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121.
The Monte Carlo computer simulation technique of classical statistical mechanics is employed to determine the structure and thermodynamics of binary microclusters of Lennard-Jones atoms as a function of cluster size, composition and temperature. Further, amorphous microclusters are prepared by a Monte Carlo quench, and their structural properties are examined. The properties of interest include the internal energy, instantaneous “snapshot” pictures of the microcluster's atomic configuration, and the single-particle and pair distribution functions. The Lennard-Jones potential parameters are chosen to model Ar13, Ar7Kr6, Ar36Kr19 and Ar19Kr36, as well as to crudely model the bimetallic clusters of Cu19Ni36, Cu19Ru36 and Cu19Os36. A large variety of interesting features associated with these systems are described. 相似文献
122.
D. B. Abraham 《Communications in Mathematical Physics》1978,60(2):181-191
A representation of the pair correlation function for the rectangular Ising model in zero magnetic field is derived using a new spinor technique; this enables the scaling limit to be established, as well as several analytical properties of the scaling functions.Supported by the Fonds National Suisse de la Recherche Scientifique, by the National Science Foundation Grant No. PHY76-17191, and by the National Research Council of Canada Grant No. NRC A9344 相似文献
123.
124.
This is a numerical analysis of the steady-state Maxwell-Bloch equations in a Fabry-Perot cavity with standing waves, atomic detuning and cavity mistuning; the atoms are homogeneously broadened. In the Mean-Field Approximation (MFA) limit, the resulting output-input characteristics agree exactly with the analytical predictions for a ring cavity. This leads to the derivation of a state equation for the Fabry-Perot cavity in the MFA limit identical to that for a ring cavity. Agreement with the MFA within 4% are obtained when αL < 3, the mirror reflectivity is above 90%, and the cavity mistuning below 4% of its free spectral range. Simulations beyond the scope of the MFA are also made and the case of purely dispersive optical bistability is also considered. 相似文献
125.
Abraham Boyarsky 《Advances in Applied Mathematics》1985,6(1):113-128
Let {τr} be the family of maps from [0,1] into [0,1] with properties similar to those of τr(x) = rx(1 ? x), 0 ≤ r ≤ 4. The limiting behaviour of orbits {τrj(x)}j∞ = 1 is a complicated and discontinuous function of the parameter r. The stochastic approximation to the difference equation xn + 1 = τr(xn), xn + 1 = τr(xn) + W, where W is a fixed random variable independent of r and xn, is considered. It is shown that this Markov process admits a unique absolutely continuous invariant measure μr and, furthermore, that the map r → μr is continuous. Such a result is important in applications, since slight changes in the shape of τr no longer cause discontinuous consequences in the limiting behaviour of the system. 相似文献
126.
Tamam L Kraack H Sloutskin E Ocko BM Pershan PS Ulman A Deutsch M 《The journal of physical chemistry. B》2005,109(25):12534-12543
The molecular-scale structure and phase behavior of single-component Langmuir films of 4'-methyl-4-mercaptobiphenyl (MMB) and 4'-perfluoromethyl-4-mercaptobiphenyl (FMMB) on mercury were studied using surface tensiometry, grazing incidence X-ray diffraction, and X-ray reflectivity. At low coverages, a condensed but in-plane disordered single layer of surface-parallel molecules is found for both compounds. At high coverages, both compounds exhibit in-plane-ordered phases of standing-up molecules. For MMB, the biphenyl core dominates the structure, yielding a centered-rectangular unit cell with an area A(x) of 21.8 A(2)/molecule, with molecules tilted by approximately 14 degrees from the surface normal in the nearest-neighbor direction, and a coherence length xi of >1000 A for the crystalline domains. For FMMB, the perfluoromethyl group dominates the structure, yielding a hexagonal unit cell with untilted molecules, an area A(x) of 24.2 A(2)/molecule, and a much smaller xi of approximately 110 A. The structure is discussed in comparison with self-assembled monolayers of MMB on crystalline Au(111) and similar-length alkanethiolate SAMs on Au(111) and on mercury. The differences in the structure are discussed and traced to the differences in the substrate's surface structure, and in the molecular cross section and rigidity. 相似文献
127.
We consider a tier of weakened bonds along the center line of a two-dimensional Ising ferromagnet strip as a model of a grain boundary. When an interface traverses such a strip at an angle, whether or not there is a continuous pinning-depinning transition at subcritical temperature depends on this angle and the degree of bond weakening. We also study the relaxation of such a system to its equilibrium state using continuous time Monte Carlo simulation with Kawasaki dynamics; this reveals a matter transport mechanism confined to the grain boundary. 相似文献
128.
129.
Photo-lithographically impregnated and molecularly imprinted polymer thin film for biosensor applications 总被引:1,自引:0,他引:1
A voltammetric sensor for albuterol was investigated where we combined the techniques of microfabrication and molecular imprinting to construct on-chip devices using photoirradiation of cross-linkable polymers. Molecularly imprinted polymer was coated as a thin film onto the gold working electrode on chip and the analyte was directly quantified by differential pulse voltammetric measurements. 相似文献
130.
Bleomycin is a clinically used antitumor antibiotic long thought to function therapeutically at the level of DNA cleavage. Recently, it has become clear that bleomycin can also cleave selected members of all major classes of RNA. Using the computer program COMPARE to search the database established by the Anticancer Drug Screening Program of the National Cancer Institute, a possible mechanism-based correlation was found between onconase, an antitumor ribonuclease currently being evaluated in phase III clinical trials, and the chemotherapeutic agent bleomycin. Following these observations, experimentation revealed that bleomycin caused tRNA cleavage and DNA-independent protein synthesis inhibition in rabbit reticulocyte lysate and when microinjected into Xenopus oocytes. The correlation of protein synthesis inhibition to the previously reported site-specific RNA cleavage caused by bleomycin supports the thesis that RNA cleavage may constitute an important element of the mechanism of action of bleomycin. 相似文献