全文获取类型
收费全文 | 2206篇 |
免费 | 34篇 |
国内免费 | 8篇 |
专业分类
化学 | 1200篇 |
晶体学 | 4篇 |
力学 | 70篇 |
数学 | 274篇 |
物理学 | 700篇 |
出版年
2021年 | 12篇 |
2019年 | 16篇 |
2018年 | 15篇 |
2017年 | 11篇 |
2016年 | 31篇 |
2015年 | 23篇 |
2014年 | 34篇 |
2013年 | 88篇 |
2012年 | 84篇 |
2011年 | 108篇 |
2010年 | 71篇 |
2009年 | 49篇 |
2008年 | 132篇 |
2007年 | 128篇 |
2006年 | 99篇 |
2005年 | 93篇 |
2004年 | 89篇 |
2003年 | 63篇 |
2002年 | 75篇 |
2001年 | 53篇 |
2000年 | 59篇 |
1999年 | 25篇 |
1998年 | 25篇 |
1997年 | 24篇 |
1996年 | 55篇 |
1995年 | 64篇 |
1994年 | 50篇 |
1993年 | 51篇 |
1992年 | 45篇 |
1991年 | 27篇 |
1990年 | 24篇 |
1989年 | 24篇 |
1988年 | 25篇 |
1987年 | 30篇 |
1986年 | 17篇 |
1985年 | 21篇 |
1984年 | 24篇 |
1983年 | 20篇 |
1982年 | 21篇 |
1981年 | 32篇 |
1980年 | 21篇 |
1979年 | 23篇 |
1978年 | 24篇 |
1977年 | 23篇 |
1976年 | 29篇 |
1975年 | 25篇 |
1974年 | 17篇 |
1973年 | 21篇 |
1971年 | 14篇 |
1970年 | 12篇 |
排序方式: 共有2248条查询结果,搜索用时 0 毫秒
31.
Recent measurements of the high-energy charged particle environment with the Radiation Environment Monitor (REM) aboard the Russian Mir space station are presented. Ionizing dose rates in a silicon detector have been measured with two shieldings. The dose is mainly accumulated in two distinct areas, the South Atlantic Anomaly (SAA) and the region of closest approach to the magnetic poles. Whereas the radiation in the South Atlantic Anomaly varied little during 1995, large changes of the daily absorbed doses in the polar regions are observed. A comparison of REM doses with the NASA AP-8 and AE-8 radiation models revealed major differences. AP-8 tends to underestimate the average REM doses, whereas AE-8 overestimates REM doses, and rather describes the worst case. 相似文献
32.
Abachi S Abbott B Abolins M Acharya BS Adam I Adams DL Adams M Ahn S Aihara H Alitti J Álvarez G Alves GA Amidi E Amos N Anderson EW Aronson SH Astur R Avery RE Baarmand MM Baden A Balamurali V Balderston J Baldin B Banerjee S Bantly J Bartlett JF Bazizi K Bendich J Beri SB Bertram I Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Bischoff A Biswas N Blazey G Blessing S Bloom P Boehnlein A Bojko NI Borcherding F Borders J Boswell C Brandt A Brock R Bross A Buchholz D Burtovoi VS Butler JM 《Physical review letters》1996,77(4):595-600
33.
Abachi S Abbott B Abolins M Acharya BS Adam I Adams DL Adams M Ahn S Aihara H Alitti J Álvarez G Alves GA Amidi E Amos N Anderson EW Aronson SH Astur R Avery RE Baarmand MM Baden A Balamurali V Balderston J Baldin B Banerjee S Bantly J Bartlett JF Bazizi K Bendich J Beri SB Bertram I Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Bischoff A Biswas N Blazey G Blessing S Bloom P Boehnlein A Bojko NI Borcherding F Borders J Boswell C Brandt A Brock R Bross A Buchholz D Burtovoi VS Butler JM 《Physical review letters》1996,77(25):5011-5015
34.
