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31.
G. Adam 《Colloid and polymer science》1960,172(2):132-141
Zusammenfassung Mit Hilfe freier Torsionsschwingungen wurde der Schubmodul von vernetztem und gequollenem Polystyrol bei 1 Hz in Abh?ngigkeit
von der Temperatur gemessen. Die Temperatur wurde zwischen −120° C und 200° C variiert.
Aus Ergebnissen verschiedener physikalischer Untersuchungsverfahren werden Vorstellungen über die zwischenmolekulare Struktur
des glasigen Polystyrols hergeleitet. Sie gestatten eine qualitative molekulare Interpretation der mechanisch-thermischen
Messungen sowie des Einflusses von chemischer Variation und Weichmachung auf den Einfriervorgang. 相似文献
32.
Sajal Sen Mark W. Perrin Adam C. Sedgwick Vincent M. Lynch Jonathan L. Sessler Jonathan F. Arambula 《Chemical science》2021,12(21):7547
Recent decades have witnessed the emergence of Au(i) bis-N-heterocyclic carbenes (NHCs) as potential anticancer agents. However, these systems exhibit little interaction with serum proteins (e.g., human serum albumin), which presumably impacts their pharmacokinetic profile and tumor exposure. Anticancer drugs bound to human serum albumin (HSA) often benefit from significant advantages, including longer circulatory half-lives, tumor targeted delivery, and easier administration relative to the drug alone. In this work, we present Au(i) bis-NHCs complexes, 7 and 9, capable of binding to HSA. Complex 7 contains a reactive maleimide moiety for covalent protein conjugation, whereas its congener 9 contains a naphthalimide fluorophore for non-covalent binding. A similar drug motif was used in both cases. Complexes 7 and 9 were prepared from a carboxylic acid functionalized Au(i) bis-NHC (complex 2) using a newly developed post-synthetic amide functionalization protocol that allows coupling to both aliphatic and aromatic amines. Analytical, and in vitro techniques were used to confirm protein binding, as well as cellular uptake and antiproliferative activity in A549 human lung cancer cells. The present findings highlight a hitherto unexplored approach to modifying Au(i) bis-NHC drug candidates for protein ligation and serve to showcase the relative benefits of covalent and non-covalent HSA binding.Au(i) bis-N-heterocyclic carbenes (NHCs) functionalized using an amide linker were found to bind to human serum albumin (HSA) in covalent and non-covalent fashion. The solubility and in vitro anti-cancer activity of these new conjugates were studied. 相似文献
33.
The Ramanujan Journal - For two varieties of dimension 5 constructed as double covers of $$\mathbb {P}^5$$ branched along the union of 12 hyperplanes, we prove that the number of points... 相似文献
34.
P. Abreu W. Adam E. Agasi I. Ajinenko R. Aleksan G. D. Alekseev P. P. Allport S. Almehed F. M. L. Almeida S. J. Alvsvaag et al. 《Zeitschrift fur Physik C Particles and Fields》1995,66(3):341-354
The forward-backward asymmetries for the processes
and
at theZ resonance are measured using identifiedD
*± mesons. In 905,000 selected hadronic events, taken in 1991 and 1992 with the DEL-PHI detector at LEP, 4757D
*+D
0+ decays are reconstructed. Thec andb quark forward-backward asymmetries are determined to be:
相似文献
35.
P. Abreu W. Adam T. Adye E. Agasi I. Ajinenko R. Aleksan G. D. Alekseev P. P. Allport S. Almehed S. J. Alvsvaag et al. 《Zeitschrift fur Physik C Particles and Fields》1995,68(3):353-362
The decayB
*B
has been observed with the DELPHI detector at LEP, where theB
* meson is produced inZ boson decays. The combination of inclusively reconstructedB mesons with well-measured converted photons yields a measurement of the flavour-averagedB
*-B mass difference of 45.5±0.3 (stat.) ±0.8 (syst.) MeV/c2. 95% confidence level upper limits at 6 MeV/c2 are placed on both the isospin (i.e.B
+-B
0) and theB
s
-B
ud
splitting of the mass difference. The production ratio ofB
* toB mesons inZ decays is measured to be 0.72±0.03 (stat.) ±0.06 (syst.). Limits on the production cross-section of other hypothetical excitedB hadron states decaying radiatively are established. The differentialB
* cross section has been measured to be in good agreement with the averageb fragmentation, yielding an average fractionalB
* energy of x
E
=0.695±0.009 (stat.) ±0.013 (syst.). From the decay angular distribution the relative contribution of longitudinalB
* polarisation states is measured to be L/(L + T) = 0.32 ± 0.04 (stat.) ±0.03 (syst.).CICYT_AEN93-0832 相似文献
36.
Consider the two-parameter family of real analytic maps $F_{a,b} :x \mapsto x + a + \tfrac{b}{{2\pi }}$ sin(2πx) which are lifts of degree one endomorphisms of the circle. The purpose of this paper is to provide a proof that for any closed intervalI, the set of mapsF a,b whose rotation interval isI, form a contractible set. 相似文献
37.
Vacuum expectation values for the Schwinger model are computed within the path integral formalism for an instanton vacuum. The calculations are done in flat Euclidean space and use the wellknown anomaly result. It can be demonstrated that the instanton vacuum is absolutely necessary to obtain a consistent quantization. At last the results are compared to a similar treatment on the sphere and to the operator solution of the Schwinger model.Supported by Fonds zur Förderung der wissenschaftlichen Forschung in Österreich, Projekt Nr. P8444-TEC 相似文献
38.
P. Abreu W. Adam T. Adye E. Agasi R. Aleksan G. D. Alekseev P. Allport S. Almehed F. M. L. Almeida Junior S. J. Alvsvaag et al. 《Zeitschrift fur Physik C Particles and Fields》1994,63(1):3-15
The average lifetime ofB hadrons was measured using data collected with the DELPHI detector at the LEP collider during 1991 and 1992. The measurement was performed using two different anayses. The first method was an improvement on a previous technique, which used charged particle impact parameter distributions. This analysis measured an average lifetime forB hadrons of
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