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排序方式: 共有310条查询结果,搜索用时 15 毫秒
261.
Edgar Acosta 《Current Opinion in Colloid & Interface Science》2009,14(1):3-15
The field of nanoparticle delivery systems for nutrients and nutraceuticals with poor water solubility has been expanding, almost exponentially, over the last five years, and some of these technologies are now in the process of being incorporated in food products. The market projections for these technologies suggest a multifold increase in their commercial potential over the next five years. The interest in the pharmaceutical and food-related applications of these technologies has sparked tremendous developments in mechanical (top-down) and chemical (bottom-up) processes to obtain such nanoparticle systems. Mechanical approaches are capable of producing nanoparticles, typically in the 100–1000 nm range, whereas chemical methods tend to produce 10–100 nm particles. Despite these technological developments, there is a lack of information regarding the basis of design for such nanoparticle systems. Fundamental thermodynamic and mass transfer equations reveal that, in order to generate a broad spectrum delivery system, nanoparticles with 100 nm diameter (or less) should be produced. However, experimental data reveal that, in some cases, even nanoparticles in the 100–1000 nm range are capable of producing substantial improvement in the bioavailability of the active ingredients. In most cases, this improvement in bioavailability seems to be linked to the direct uptake of the nanoparticle. Furthermore, direct nanoparticle uptake is controlled by the size and surface chemistry of the nanoparticle system. The use of this direct nanoparticle uptake, in particular for soluble but poorly absorbed ingredients, is one of the areas that needs to be explored in the future, as well as the potential side effects of these nanoparticle carriers. 相似文献
262.
Sobron P Sanz A Acosta T Rull F 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,71(5):1678-1682
Acidic waters and sulfate-rich precipitates are found in mine tailings such as Rio Tinto (Huelva, SW, Spain). In this work we have characterized the chemical constituents of stream water and have identified some efflorescent salts and precipitates by means of Raman spectroscopy. Variable amounts of sulfate and bisulfate are found in the aqueous samples, suggesting changes in the acidity of the solutions. An estimation of the sulfate/water relative abundance is also given. Solid samples are readily identified as gypsum and as mixtures of hydrated hydroxysulfates belonging to the copiapite group. These results are consistent with previous works reporting the mineralogy and water composition of acid mine drainage-related sites, and proves the importance of Raman spectroscopy as a tool for accurate and noninvasive analyses of acid waters and associated geochemistry. 相似文献
263.
Sherol Acosta Rodrigues 《Analytica chimica acta》2010,678(1):82-89
An evaluation of the extraction of pesticides from onion by matrix solid-phase dispersion (MSPD) with the determination by liquid chromatography tandem mass spectrometry using electrospray as the ionization source (LC-ESI-MS/MS) was carried out. The performance of different sorbents, including reused C18 bonded silica, was evaluated. Different parameters affecting the extraction efficiency were evaluated, such as the type and amount of sorbent, the time of interaction after the fortification step, the time of sample dispersion and the elution solvent. The matrix effect regarding the recovery of the pesticides by MSPD was also investigated. The best results were obtained using 0.5 g of sample, 1.0 g reused C18, interaction time of 1 h, dispersion time of 5 min, and acetonitrile as the elution solvent. The method was validated by the fortification of the onion sample, free of pesticides, at different concentration levels (0.01, 0.1 and 1.0 mg kg−1). Average recoveries ranged from 78.3 to 120.4% and relative standard deviation below 20% was obtained. Detection and quantification limits ranged from 0.003 to 0.03 mg kg−1 and from 0.01 to 0.1 mg kg−1, respectively. 相似文献
264.
Xiaoxu Zhou Brian G. Thomas C. Alberto Hernández B. A. Humberto Castillejos E. F. Andrés Acosta G. 《Applied Mathematical Modelling》2013
This paper presents a methodology combining experimental measurements with computational modeling to find the heat flux extracted during spray cooling of a metal surface. Controlled experiments are performed to impinge air-mist spray onto a metal probe surface while applying induction heating to follow a desired temperature history. A transient axisymmetric computational model of induction heating which couples electromagnetics and heat conduction has been developed and validated with a test problem. The model is calibrated to match transient dry measurements and then used to simulate a steady-state air-mist spray cooling experiment in order to quantify the heat extracted from the probe surface by the boiling water droplets. A detailed example is presented to illustrate this approach. 相似文献
265.
Abulencia A Acosta D Adelman J Affolder T Akimoto T Albrow MG Ambrose D Amerio S Amidei D Anastassov A Anikeev K Annovi A Antos J Aoki M Apollinari G Arguin JF Arisawa T Artikov A Ashmanskas W Attal A Azfar F Azzi-Bacchetta P Azzurri P Bacchetta N Bachacou H Badgett W Barbaro-Galtieri A Barnes VE Barnett BA Baroiant S Bartsch V Bauer G Bedeschi F Behari S Belforte S Bellettini G Bellinger J Belloni A Ben-Haim E Benjamin D Beretvas A Beringer J Berry T Bhatti A Binkley M Bisello D Bishai M 《Physical review letters》2006,96(20):202002
We present a measurement of the tt production cross section in pp collisions at square root s = 1.96 TeV which uses events with an inclusive signature of significant missing transverse energy and jets. This is the first measurement which makes no explicit lepton identification requirements, so that sensitivity to W --> tau nu decays is maintained. Heavy flavor jets from top quark decay are identified with a secondary vertex tagging algorithm. From 311 pb(-1) of data collected by the Collider Detector at Fermilab, we measure a production cross section of 5.8 +/- 1.2(stat)(-0.7)(+0.9)(syst) pb for a top quark mass of 178 GeV/c2, in agreement with previous determinations and standard model predictions. 相似文献
266.