Abachi S Abbott B Abolins M Acharya BS Adam I Adams DL Adams M Ahn S Aihara H Alitti J Álvarez G Alves GA Amidi E Amos N Anderson EW Aronson SH Astur R Avery RE Baden A Balamurali V Balderston J Baldin B Bantly J Bartlett JF Bazizi K Bendich J Beri SB Bertram I Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Bischoff A Biswas N Blazey G Blessing S Bloom P Boehnlein A Bojko NI Borcherding F Borders J Boswell C Brandt A Brock R Bross A Buchholz D Burtovoi VS Butler JM Carvalho W Casey D 《Physical review letters》1996,76(18):3271-3276
35.
36.
37.
M. Ceulemans R. obiski W. M. R. Dirkx F. C. Adams 《Fresenius' Journal of Analytical Chemistry》1993,347(6-7):256-262
Summary A rapid, simple and sensitive method has been developed for the simultaneous determination of butyl- and phenyltin species in environmental waters. The ionic organotin compounds are ethylated in the aqueous phase using sodium tetraethylborate (NaBEt4) and extracted with hexane. A 25 l aliquot of the extract is injected at a low temperature into a Tenax filled liner. After solvent venting the analytes are transferred onto the capillary column using programmed temperature vaporization (PTV) injection. Detection is done by means of a microwave induced plasma atomic emission detector (MIP AED). The method allows the determination of butyl- and phenyltin compounds in water samples down to the level of 0.1 ng/l (as Sn) while 50 ml of sample is sufficient for analysis. The accuracy of the method was confirmed by GC-AAS after chelation and Grignard derivatization. 相似文献
38.
A flow injection on-line sorption preconcentration method for the electrothermal AAS determination of platinum has been developed. The pyrrolidine dithiocarbamate complexes of either Pt4+ or Pt2+, formed in 0.7 mol L–1 HNO3, are on-line adsorbed on the inner walls of a PTFE knotted reactor and subsequently eluted with methanol. An enhancement factor of 112 and a detection limit (3 σ) of 10 ng L–1 along with a sampling frequency of 21 h–1 are achieved with a 90 s preconcentration time at a sample flow rate of 8.8 mL min–1. The relative standard deviation is 2.5% for 0.4 μg L–1 Pt. The method has been applied to the determination of platinum in blood samples. 相似文献
39.
Reaction of CpMoMn(CO)(8) with elemental selenium and Me(3)NO in the absence of light yielded the diselenido complex CpMoMn(CO)(5)(mu-Se(2)), 2. Compound 2 contains a bridging diselenido ligand lying perpendicular to the Mo-Mn bond, Mo-Mn = 2.8421(10) A. In the presence of room light, the reaction yielded the tetranuclear metal complex Cp(2)Mo(2)Mn(2)(CO)(7)(mu(3)-Se)(4), 3 (36% yield), and 2 (7% yield). Compound 2 reacted with ethylene to yield the ethanediselenato complex CpMoMn(CO)(5)(mu-SeCH(2)CH(2)Se), 4, by insertion of ethylene into the Se-Se bond. Compound 2 also reacted with (PPh(3))(2)Pt(PhC(2)Ph) and CpCo(CO)(2) to yield the complexes CpMoMnPt(PPh(3))(2)(CO)(5)(mu(3)-Se)(2), 5, and Cp(2)CoMoMn(CO)(5)(mu(3)-Se)(2), 6, respectively, by insertion of the metal groupings CpCo and Pt(PPh(3))(2) into the Se-Se bond of 2. The oxo compound Cp(2)CoMo(O)Mn(CO)(5)(mu(3)-Se)(2), 7, was obtained from 6 by decarbonylation at molybdenum by using Me(3)NO. The molecular structures of the complexes 2-7 were established by single-crystal X-ray diffraction analyses. 相似文献
40.
The determination of beryllium and manganese in air particulate matter collected on filter material is discussed. Destruction by digestion with nitric and perchloric acids and by low-temperature ashing with dissolution of the ash in a hydrofluoric-nitric acid mixture were tested. The graphite furnace parameters were investigated for different acid solutions. Interferences of some cations and anions that are abundant in aerosol material are described. Accuracy was checked against standard samples. For manganese, the results are compared with those obtained by energy-dispersive x-ray fluorescence. 相似文献