全文获取类型
收费全文 | 1237篇 |
免费 | 43篇 |
国内免费 | 4篇 |
专业分类
化学 | 861篇 |
晶体学 | 50篇 |
力学 | 20篇 |
数学 | 68篇 |
物理学 | 285篇 |
出版年
2023年 | 14篇 |
2022年 | 29篇 |
2021年 | 37篇 |
2020年 | 36篇 |
2019年 | 45篇 |
2018年 | 34篇 |
2017年 | 22篇 |
2016年 | 40篇 |
2015年 | 27篇 |
2014年 | 48篇 |
2013年 | 85篇 |
2012年 | 77篇 |
2011年 | 71篇 |
2010年 | 53篇 |
2009年 | 49篇 |
2008年 | 72篇 |
2007年 | 53篇 |
2006年 | 45篇 |
2005年 | 34篇 |
2004年 | 30篇 |
2003年 | 26篇 |
2002年 | 21篇 |
2001年 | 29篇 |
2000年 | 46篇 |
1999年 | 58篇 |
1998年 | 14篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 6篇 |
1989年 | 7篇 |
1987年 | 5篇 |
1986年 | 8篇 |
1985年 | 14篇 |
1984年 | 8篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 8篇 |
1977年 | 12篇 |
1976年 | 5篇 |
1975年 | 4篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1972年 | 4篇 |
排序方式: 共有1284条查询结果,搜索用时 15 毫秒
31.
K. A. Sree Raj Afsal S. Shajahan Dr. Brahmananda Chakraborty Dr. Chandra Sekhar Rout 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6662-6669
In this work, the ternary hybrid structure VSe2/SWCNTs/rGO is reported for supercapacitor applications. The ternary composite exhibits a high specific capacitance of 450 F g−1 in a symmetric cell configuration, with maximum energy density of 131.4 Wh kg−1 and power density of 27.49 kW kg−1. The ternary hybrid also shows a cyclic stability of 91 % after 5000 cycles. Extensive density functional theory (DFT) simulations on the structure as well as on the electronic properties of the binary hybrid structure VSe2/SWCNTs and the ternary hybrid structure VSe2/SWCNTs/rGO have been carried out. Due to a synergic effect, there are enhanced density of states near the Fermi level and higher quantum capacitance for the hybrid ternary structure compared to VSe2/SWCNTs, leading to higher energy and power density for VSe2/SWCNTs/rGO, supporting our experimental observation. Computed diffusion energy barrier of electrolyte ions (K+) predicts that ions move faster in the ternary structure, providing higher charge storage performance. 相似文献
32.
Dr. Chandan Kumar Karan Sourav Mallick Prof. Dr. C. Retna Raj Prof. Dr. Manish Bhattacharjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(65):14775-14779
A zinc containing metal–organic gel (Zn-MOG) with embedded free ions, which exhibits self-healing properties, has been synthesized for application in supercapacitors. The activated carbon-based flexible supercapacitor device with the MOG electrolyte has a broad potential window of 2.1 V, with high retention of specific capacitance compared to the traditional polyvinyl alcohol (PVA)-based gel. The Zn-MOG does not require an additional electrolyte. The sodium and sulphate ions embedded in the MOG are sufficient enough for the charge storage. 相似文献
33.
We present a seventh order iterative method for solving systems of nonlinear equations. The algorithm is derivative free per full iteration. A comparison between the computational efficiencies of proposed technique and existing techniques of similar nature is made. It is shown that for large system the new method is more efficient. The performance is tested through numerical experimentation which also confirms the theoretical results. 相似文献
34.
Amit Vijay Sasane Dr. Antony Sekar Kulandai Raj Tzu-Hsuan Chao Dr. Mu-Jeng Chen Dr. Rai-Shung Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(70):16932-16938
Gold-catalyzed oxidations of propargyl alcohols with nitrones by using a P(tBu)2(o-biphenyl)Au+ catalyst, afforded bicyclic annulation products from the Mannich reactions of gold enolates. The same reactions of propargyl amines with nitrones by using the same gold catalyst gave distinct oxoarylation products. Our DFT calculations indicate that oxidation of propargyl alcohols with nitrones by using electron-rich gold catalysts lead only to gold carbenes, which can generate gold enolates or oxoarylation intermediates with enolate species having a barrier smaller than that of oxoarylation species. 相似文献
35.
36.
Bianchi Type-III cosmological models for perfect fluid distribution with time dependent displacement field in the framework
of Lyra geometry are investigated. To get the deterministic model of the universe, we have assumed two conditions (i) shear
(σ) is proportional to the expansion (θ). This leads to B=C
n
where B and C are metric potentials and n is a constant. (ii) Universe is filled with barotropic fluid distribution which leads to p=γ
ρ, 0≤γ≤1, p being isotropic pressure and ρ the energy density. The physical and geometrical aspects of the model with a special case and singularities in the models
are also discussed. 相似文献
37.
38.
K. K. Vijaya Raj B. Narayana 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):1971-1981
A smooth one-step synthesis of 2-(2-bromo-5-methoxyphenyl)-5-(3-arylidene)-1,3-thiazolo[3,2-b]-1,2,4-triazol-6-(5H)-ones (4a–n) is described. The newly prepared compounds are characterized by analytical and IR, 1 H NMR, 13 C NMR, and FABMS spectral analysis. A few compounds are screened for anticonvulsant activity. Compounds 4i and 4n exhibit promising anticonvulsant activity and are recommended for further studies. 相似文献
39.
A. S. Singha Ashish Guleria Raj K. Rana 《International Journal of Polymer Analysis and Characterization》2013,18(6):451-463
The present study explores surface modification of Abelmoschus esculentus by graft copolymerization reaction using acrylonitrile as a monomer and ascorbic acid/H2O2 as a redox initiator. Further, polyacrylonitrile grafted fibers were treated with hydroxylamine to convert the nitrile group of the grafted fiber into the amidoxime group to enhance adsorption of copper ions from wastewater. The graft copolymers and amidoximated fibers were characterized by FT-IR and FE-SEM. The effects of physicochemical parameters such as pH of the solution, initial metal ion concentration, and time on Cu(II) adsorption were studied to optimize condition for maximum adsorption. In addition, Langmuir, Freundlich, and Tempkin models were applied to describe the adsorption isotherm of Cu2+ ions. 相似文献
40.
Rinki Bhadra Vidya Nand Singh Bodh Raj Mehta Pranayee Datta 《Journal of Dispersion Science and Technology》2013,34(9):1202-1207
ZnO nanocrystals are synthesized using the quenching method. The properties of the grown nanocrystals are studied using ultraviolet-vis spectroscopy, x-ray diffraction, photoluminescence, electron diffraction, energy dispersive x-ray spectroscopy, and high resolution transmission electron microscopy. Current-voltage characteristics of the prepared samples are studied for investigating the possible application of the samples as switch and memristor. 相似文献