全文获取类型
收费全文 | 303篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 121篇 |
晶体学 | 4篇 |
力学 | 7篇 |
数学 | 56篇 |
物理学 | 122篇 |
出版年
2023年 | 1篇 |
2022年 | 5篇 |
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 4篇 |
2016年 | 8篇 |
2015年 | 5篇 |
2014年 | 4篇 |
2013年 | 15篇 |
2012年 | 12篇 |
2011年 | 10篇 |
2010年 | 12篇 |
2009年 | 16篇 |
2008年 | 13篇 |
2007年 | 14篇 |
2006年 | 38篇 |
2005年 | 23篇 |
2004年 | 14篇 |
2003年 | 13篇 |
2002年 | 6篇 |
2001年 | 5篇 |
2000年 | 6篇 |
1999年 | 6篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 12篇 |
1993年 | 10篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1968年 | 2篇 |
排序方式: 共有310条查询结果,搜索用时 15 毫秒
231.
Bartelt J Csorna SE Egyed Z Jain V Akerib DS Barish B Chadha M Chan S Cowen DF Eigen G Miller JS O'Grady C Urheim J Weinstein AJ Acosta D Athanas M Masek G Paar H Sivertz M Bean A Gronberg J Kutschke R Menary S Morrison RJ Nakanishi S Nelson HN Nelson TK Richman JD Ryd A Tajima H Schmidt D Sperka D Witherell MS Procario M Yang S Cho K Daoudi M Ford WT Johnson DR Lingel K Lohner M Rankin P Smith JG Alexander JP Bebek C Berkelman K Besson D Browder TE Cassel DG Cho HA Coffman DM Drell PS 《Physical review letters》1993,71(25):4111-4115
232.
Bartelt J Csorna SE Egyed Z Jain V Sheldon P Akerib DS Barish B Chadha M Chan S Cowen DF Eigen G Miller JS O'Grady C Urheim J Weinstein AJ Acosta D Athanas M Masek G Ong B Paar H Sivertz M Bean A Gronberg J Kutschke R Menary S Morrison RJ Nakanishi S Nelson HN Nelson TK Richman JD Ryd A Tajima H Schmidt D Sperka D Witherell MS Procario M Yang S Balest R Cho K Daoudi M Ford WT Johnson DR Lingel K Lohner M Rankin P Smith JG Alexander JP Bebek C Berkelman K Besson D Browder TE Cassel DG Cho HA 《Physical review letters》1993,71(11):1680-1684
233.
234.
J.C. Herrera A.J. Rosas Romero O.E. Crescente M. Acosta S. Pekerar 《Journal of chromatography. A》1996,740(2):201-206
The separation and identification of flavones present in a chloroform extract of Baccharis trinervis leaves was investigated. The chromatographic system consisted of a amino-bonded column, gradient elution from hexane-chloroform (85:15) to chloroform-acetonitrile (40:60) and detection at 346 nm. Four flavones were found. From NMR and MS data they were identified as 5-hydroxy-7,4′-dimethoxyflavone (I), 5-hydroxy-7,3′,4′-trimethoxyflavone (II), 5,3′-dihydroxy-7,4′-dimethoxyflavone (III) and 5,4′-dihydroxy-7-methoxyflavone (IV). Flavone II and III have not been found in Baccharis trinervis before. The chromatographic system showed good selectivity for the separation of the flavones. The relation between tR and the structure is discussed. 相似文献
235.
Butler F Fu X Kalbfleisch G Lambrecht M Ross WR Skubic P Snow J Wang PL Wood M Bortoletto D Brown DN Fast J McIlwain RL Miao T Miller DH Modesitt M Schaffner SF Shibata EI Shipsey IP Wang PN Battle M Ernst J Kroha H Roberts S Sparks K Thorndike EH Wang CH Dominick J Sanghera S Skwarnicki T Stroynowski R Artuso M He D Goldberg M Horwitz N Kennett R Moneti GC Muheim F Mukhin Y Playfer S Rozen Y Stone S Thulasidas M Vasseur G Zhu G Bartelt J Csorna SE Egyed Z Jain V Sheldon P Akerib DS Barish B 《Physical review D: Particles and fields》1994,49(1):40-57
236.
