On the bremsstrahlung background correction to the high-energy Compton spectroscopy

methodology for bremsstrahlung (BS) background correction to extract a true Compton profile in high-energy Compton scattering experiments is presented. The BS background profiles for Hg, computed within the Born approximation, are estimated for different values of incident energy. It is seen for the first time that the BS background contribution in high-energy Compton profile experiments like those employing third generation synchrotron radiation sources comes out to be significant and non-linear. Further, it is found that the incorporation of BS correction in data reduction of such an experiment performed on Hg at 662 keV energy helps in reconciliation of theory and experiment.     

A study of pion absorption by16O using realistic interactions—I. Twonucleon emission following bound-pion absorption

Matrix element of the Galilean invariant non-relativistic reduction of the pseudoscalar-pseudovector interaction has been calculated assuming the reaction to be a direct process with boundπ ⁻ being absorbed by a correlated pair of nucleons. The Hartree-Fock wavefunctions obtained with the unitary-model-operator approach starting with the realistic nucleon-nucleon interaction have been used forπ-capturing nucleon pair in the initial state. The calculations have been done with and without antisymmetrising the initial state wavefunction of the pion absorbing pair. For the final state nucleon-nucleon interaction has been taken into account. The strongπ-nucleus interaction together with the Coulomb interaction with the finite nuclear size on the bound pion wavefunction are taken into account. Angular distributions of the emitted nucleon-pair, the branching ratios and the total absorption rates are calculated for¹⁶O with and without antisymmetrisation effect. The calculated results are compared with the experimental and other theoretical work.     

Conservation of channel spin in transfer reactions

The conservation of channel spin implying that the spin of the initial bound pair coupled to that of the initial free particle should result in the same channel spin as the spin of the final bound pair coupled to the spin of the final free particle, follows as a consequence of three-body theory of transfer reactions with the assumption of separability of two-bodyt-matrix. To test the validity of this principle we look at the experimental data on stripping reactions on even-even nuclei. We find that although reactions to channels not conforming to channel spin conservation are not altogether ruled out, the cross-sections of reactions violating channel spin conservation are much smaller than those conforming to channel spin conservation.     

A new synthesis of aldehydes from acids via reduction of N-acyl saccharins using sodium dihydro bis-(2-methoxy-ethoxy) aluminate

Synthesis of certain aldehydes from the carboxylic acids has been carried by reduction of the corresponding N-acyl saccharins using SDA. The N-acyl saccharins are easily prepared by reaction of an acid with γ-saccharin chloride, which can be used for the next step of reduction without isolation and purification. This provides a convenient and one step synthesis of aldehydes by combining the two reactions, viz., preparation of the N-acyl compound and its reduction. The method has been successfully applied for the reduction of aliphatic, alicyclic, aromatic, and a α,β-unsaturated acids to the corresponding aldehydes and the yields obtained are quite satisfactory.     

Determination of sulphanilamides with alkyl nitrites by a potentiometric method

A potentiometric titration with alkye nitrite solutions is described for the determination of various sulpha, drugs.     

Radiation effects in samarium-doped calcium fluoride

A study was conducted of the effects of gamma radiation on samarium (Sm)-doped calcium flouride (CaF₂) crystals. Optical absorption measurements indicate that many of the Sm³⁺ ions are converted to Sm²⁺ during irradiation. Heavy doses of 10⁶ rad also modify the trapping structures and enhance certain defects within the crystals. A comparison is provided between unirradiated and heavily irradiated CaF₂ crystals with three Sm concentrations: 0.01, 0.1, and 1.0 molar-percent. Thermoluminescence measurements indicate that the crystals with high Sm content provide less luminescence and that the activation energy is less than seen in the 0.01 molar-percent Sm crystals.