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271.
Sebastian Acosta 《Journal of Computational and Applied Mathematics》2010,234(6):1970-1979
A finite difference time-dependent numerical method for the wave equation, supported by recently derived novel elliptic grids, is analyzed. The method is successfully applied to single and multiple two-dimensional acoustic scattering problems including soft and hard obstacles with complexly shaped boundaries. The new grids have nearly uniform cell area (J-grids) and nearly uniform grid line spacing (αγ-grids). Numerical experiments reveal the positive impact of these two grid properties on the scattered field convergence to its harmonic steady state. The restriction imposed by stability conditions on the time step size is relaxed due to the near uniformity cell areas and grid line spacing. As a consequence, moderately large time steps can be used for relatively fine spatial grids resulting in greater accuracy at a lower computational cost. Also, numerical solutions for wave problems inside annular regions of complex shapes are obtained. The use of the new grids results in late time stability in contrast with other classical finite difference time-dependent methods. 相似文献
272.
An experiment aimed to investigate the two-proton (2p) decay of the previously unknown nucleus 30Ar was performed at GSI: By tracking the decay products in-flight with silicon micro-strip detectors, the 2p decays of 30Ar were observed for the first time. For the calibration purpose, 2p decays of 19Mg were also remeasured by tracking the coincident 17Ne+p+p trajectories. By comparing the measured angular p-17Ne correlations with those obtained from the corresponding Monte Carlo simulations, the simultaneous 2p decay of 19Mg ground state and the sequential 2p emission of several known excited states of 19Mg were confirmed. One new excited state in 19Mg and two new excited states in 18Na were observed. 相似文献
273.
274.
Acosta Gloria Chapela Víctor Manuel 《Journal of inclusion phenomena and macrocyclic chemistry》1985,3(1):9-12
It was hypothesized that the formation of polypeptide bonds inside a lamellar superconducting compound such as 2H-TaS2 could enhance the superconducting transition temperature. The preparation of tantalum disulfide intercalated with polyglycine is described. The intercalated systems were characterized by powder X-ray diffraction and thermogravimetric analysis. Superconducting transition temperatures were also measured. The results show that the system 2H-TaS2/polyglycine does not have a more favourableT
cvalue than 2H-TaS2/glycine. 相似文献
275.
276.
277.
John A. Manson Stanley A. Iobst Rodrigo Acosta 《Journal of polymer science. Part A, Polymer chemistry》1972,10(1):179-186
A convenient method has been developed for the polymerization of vinyl chloride at low temperatures (to at least ?75°C) by using a tungsten–iodine rather than an ultraviolet lamp, and uranyl nitrate as sensitizer. The use of predominantly visible light minimizes degradation reactions sometimes encountered with ultraviolet light. Measurements of the fraction of racemic (or syndiotactic) diads and per cent crystallinity confirm that the products resemble polymers prepared by other techniques, such as polymerization initiated by a boron alkyl. It is concluded, therefore, that the method can provide a useful alternate to the more common, organometallic system. Measurements of torsional modulus as a function of temperature were also made. As the temperature of polymerization is lowered, the fraction of racemic diads and the per cent crystallinity are increased. The higher the per cent crystallinity, the higher the glass temperature, the broader the glass transition, and the higher the modulus in the rubbery state. Thus, the increased stereoregularity permits the development of a higher level of crystallinity which, in turn, restricts the mobility of the polymer chains. 相似文献
278.
279.
Linker molecules are added to microemulsion systems to enhance the interaction between the surfactant and oil (lipophilic linkers) or water (hydrophilic linkers) phases. Previous results suggest that when lipophilic and hydrophilic linkers are combined they behave as a self-assembled surfactant at the oil/water interface. In this work we investigate this self-assembly phenomenon as a function of surfactant, linker and electrolyte concentration. We find that middle phase microemulsion appears at a specific concentration higher than the critical micelle concentration (CMC), which we denote as the critical middle phase microemulsion concentration (CmicroC). When the lipophilic linker dodecanol is added in equimolar ratio to the hydrophilic linker sodium mono- and dimethyl naphthalene sulfonate (SMDNS), the middle phase microemulsion did not appear until the surfactant sodium dihexyl sulfosuccinate (SDHS) concentration was larger than the CmicroC of the SDHS-alone system. Dodecanol is shown to segregate near the surfactant tails following a Langmuir-type adsorption process. This segregation is not affected by the electrolyte concentration but is significantly reduced when the surfactant (SDHS) concentration approaches the CmicroC. The data suggest that the self-assembly between hydrophilic and lipophilic linkers to form middle phase microemulsions is only possible if a minimum amount of surfactant is present. 相似文献
280.
Various β-diketone chelates of Sc(III), Y(III), Th(IV), U(IV). U(VI), Zr(IV) and the lanthanides have been prepared, characterized and investigated to determine if they were volatile and stable. The ligands employed were acetylacetone(AA), trifluoroacetylacetone(TFAA), hexafluoroacetylacetone(HFAA), and dipivaloyl-methane(DPM). The chelates were sublimed in a fractional vacuum sublimator and the recrystallization temperature zones recorded for individual chelates. None of the lanthanide acetylacetonates arc volatile but the Sc(III), Th(IV), U(IV) and dioxouranium(VI) acetylacetonates are thermally stable and quite volatile below 150° at 1 mm mercury pressure. The lanthanide, Sc(III), Y(III), and dioxouranium(VI) trifluoroacetylacetonates are volatile and can be vacuum-sublimed below 150°, but are thermally unstable; only the Th(IV) chelate is sufficiently stable to be quantitatively recovered by sublimation. The Sc(III), Y(III), Th(IV), and lanthanide hexafluoroacetylacetonates are thermally stable and easily sublimed below 125° in vacua or at atmospheric pressure. All the dipivaloylmethanates studied were thermally stable and volatile and could be quantitatively recovered by vacuum sublimation below 140°.The volatility of the HFAA and DPM lanthanide chelates increased with an increase in atomic weight (a decrease in ionic radii) of the lanthanides. The lack of volatility observed for the lanthanide AA and TFAA chelates is attributed to the fact that only hydrates of the chelates were formed, which decomposed at elevated temperatures in vacuo to form basic polymeric compounds.Separations are proposed for numerous binary mixtures of the β-diketone chelates of the lanthanide and related elements. Recrystallization temperature zones are given for the following binary mixtures which were quantitatively resolved by the fractional sublimation technique; 118-88° for Nd(DPM)3 and 84-48° for Tm(DPM)3; 72-49° for Sc(DPM) and 120-88° for Pr(DPM); 128-79° for La(DPM)3 and 79-47° for Yb(DPM)3; 70-47° for Th(TFAA)4 and 116-96° for Gd(TFAA)3; 52-42° for Th(HFAA)4 and 120-80° for La(HFAA)3. 相似文献