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671.
Maxwell equations are studied for a vacuum with nonzero conductivity coefficient. The loss of energy of a photon during its propagation through this vacuum is calculated and the nonzero rest mass of the photon is shown to be related to the conductivity coefficient of the vacuum. The dissipative mechanism is investigated considering a conformally fluctuating metric in the Einstein equation. Possible astrophysical consequences are discussed. 相似文献
672.
Summary A novel microanalytical method is described for the quantitative determination of nitro and nitroso groups in aliphatic, aromatic and nitro-arginine compounds.During decomposition by pyrolysis in a stream of oxygen, nitrogen oxides and decomposition products containing nitrogen were formed from the nitro and nitroso groups of the substances studied. These were transformed into nitrogen dioxide by a lead dioxide packing. The nitrogen dioxide was absorbed in acetic acid and determined iodometrically after deoxygenation with carbon dioxide. A statistical evaluation of the results for ten aplihatic and aromatic compounds and eight nitro-arginine compounds showed the error did not exceed ±0.3% absolute.
Mikrobestimmung von Nitro- und Nitrosogruppen in aliphatischen und aromatischen Verbindungen, besonders in Nitroargininderivaten
Zusammenfassung Zur quantitativen Bestimmung des Gehaltes an Nitro- und Nitrosogruppen in aliphatischen und aromatischen Verbindungen wird eine neue mikroanalytische Methode beschrieben.Während des pyrolytischen Zerfalls im Sauerstoffstrom bilden sich Stickstoffoxide und stickstoffhaltige Zersetzungsprodukte aus den Nitro- und Nitrosogruppen der untersuchten Substanzen. Diese werden in einem mit Bleidioxid gefüllten Röhrchen zu Stickstoffdioxid umgewandelt.Das in äquivalenter Menge gebildete Stickstoffdioxid wird absorbiert und jodometrisch bestimmt. Aufgrund der statistischen Auswertung ist die Genauigkeit der Resultate von 10 auf diese Weise bestimmten Verbindungen ±0,3%.相似文献
673.
The emission of electrons from a cold cathode upon application of a strong electric field is called field emission. Since the electrons must tunnel through the classically forbidden barrier outside the solid, field emission was one of the first confirmations of the new quantum theory of the 1920's.1 A field of tens of million volts per centimeter is required to obtain a reasonable current. In order to achieve such hgh fields at reasonable voltages, the cathode or emitter is usually etched to a very sharp point (~1,000 Å in radius). Therefore, several thousands of volts applied to the anode will produce the desired field. In 1937, Miiller2 developed what is known as the field emission microscope. The success of Miiller's microscope was a consequence of his realization that, if he produced a small hemispherically shaped tip that was thermally smoothed and cleaned, he would project a greatly magnified image of the spatial distribution of electrons tunneling from the emitter onto a fluorescent screen. Such a field emission pattern for clean tungsten is shown in Figure 1. The image on the screen is a nearly stereographic projection of the hemispherical end of the emitter. Because of its small size, the emitter is usually part of a single crystal and thus exposes all crystallographic orientations, so that individual crystal planes can be located and identified in the field emission pattern. The changes in the field emission pattern with exposure to adsorbed atoms or molecules have been used very successfully to study surface processes, such as diffusion, adsorption and desorption kinetics, or work function changes.3 相似文献
674.
The absorption of n-type gallium phosphide at 2.8 μm wavelength decreases at high light intensity. The saturation intensity is found to be 10 MW cm?2. 相似文献
675.
G. Kar 《International Journal of Theoretical Physics》1996,35(7):1279-1288
It is shown that in the double-slit experiment, which is an unsharp path determination if represented by a generalized Luder operation, the interference term in the probability expression exactly corresponds to one of the marginals representing an unsharp interference observable in the realistic joint measurement presented by Busch. A complicated arrangement is presented to show a nontrivial joint triple measurement for spin-1/2 observables 相似文献
676.
We discuss the effect of various classes of adsorbates on the surface states and resonances known to produce structure in the field emission energy distribution from (100) tungsten. We show that it is the overlayer geometry which is of importance in determining whether or not the resonances and concomittant FEED structure persist in the presence of adsorbates. In particular, a c(2 × 2) krypton overlayer destroys the structure while a (1 × 1) gold overlayer does not. 相似文献
677.
The application of spectral distribution theory for binding energy, spectra and occupancies using universal-sd interaction in (sd) shell and for Gamow-Teller and M1 strength sums in both (fp) and (sd)-shell is described. 相似文献
678.
679.
Noojaree Prasitpan Jayeshkumar N. Patel Philomen Z. De Croos Brenda L. Stockwell Parthasarathy Manavalan Leela Kar Michael E. Johnson Bruce L. Currie 《Journal of heterocyclic chemistry》1992,29(2):335-341
A series of N-1 or C-2 phenylalkyl substituted tryptophans and C-1 phenylalkyl substituted 3,4-dihydro-β-carbolines were prepared from the apropriate aniline, 1b or 1e , or tryptophan, 8 or 11 , by ring closure methods. None of the compounds prepared were more potent than 5-bromotryptophan (11) as inhibitors of sickle cell hemoglobin gelation. 相似文献
680.
Theoretical calculations of the field emission energy distributions from (111) Cu are presented. Both bulk and surface state contributions are considered, with the latter in particular being predicted to be predominant in part of the accessible energy region. The d-band contribution is also considered and shown to be small but clearly observable. 相似文献