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111.
112.
Detailed surface reaction mechanism in a three-way catalyst 总被引:1,自引:0,他引:1
113.
Rupankar PairaArindam Maity Shyamal MondalSubhendu Naskar Krishnendu B. SahuPritam Saha Abhijit HazraE. Padmanaban Sukdeb BanerjeeNirup B. Mondal 《Tetrahedron letters》2011,52(14):1653-1657
Basic alumina supported solvent-free one-pot synthesis of pyridine-fused polycyclic diazepaniums was achieved under microwave irradiation. The process was successfully extended to the synthesis of pyridine-fused bicyclic imidazolidiniums and tetrahydro-pyrimidiniums and also of tri- and tetracyclic diaza-heterocycle-fused quinoliniums. The dual characteristic of basic alumina, a solid support as well as a base, was successfully employed in the current investigation. The method emerged to be an effective route in terms of product yield, reaction time, and ease of purification and most importantly for environment friendly protocols. 相似文献
114.
Free energies of transfer (ΔGt) of RibonucleaseA (RNaseA) from water to aqueous solutions of urea (4 M, 6 M and 8 M), a protein denaturing solvent as well as ΔGt of RibonucleaseA, β‐Lactoglobulin, α‐Chymotripsin and ChymotrypsinogenA from water to aqueous glycerol (10%, 20%, 30% and 40%), a protein stabilizing solvent has been dissected into cavity term [ΔGt(cav)] and interaction term [ΔGt(int)]. The interaction free energy includes all types of interactions like hard‐soft, hydrogen bonding, electrostatic, etc. The cavity forming free energies have been calculated using the standard version of scaled particle theory (SPT) with well‐reported SPT parameters. It has been found that transfer free energies of cavity terms ΔGt(cav) for native protein from water to urea‐water and water to aqueous glycerol follow almost opposite trends. This primarily indicates there may be some correlation between cavity creation energies and protein denaturing and stabilizing ability of a solvent. The results are in agreement with those obtained from preferential binding coefficient studies in these media. 相似文献
115.
Samrat Chatterjee Ezio Venturino Subhendu Chakraborty Joydev Chattopadhyay 《Mathematical Methods in the Applied Sciences》2009,32(13):1738-1750
We show how the inclusion of the defense strategy by different species can alter the prediction of simple models. One of the defense strategy by the phytoplankton population against their grazer is the release of toxic chemicals. In turn the zooplankton population reduces there predation rate over toxin producing phytoplankton (TPP) to protect themselves from those toxic chemicals. Thus, when the level of toxicity is high, the grazing pressure is low and when the level of toxicity is low or when the toxin is absent, the grazing pressure is high. Here we have considered a TPP–zooplankton system where the rate of toxin liberation and the predation rate vary with zooplankton abundance. We observe that our proposed model has the potential to show different dynamical behaviour that are similar to that seen in real‐world situations. Further, we consider three different functional forms for the distribution of the toxins and compare them using latin hypercube sampling technique and found that the functional forms seem to have no effect in determining the final outcome of the system. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
116.
We present a new algorithm for continuation of limit cycles of autonomous systems as a system parameter is varied. The algorithm
works in phase space with an ordered set of points on the limit cycle, along with spline interpolation. Currently popular
algorithms in bifurcation analysis packages compute time-domain approximations of limit cycles using either shooting or collocation.
The present approach seems useful for continuation near saddle homoclinic points, where it encounters a corner while time-domain
methods essentially encounter a discontinuity (a relatively short period of rapid variation). Other phase space-based algorithms
use rescaled arclength in place of time, but subsequently resemble the time-domain methods. Compared to these, we introduce
additional freedom through a variable stretching of arclength based on local curvature, through the use of an auxiliary index-based
variable. Several numerical examples are presented. Comparisons with results from the popular package, MATCONT, are favorable
close to saddle homoclinic points. 相似文献
117.
118.
H R Morris A Chatterjee M Panico B N Green M A Almeida da Silva B S Hartley 《Rapid communications in mass spectrometry : RCM》1989,3(4):110-116
Two-sector linked-scan analysis of an unpurified proteolytic digest of a pyruvate decarboxylase enzyme (60,000 Da) has allowed the discovery and assignment of an amino-terminal post-translational modification and processing event. A difference in amino acid sequence from that predicted by a recently published nucleotide sequence has also been found. These results illustrate both the use and considerable potential of linked-scan methods for the analysis of complex biopolymer mixtures. 相似文献
119.
Alpha particle and deuteron impactL-subshell ionization cross-sections of Ar, Cu, Ge, Br, Zr and Ag have been computed using Vriens’ expressions for ionization
cross-section of atoms due to impact of heavy charged particles. The effects of Coulomb deflection of the projectile and increase
in binding of the target electron in the presence of projectile have been incorporated. Hartree-Fock velocity distributions
for the target electrons have been used in the present calculations. The simple binary encounter approximation model is found
to give results which are in satisfactory agreement with those obtained from experiments and from other theories. 相似文献
120.
The basic principle that has been used in the application of superheated drops in neutron spectrometry is its dependence of threshold energy of nucleation on temperature. In the present work, superheated drops of R114 suspended in a visco-elastic gel were irradiated at different temperatures by neutrons obtained from an 241Am–Be source. The temperature of the detector was converted to the energy of the incident neutrons following the method developed by us to unfold the neutron energy spectrum. The threshold energy obtained by us agrees well with other results obtained using monochromatic neutron sources, clearly demonstrating the validity of our principle of spectrometry. 相似文献