排序方式: 共有23条查询结果,搜索用时 15 毫秒
11.
This work investigates entropy generation in a steady flow of viscous incompressible fluids between two infinite parallel porous plates. The fluid temperature variation is due to asymmetric heating of the porous plates as well as viscous dissipation. Two different physical situations are discussed with their entropy generation profiles: (i) Couette flow with suction/injection and (ii) pressure-driven Poiseuille flow with suction/injection. In each case, closed form expressions for entropy generation number and Bejan number are derived in dimensionless form by using the expressions for velocity and temperature which are derived by solving the resulting momentum and energy equations by the method of undetermined coefficient. The effect of the governing parameters on velocity, temperature, entropy generation and Bejan number are extensively discussed with the help of graphs. It is interesting to remark that entropy generation number increases with suction on one porous plate while it decreases on the other porous plate with injection. 相似文献
12.
Dr. Cecilia C. Russell Dr. Andrew Stevens Kelly A. Young Jennifer R. Baker Siobhann N. McCluskey Dr. Manouchehr Khazandi Hongfei Pi Dr. Abiodun Ogunniyi Dr. Stephen W. Page Prof. Darren J. Trott Prof. Adam McCluskey 《ChemistryOpen》2019,8(7):896-907
Robenidine (E)-N′-((E)-1-(4-chlorophenyl)ethylidene)-2-(1-(4-chlorophenyl)ethylidene)hydrazine-1-carboximidhydrazide displays methicillin-resistant Staphyoccoccus aureus (MRSA) and vancomycin-resistant Enterococci (VRE) MICs of 2 μg mL−1. Herein we describe the structure-activity relationship development of a novel series of guanidine to 2-aminopyrimidine isosteres that ameliorate the low levels of mammalian cytotoxicity in the lead compound while retaining good antibiotic activity. Removal of the 2-NH2 pyrimidine moiety renders these analogues inactive. Introduction of a central 2-NH2 triazine moiety saw a 10-fold activity reduction. Phenyl to cyclohexyl isosteres were inactive. The 4-BrPh and 4-CH3Ph with MIC values of 2 and 4 μg mL−1, against MRSA and VRE respectively, are promising candidates for future development. 相似文献
13.
Transition Metal Chemistry - Ligands bearing soft donors including N- and S- have found applications in selective metal recovery due to the ability to preferentially bind soft acceptors like Ag+.... 相似文献
14.
Sinozuko Hope Bika Abiodun Olagoke Adeniji Anthony Ifeanyi Okoh Omobola Oluranti Okoh 《Molecules (Basel, Switzerland)》2022,27(2)
In recent times, there has been a cumulative apprehension regarding organophosphate flame retardants (OPFRs) owing to their high manufacturing and usage after brominated flame retardants were strictly regulated and banned from being distributed and used in many countries. OPFRs are known as the main organic pollutants in the terrestrial and aquatic environment. They are very dangerous to humans, plants and animals. They are also carcinogenic and some have been implicated in neurodevelopmental and fertility challenges. OPFRs are distributed into the environment through a number of processes, including the usage, improper disposal and production of materials. The solid phase extraction (SPE) method is suggested for the extraction of OPFRs from water samples since it provides high quality recoveries ranging from 67% to 105% and relative standard deviations (RSDs) below 20%. In the same vein, microwave-assisted extraction (MAE) is highly advocated for the extraction of OPFRs from sediment/soil. Recoveries in the range of 78% to 105% and RSDs ranging from 3% to 8% have been reported. Hence, it is a faster method of extraction for solid samples and only demands a reduced amount of solvent, unlike other methods. The extract of OPFRs from various matrices is then followed by a clean-up of the extract using a silica gel packed column followed by the quantification of compounds by gas chromatography coupled with a mass spectrometer (GC–MS) or a flame ionization detector (GC-FID). In this paper, different analytical methods for the evaluation of OPFRs in different environmental samples are reviewed. The effects and toxicities of these contaminants on humans and other organisms are also discussed. 相似文献
15.
Basant K. Jha Abiodun O. Ajibade 《Communications in Nonlinear Science & Numerical Simulation》2012,17(4):1576-1587
This article investigates the natural convection flow of viscous incompressible fluid in a channel formed by two infinite vertical parallel plates. Fully developed laminar flow is considered in a vertical channel with steady-periodic temperature regime on the boundaries. The effect of internal heating by viscous dissipation is taken into consideration. Separating the velocity and temperature fields into steady and periodic parts, the resulting second order ordinary differential equations are solved to obtain the expressions for velocity, and temperature. The amplitudes and phases of temperature and velocity are also obtained as well as the rate of heat transfer and the skin-friction on the plates. In presence of viscous dissipation, fluids of relatively small Prandtl number has higher temperature than the channel plates and as such, heat is being transferred from the fluid to the plate. 相似文献
16.
