A theoretical study of the stereodynamics for reaction O(1D) + CH4→OH + CH3 has been carried out using the quasiclassical trajectory method(QCT) on a potential energy surface structured by Gonzalez et al. The integral cross sections(ICSs), differential cross sections(DCSs) and product rotational angular momentum polarization have been calculated. With the collision energy increasing, the ICS decreases. There is no threshold energy, because no barrier is found on the minimum energy path. The DCS results show that the backward and forward scatterings exist at the same time. With the collision energy increasing, the dominant rotation of the product changes from the right-handed direction to the left-handed direction in planes parallel to the scattering plane. In the isotopic effect study, the decrease of the mass factor weakens the polarization degree of the rotational angular momentum vectors of the products. 相似文献
How to remove local oscillator (LO) side channel attacks has been a notoriously hard problem in continuous-variable quantum key distribution (CV-QKD). In the self-referenced CV-QKD schemes, the LO signal is locally generated at the receiver by an independent laser so that it is not co-transmitted with the quantum signal. This simple solution removes all LO side channels. However it also introduces some other practical vulnerabilities. Especially the polarization states of the quantum signal and LO signal may not be identical across the detector because of the presence of the polarization aberrations. Thus, the detection efficiency which is arguably the most critical experiment parameter of the practical implementation will be impaired. In this paper, we analyze the impact of polarization aberrations on the detection efficiency for CV-QKD and propose a self-referenced CV-QKD scheme in the presence of polarization aberrations by using an off-axis optical system. In the proposed scheme, the polarization states of the quantum signal would change with the off-axis optical system, thus impairing the heterodyne efficiency. Our security analysis shows a gap between the theory and practice of CV-QKD.
The health monitoring has been studied to ensure integrity of design of engine structure by detection, quantification, and prediction of damages. Early detection of faults may allow the downtime of maintenance to be rescheduled, thus preventing sudden shutdown of machines. In cylinder pressure developed, vibrations and noise emissions data provide a rich source of information about condition of engines. Monitoring of vibrations and noise emissions are novel non-intrusive methodologies for which positioning of various transducers are important issue. The presented work shows applicability of these diagnosis methodologies adopted in case of diesel engines. The effects of changing various fuel injection parameters was analyzed. Scope of using non-intrusive technique has been analyzed by changing locations of microphone. Novelty of this worklies in exploring signal processing methods for various locations around the engine test set up. Various frequency ranges of contributing noise and vibration sources were identified. Time-Frequency analysis showed the onset of various cyclic. Based on the identification of various frequency bands, it is possible to device suitable filters in order to extract more information. 相似文献