Abulencia A Acosta D Adelman J Affolder T Akimoto T Albrow MG Ambrose D Amerio S Amidei D Anastassov A Anikeev K Annovi A Antos J Aoki M Apollinari G Arguin JF Arisawa T Artikov A Ashmanskas W Attal A Azfar F Azzi-Bacchetta P Azzurri P Bacchetta N Bachacou H Badgett W Barbaro-Galtieri A Barnes VE Barnett BA Baroiant S Bartsch V Bauer G Bedeschi F Behari S Belforte S Bellettini G Bellinger J Belloni A Ben-Haim E Benjamin D Beretvas A Beringer J Berry T Bhatti A Binkley M Bisello D Bishai M 《Physical review letters》2006,96(20):201801
We search for pair-produced Dirac magnetic monopoles in 35.7 pb(-1) of proton-antiproton collisions at square root s = 1.96 TeV with the Collider Detector at Fermilab (CDF). We find no monopole candidates corresponding to a 95% confidence-level cross-section limit sigma < 0.2 pb for a monopole with mass between 200 and 700 GeV/c2. Assuming a Drell-Yan pair-production mechanism, we set a mass limit m > 360 GeV/c2. 相似文献
267.
Abulencia A Acosta D Adelman J Affolder T Akimoto T Albrow MG Ambrose D Amerio S Amidei D Anastassov A Anikeev K Annovi A Antos J Aoki M Apollinari G Arguin JF Arisawa T Artikov A Ashmanskas W Attal A Azfar F Azzi-Bacchetta P Azzurri P Bacchetta N Bachacou H Badgett W Barbaro-Galtieri A Barnes VE Barnett BA Baroiant S Bartsch V Bauer G Bedeschi F Behari S Belforte S Bellettini G Bellinger J Belloni A Ben-Haim E Benjamin D Beretvas A Beringer J Berry T Bhatti A Binkley M Bisello D Bishai M 《Physical review letters》2006,96(4):042003
We report the results of a search for a charged Higgs boson in the decays of top quarks produced in pp collisions at a center-of-mass energy of 1.96 TeV. We use a data sample corresponding to an integrated luminosity of 193 pb-1 collected by the upgraded Collider Detector at Fermilab. No evidence for charged Higgs production is found, allowing 95% C.L. upper limits to be placed on BR(t-->H+b) for different charged Higgs decay scenarios. In addition, we present in the minimal supersymmetric standard model (mH+/-, tanbeta) plane the first exclusion regions with radiative and Yukawa coupling corrections. 相似文献
268.
Abulencia A Acosta D Adelman J Affolder T Akimoto T Albrow MG Ambrose D Amerio S Amidei D Anastassov A Anikeev K Annovi A Antos J Aoki M Apollinari G Arguin JF Arisawa T Artikov A Ashmanskas W Attal A Azfar F Azzi-Bacchetta P Azzurri P Bacchetta N Bachacou H Badgett W Barbaro-Galtieri A Barnes VE Barnett BA Baroiant S Bartsch V Bauer G Bedeschi F Behari S Belforte S Bellettini G Bellinger J Belloni A Ben-Haim E Benjamin D Beretvas A Beringer J Berry T Bhatti A Binkley M Bisello D Bishai M 《Physical review letters》2006,96(19):191801
We report an observation of the decay B(O)(S) --> D(-)(s)pi(+) in pp collisions at radical S = 1.96 TeV using 115 pb(-1) of data collected by the CDF II detector at the Fermilab Tevatron. We observe 83 +/- 11(stat) B(O)(s) --> D(-)(s)pi(+) candidates, representing a large increase in statistics over previous measurements and the first observation of this decay at a pp collider. We present the first measurement of the relative branching fraction Beta(B(O)(s) --> D(-)(s)pi(+))/Beta(B(0) --> D(-)(pi)(+)) = 1.32 +/- 0.18(stat) +/- 0.38(syst). We also measure Beta(B(+) --> D(0)pi(+))/Beta(B(0) -->D(-)pi(+)) = 1.97 +/- 0.10(stat) +/- 0.21(syst), which is consistent with previous measurements. 相似文献
269.
We present an approach to the characterization of low-power bright picosecond optical pulses with an internal frequency modulation simultaneously in both time and frequency domains in practically much used case of the Gaussian shape. This approach exploits the Wigner time-frequency distribution, which can be found for these bright pulses by using a novel interferometric technique under our proposal. Then, the simplest two-beam scanning Michelson interferometer is selected for shaping the field-strength auto-correlation function of low-power picosecond pulse trains. We are proposing and considering in principle the key features of a new experimental technique for accurate and reliable measurements of the train-average width as well as the value and sign of the frequency chirp of pulses in high-repetition-rate trains. This technique is founded on an ingenious algorithm for the advanced metrology, assumes using a specially designed supplementary semiconductor cell, and suggests carrying out a pair of additional measures with exploiting this semiconductor cell. Such a procedure makes possible constructing the Wigner distribution and describing the above-listed time-frequency parameters of low-power bright picosecond optical pulses. In the appendix, we follow one of possible avenues for deriving the joint Wigner time-frequency distribution via choosing the Weil's correspondence between classical functions and operators. 相似文献
270.
Jairo Quiroga Norha E. Sánchez Paola Acosta Braulio Insuasty Rodrigo Abonia 《Tetrahedron letters》2012,53(25):3181-3187
Novel fused pyrazolo[3,4-b]pyrazines 3 were prepared by assisted microwave cyclocondensation reaction of ortho-aminonitrosopyrazoles 1 and cyclic β-diketones 2 in dimethylformamide. This protocol provides a simple procedure for the synthesis of the title compounds with the advantages of easy work-up, mild reaction conditions and good yields. 相似文献