlled by the styrene content and microstructure (blocky versus random) in the polymer chain. Kinetic data confirmed that styrene and isoprene have similar reaction kinetics. NMR and ozonolysis confirmed that random, low vinyl SIR’s were indeed being synthesized. The unique features of this system are that it does not metallate the polymers as was seen in the previous publication using the sodium and potassium alkoxides. Molecular weight differences due to SDBS are discussed. Finally, rubber process analyzer (RPA) results were presented for various styrenes content SIR’s. 相似文献
72.
Some 6-(1H-1,2,3-triazol-1-yl)pyrimidine-2,4(1H,3H)-dione derivatives were synthesized via the reaction of 6-azido-1,3-dimethyluracil
with ethyl acetoacetate in the presence of sodium ethoxide. The antiviral activities of these compounds against Hepatitis
A virus (HAV, MBB-cell culture adapted strain) and Herpes simples virus type-1 (HSV-1) were tested. 相似文献
73.
74.
Hanaa A. El-Boraey Randa M. Abdel-Rahman Ensaf M. Atia Khalid H. Hilmy 《Central European Journal of Chemistry》2010,8(4):820-833
Two novel Schiff base ligands of 2-amino-3-cyano-1,5-diphenylpyrrole and salicylaldehyde (HL1) or 2- hydroxy1-naphthylaldehyde (HL2) and their copper(II) complexes have been synthesized and characterized by elemental analyses, spectral (UV-Vis, IR, EPR,
Mass (for ligands)), thermal (DTA-TGA) methods, magnetic and conductance measurements. IR results demonstrate the bidentate
binding of the Schiff base ligands involving azomethine nitrogen, phenolic or naphtholic oxygen and suggest the presence of
HL2 and complexes (1, 2, 4 and 8) in enolimine-ketonamine tautomeric forms in the solid state. The EPR spectral data of complexes
(2, 5, 6) show that the metal — ligand bonds have considerable covalent character. The thermal studies show that complexes
(1, 2, 4 and 8) that are present in enolimine-ketonamine tautomeric forms exhibit lower thermal stability. The effect of synthesized
ligands (HL1, HL2) and complexes (1, 5) were tested on the mortality of entomopathogenic nematodes (EPN) (Heterorhabditis bacteriophora and
Steinernema carpocapsae). The study shows that the mortality of the nematodes increased with increasing concentrations of
copper(II) ion, ligands and complexes. Copper(II) ion was the most toxic for EPN.
相似文献
75.
76.
This paper aims to present a general framework of the quadratic spline functions to develop a numerical method for solving the nonlinear space fractional Fisher's equation. Using Von Neumann method, the proposed method is shown to be conditionally stable. Finally, a numerical example is given to verify the effectiveness of the proposed algorithm. The results reveal that the proposed approach is very effective, convenient, and quite accurate to such considered problems. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
77.
In this paper, we propose a new model for the search and rescue problem. We focus on the case of a single airborne search asset through a connected space and continuous time with a maximum travel time \(T\) . The intent is to maximize the detection of a cooperative target (search and rescue). The proposed model is based on the assumption of existing a priori information (e.g., result of information fusion process) to establish a spatial distribution of probability of containment in possible geographic locations. The possibility area is defined using a cut threshold on the probability of containment and the search path as well as the allocation of the level of effort to each region in the search space is obtained based on an orienteering model. We illustrate the application of the proposed model on an empirical example. 相似文献
78.
Chahra Bouchameni Chahrazed Beghidja Adel Beghidja Pierre Rabu Richard Welter 《Polyhedron》2011,30(11):1774-1778
Two new complexes [MnIII(HL)2(acac)] and [MnII(HL)2]n have been obtained by reacting manganese(III) acetylacetonate monohydrate or manganese(II) chloride monohydrate with 2-salicylichydrazono-1,3-dithiolane ligand (H2L). Both compounds have been fully characterized by spectroscopic methods and single crystal X-ray diffraction. In the solid state, the molecular packing are described and discussed in term of weak H-bonds and short contacts. The unprecedented bridging coordination mode of this ligand lead to the first 2-salicylichydrazono-1,3-dithiolane-bridged coordination polymer [MnII(HL)2]n. The EPR spectrum of this compound was obtained with g ≈ 2.07, corresponding to a manganese ion (+II) in octahedral high-spin coordination sphere. The MnII complex exhibit paramagnetic behavior corresponding to quasi-isolated metal centers. 相似文献
79.
80.
A. A.-H. Abdel-Rahman A. H. A. Ahmed M. M. M. Ramiz 《Chemistry of Heterocyclic Compounds》2010,46(1):72-78
The reactions of 4-aminoantipyrine with acetylacetone, ethyl acetoacetate, morpholine, piperazine, and ethyl cyanoacetate
were studied. All structures were determined by 1H NMR and mass spectroscopy techniques. 相似文献