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181.
A 3-step synthesis of menthofuran from isopulegol in 65–70% is reported. 相似文献
182.
Muhammad Arshad Sibtain Ahmed Muhammad Anjum Zia Muhammad Ibrahim Rajoka 《Applied biochemistry and biotechnology》2014,172(5):2455-2464
In this study, we have used ultraviolet (UV) and γ-ray induction to get a catabolite repression resistant and thermotolerant mutant with enhanced ethanol production along with optimization of sugar concentration and temperature of fermentation. Classical mutagenesis in two consecutive cycles of UV- and γ-ray-induced mutations evolved one best catabolite-resistant and thermotolerant mutant Saccharomyces cerevisiae MLD10 which showed improved ethanol yield (0.48?±?0.02 g g?1), theoretical yield (93?±?3 %), and extracellular invertase productivity (1,430?±?50 IU l?1 h?1), respectively, when fermenting 180 g sugars l?1 in molasses medium at 43 °C in 300 m3 working volume fermenter. Ethanol production was highly dependent on invertase production. Enthalpy (ΔH*) (32.27 kJ M?1) and entropy (ΔS*) (?202.88 J M?1 K?1) values at 43 °C by the mutant MLD10 were significantly lower than those of β-glucosidase production by a thermophilic mutant derivative of Thermomyces lanuginosus. These results confirmed the enhanced production of ethanol and invertase by this mutant derivative. These studies proved that mutant was significantly improved for ethanol production and was thermostable in nature. Lower fermentation time for ethanol production and maintenance of ethanol production rates (3.1 g l?1 h?1) at higher temperature (43 °C) by this mutant could decrease the overall cost of fermentation process and increase the quality of ethanol production. 相似文献
183.
Zeshan Adeel Umar Ijaz Ahmad Khan Tousif Hussain Ali Hussnain Nida Khalid 《辐射效应与固体损伤》2013,168(11-12):892-901
Composite films of TiN/Ni3N/a-Si3N4 were synthesized using the Mather-type plasma focus device with varying numbers of focus deposition shots (5, 15, and 25) at 0° and 10° angular positions. The composition and structural analysis of these films were analyzed by using Rutherford backscattering (RBS) and X-ray diffraction (XRD). Scanning electron microscope and atomic force microscope were used to study the surface morphology of films. XRD patterns confirm the formation of composite TiN/Ni3N/a-Si3N4 films. The crystallite size of TiN (200) plane is 11 and 22 nm, respectively, at 0° and 10° angular positions for same 25 focus deposition shots. Impurity levels and thickness were measured using RBS. Scanning electron microscopy results show the formation of net-like structures for multiple focus shots (5, 15, and 25) at angular positions of 0° and 10°. The average surface roughness of the deposited films increases with increasing focus shots. The roughness of the film decreases at higher angle 10° and the films obtained are smoother as compared with the films deposited at 0° angular positions. 相似文献
184.
Synthesis of Hollow Mesoporous TiO2 Microspheres with Single and Double Au Nanoparticle Layers for Enhanced Visible‐Light Photocatalysis
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Dr. Zia Ur Rahman Dr. Ning Wei Dr. Yange Feng Dr. Xiaolong Zhang Prof. Daoai Wang 《化学:亚洲杂志》2018,13(4):432-439
A facile method was used to prepare hollow mesoporous TiO2 and Au@TiO2 spheres using polystyrene (PS) templates. Au nanoparticles (NPs) were simultaneously synthesized and attached on the surface of PS spheres by reducing AuCl4? ions using sodium citrate which resulted in the uniform deposition of Au NPs. The outer coating of titania via sol‐gel produced PS@Au@TiO2 core–shell spheres. Removing the templates from these core–shell spheres through calcination produced hollow mesoporous and crystalline Au@TiO2 spheres with Au NPs inside the TiO2 shell in a single step. Anatase spheres with double Au NPs layers, one inside and another outside of TiO2 shell, were also prepared. Different characterization techniques indicated the hollow mesoporous and crystalline morphology of the prepared spheres with Au NPs. Hollow anatase spheres with Au NPs indicated enhanced harvesting of visible light and therefore demonstrated efficient catalytic activity toward the degradation of organic dyes under the irradiation of visible light as compared to bare TiO2 spheres. 相似文献
185.