Artuso M Goldberg M He D Horwitz N Kennett R Mountain R Moneti GC Muheim F Mukhin Y Playfer S Rozen Y Stone S Thulasidas M Vasseur G Xing X Zhu G Bartelt J Csorna SE Egyed Z Jain V Kinoshita K Barish B Chadha M Chan S Cowen DF Eigen G Miller JS O'Grady C Urheim J Weinstein AJ Acosta D Athanas M Masek G Paar HP Sivertz M Gronberg J Kutschke R Menary S Morrison RJ Nakanishi S Nelson HN Nelson TK Qiao C Richman JD Ryd A Tajima H Sperka D Witherell MS Procario M Balest R Cho K Daoudi M Ford WT 《Physical review letters》1994,72(24):3762-3766
237.
Lina M. Acosta Ali Bahsas Alirio Palma Justo Cobo John N. Low Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(9):o514-o518
(2SR,4RS)‐7‐Chloro‐2‐exo‐[(E)‐styryl]‐2,3,4,5‐tetrahydro‐1H‐1,4‐epoxy‐1‐benzazepine, C18H16ClNO, (I), crystallizes as a racemic twin in the space group P21 and the molecules are linked into a chain of edge‐fused R33(9) rings by a combination of C—H...O and C—H...N hydrogen bonds. The diastereoisomer (2RS,4RS)‐7‐chloro‐2‐endo‐[(E)‐styryl]‐2,3,4,5‐tetrahydro‐1H‐1,4‐epoxy‐1‐benzazepine, (II), also crystallizes as a racemic twin, but in the space group P212121, and a two‐centre C—H...N hydrogen bond and a three‐centre C—H...(O,N) hydrogen bond combine to link the molecules into a complex chain of rings. In (2R,4R)‐7‐fluoro‐2‐endo‐[(E)‐styryl]‐2,3,4,5‐tetrahydro‐1H‐1,4‐epoxy‐1‐benzazepine, C18H16FNO, (III), which is not isomorphous with (II), the molecules are linked by a single C—H...O hydrogen bond into simple chains, but the molecular arrangements in (II) and (III) are nonetheless very similar. The significance of this study lies in its observation of the variations in molecular configuration and conformation, and in the variation in the supramolecular aggregation, consequent upon modest changes in the peripheral substituents. 相似文献
238.
Spin echo formation in magnetic field gradients in the presence of fast stochastic motion is studied for hyperpolarized 3He gas at different diffusivities. The fast translational motion leads to frequency shifts already during echo formation, which can be described analytically for a linear gradient. Despite complete signal loss at the position of the spin echo itself, considerable intensity can be preserved at an earlier time (sqrt[2]tau rather than 2tau, where tau is the pulse delay). Hence, the phenomenon is designated as a pseudo spin echo. 相似文献
239.
For two complex Banach spaces X and Y,
(B
X; Y) will denote the space of bounded and continuous functions from B
X
to Y that are holomorphic on the open unit ball. The numerical radius of an element h in
(B
X; X) is the supremum of the set
. We prove that every complex Banach space X with the Radon-Nikodym property satisfies that the subset of numerical radius attaining functions in
(B
X; X) is dense in
(B
X; X). We also show the denseness of the numerical radius attaining elements of
in the whole space, where
is the subset of functions in
which are uniformly continuous on the unit ball. For C(K) we prove a denseness result for the subset of the functions in
(B
C(K); C(K)) which are weakly uniformly continuous on the closed unit ball. For a certain sequence space X, there is a 2-homogenous polynomial P from X to X such that for every R > e, P cannot be approximated by bounded and numerical radius attaining holomorphic functions defined on RB
X
. If Y satisfies some isometric conditions and X is such that the subset of norm attaining functions of
(B
X; ℂ) is dense in
(B
X; ℂ), then the subset of norm attaining functions in
(B
X; Y) is dense in the whole space.
The first author was supported in part by D.G.E.S. Project BFM2003-01681.
The second author’s work was performed during a visit to the Departamento de Análisis Matem’atico of Universidad de Granada,
with a grant supported by the Korea Research Foundation under grant (KRF-2002-070-C00006). 相似文献
240.
Gerardo A. Acosta Miriam Royo Beatriz G. de la Torre Fernando Albericio 《Tetrahedron letters》2017,58(28):2788-2791
Head to side-chain cyclothiodepsipeptides were conveniently prepared through a cyclative cleavage using the MeDbz linker. Briefly, the peptide sequence was elongated on a MeDbz-Gly-ChemMatrix resin and reacted with 4-nitrophenyl chloroformate, followed by treatment with DIEA to render an activated cyclic N-acyl-N′-methylurea-resin. Removal of the Cys protecting group and further treatment with DIEA allowed the formation of the thiolactone with the concomitant release of the cyclic peptide from the resin. 相似文献