17.
Christopher F. Harrington Abiodun A. Ojo Vivan W.-M. Lai Kenneth J. Reimer William R. Cullen 《应用有机金属化学》1997,11(12):931-940
The extraction and clean-up procedures developed to isolate the water-soluble arsenic species present in the marine macroalga Fucus distichus, from British Columbia, Canada, are described. The arsenic species were extracted into methanol and then subjected to gel-permeation and ion-exchange chromatography. Fractions high in arsenic were identified by using graphite furnace atomic absorption spectroscopy (GF-AAS), and further investigated by using high-performance liquid chromatography coupled to inductively coupled plasma–mass spectrometry (HPLC–ICP MS). By using different HPLC columns and mobile-phase conditions, the four major arsenic-containing compounds present in the macroalga were positively identified as arsenosugars; one minor compound remained unidentified. © 1997 John Wiley & Sons, Ltd. 相似文献
18.
Franziska Bendrath Zharylkasyn A. Abilov Abiodun Falodun Martin Hein Alexander Villinger Peter Langer 《Helvetica chimica acta》2013,96(12):2185-2190
5‐(2‐Cyanoethyl)‐1,1′‐biphenyl‐2‐carboxylates were prepared by regioselective formal [3+3] cyclocondensations of 1,3‐bis[(trimethylsilyl)oxy]buta‐1,3‐dienes. 相似文献
19.
Abiodun O. Eseola Wen Li Olalere G. Adeyemi Nelson O. Obi-Egbedi Joseph A.O. Woods 《Polyhedron》2010,29(8):1891-1901
Fourteen new organic molecules A1–A4, B1–B5, C1–C4 and D and a series of transition metal(II) complexes (Ni1–Ni9 and Pd1–Pd2b) were synthesized and studied in order to characterize the hemilability of 2-(1H-imidazol-2-yl)pyridine and 2-(oxazol-2-yl)pyridine ligands (A1–A4 = 2-R2-6-(4,5-diphenyl-1R1-imidazol-2-yl)pyridines, R1 = H or CH3, R2 = H or CH3; B1–B5 = 1-R2-2-(pyridin-2-yl)-1R1-phenanthro[9,10-d]imidazoles/oxazoles, R1 = H or CH3, R2 = H or CH3; C1–C4 = 2-(6-R2-pyridin-2-yl)-1H-imidazo/oxazo[4,5-f][1,10]phenanthrolines, R2 = H or CH3; D = 2-mesityl-1H-imidazo[4,5-f][1,10]phenanthroline). They were also used to study the substituent effects on the donor strengths as well as the coordination chemistries of the imidazole/oxazole fragments of the hemilabile ligands.All the observed protonation–deprotonation processes found within pH 1–14 media pertain to the imidazole or oxazole rings rather than the pyridyl Lewis bases. The donor characteristics of the imidazole/oxazole ring can be estimated by spectroscopic methods regardless of the presence of other strong N donor fragments. The oxazoles possessed notably lower donor strengths than the imidazoles. The electron-withdrawing influence and capacity to hinder the azole base donor strength of 4,5-azole substituents were found to be in the order phenanthrenyl (B series) > 4,5-diphenyl (A series) > phenanthrolinyl (C series). An X-ray structure of Ni5b gave evidence for solvent induced ligand reconstitution while the structure of Pd2b provided evidence for solvent induced metal–ligand bond disconnection.Interestingly, alkylation of 1H-imidazoles did not necessarily produce the anticipated push of electron density to the donor nitrogen. Furthermore, substituents on the 4,5-carbons of the azole ring were more important for tuning donor strength of the azole base. DFT calculations were employed to investigate the observed trends. It is believed that the information provided on substituent effects and trends in this family of ligands will be useful in the rational design and synthesis of desired azole-containing chelate ligands, tuning of donor properties and application of this family of ligands in inorganic architectural designs, template-directed coordination polymer preparations, mixed-ligand inorganic self-assemblies, etc. 相似文献
20.
Over time, stable isotopes have proven to be a useful tool in petroleum geochemistry. However, there is currently insufficient literature on stable isotope geochemistry of the organic elements within shales and crude oils in many petroleum systems around the world. As a result, this paper critically reviews the early and recent trends in stable isotope geochemistry of organic elements in shales and crude oils. The bulk and compound-specific stable isotopes of H, C, and S, as well as their uses as source facies, depositional environments, thermal maturity, geological age, and oil–oil and oil–source rock correlation studies, are all taken into account. The applications of the stable isotopes of H and C in gas exploration are also discussed. Then, the experimental and instrumental approaches to the stable isotopes of H, C, and S, are discussed. 相似文献