Tauqeer Ahmed Arif-ullah Khan Muzaffar Abbass Edson Rodrigues Filho Zia Ud Din Aslam Khan 《Chemistry Central journal》2018,12(1):134
In this study dibenzylidene ketone derivatives (2E,5E)-2-(4-methoxybenzylidene)-5-(4-nitrobenzylidene) cyclopentanone (AK-1a) and (1E,4E)-4-(4-nitrobenzylidene)-1-(4-nitrophenyl) oct-1-en-3-one (AK-2a) were newly synthesized, inspired from curcuminoids natural origin. Novel scheme was used for synthesis of AK-1a and AK-2a. The synthesized compounds were characterized by spectroscopic techniques. AK-1a and AK-2a showed high computational affinities (E-value >???9.0 kcal/mol) against cyclooxygenase-1, cyclooxygenase-2, proteinase-activated receptor 1 and vitamin K epoxide reductase. AK-1a and AK-2a showed moderate docking affinities (E-value >???8.0 kcal/mol) against mu receptor, kappa receptor, delta receptor, human capsaicin receptor, glycoprotein IIb/IIIa, prostacyclin receptor I2, antithrombin-III, factor-II and factor-X. AK-1a and AK-2a showed lower affinities (E-value >???7.0 kcal/mol) against purinoceptor-3, glycoprotein-VI and purinergic receptor P2Y12. In analgesic activity, AK-1a and AK-2a decreased numbers of acetic acid-induced writhes (P?<?0.001 vs. saline group) in mice. AK-1a and AK-2a significantly prolonged the latency time of mice (P?<?0.05, P?<?0.01 and P?<?0.001 vs. saline group) in hotplate assay. AK-1a and AK-2a inhibited arachidonic acid and adenosine diphosphate induced platelet aggregation with IC50 values of 65.2, 37.7, 750.4 and 422 µM respectively. At 30, 100, 300 and 1000 µM concentrations, AK-1a and AK-2a increased plasma recalcification time (P?<?0.001 and P?<?0.001 vs. saline group) respectively. At 100, 300 and 1000 µg/kg doses, AK-1a and AK-2a effectively prolonged bleeding time (P?<?0.001 and P?<?0.01 vs. saline group) respectively. Thus in-silico, in-vitro and in-vivo investigation of AK-1a and AK-2a reports their analgesic, antiplatelet and anticoagulant actions. 相似文献
186.
In this article, we apply the concept of m-polar fuzzy sets in labeling graphs and introduce the concept of m-polar fuzzy labeling graphs. We present properties of m-polar fuzzy labeling cycle and m-polar fuzzy labeling with bridge and cut nodes. We introduce several different types of distances, including w-distance, strongest strong distance, strong geodesic distance, \(\delta \)-distance in m-polar fuzzy labeling graph and investigate some of their properties. We also present an application of m-polar fuzzy labeling graphs in image processing. 相似文献
187.
Ayesha Murtaza Zia Ulhaq Bahareh Shirinfar Sadia Rani Samina Aslam Guilherme M. Martins Nisar Ahmed 《Chemical record (New York, N.Y.)》2023,23(10):e202300119
C−H bond functionalization generates molecular complexity in single-step transformation. However, the activation of C−H bonds requires expensive metals or stoichiometric amounts of oxidizing/reducing species. In many cases, they often require pre-functionalization of starting molecules. Such pre-activating measures cause waste generation and their separation from the final product is also troublesome. In such a scenario, reactions activating elements generating from renewable energy resources such as electricity and light would be more efficient, green, and cost-effective. Further, incorporation of growing flow technology in chemical transformation processes will accelerate the safer accesses of valuable products. Arenes & heteroarenes are ubiquitous in pharmaceuticals, natural products, medicinal compounds, and other biologically important molecules. Herein, we discussed enabling tools and technologies used for the recent C−H bonds functionalization of arenes and heteroarenes. 相似文献
188.
189.
Douglas Cenzer Rodney G. Downey Jeffrey B. Remmel Zia Uddin 《Archive for Mathematical Logic》2009,48(1):115-140
We develop a theory of LOGSPACE structures and apply it to construct a number of examples of Abelian Groups which have LOGSPACE presentations. We show that all computable torsion Abelian groups have LOGSPACE presentations and we show that the groups , and the additive group of the rationals have LOGSPACE presentations over a standard universe such as the tally representation and the binary representation of the natural numbers.
We also study the effective categoricity of such groups. For example, we give conditions are given under which two isomorphic
LOGSPACE structures will have a linear space isomorphism.
相似文献
190.
In the present work, a new ligandless-dispersive liquid-liquid microextraction (LL-DLLME) method has been developed for preconcentration trace amounts of copper as a prior step to its determination by flame atomic absorption spectrometry. In the proposed approach 1,2-dicholorobenzene and ethanol were used as extraction and dispersive solvents, respectively. Some factors influencing on the extraction efficiency of copper and its subsequent determination were studied and optimized, such as the extraction and dispersive solvent type and volume, pH of sample solution, extraction time and salting out effect. Under the optimal conditions, the calibration curve was linear in the range of 1.0 ng mL−1-0.6 μg mL−1 of copper with R2 = 0.9985. Detection limit was 0.5 ng mL−1 in original solution (3Sb/m) and the relative standard deviation for seven replicate determination of 0.2 μg mL−1 copper was ±1.4%. The proposed method has been applied for determination of copper in standard and water samples with satisfactory results. 相似文献