Self-connected horizontal silicon nanowire field effect transistor

We propose a technique to fabricate self-connected horizontal Si nanowire (NW) field effect transistors (FETs) by a self-assembly mechanism. We show direct growth of Si NWs between two predefined metallic electrodes along the SiO₂ gate oxide using the vapour–liquid–solid (VLS) growth mode. In our approach, the gold catalyst layer is covered by the contact metal, giving rise to selective and localized catalytic activity and growth of NWs from the gold edges. The diameter of the NWs can be adjusted by the thickness of the catalyst layer. Using such a process, we demonstrate field effect operation on the conductivity of a non-intentionally doped 20 nm diameter Si NW. This technique can be implemented in three dimensions, paving the way to three-dimensionalD integration using vertical stacks of self-connected FETs.     

Ionization and electroreduction of some benzthiazin-4-one azodyes

pKa values of a series of the titled compounds (2 a–g) together with a model compound3 have been determined spectrophotometrically in alcoholic buffered media. These values were correlated to different sets. The polarographic behaviour of the parent2 a and its nitro derivative2 g was studied in detail. The obtained data showed that2 a is reduced via a 2-electron process to the corresponding hydrazo from which was stabilized through hydrogen bonding.

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Ionisierung und Elektroreduktion einiger Benzthiazin-4-on-Azofarbstoffe

Zusammenfassung Es wurden diepKa-Werte einer Serie der Titelverbindungen (2 a–g) zusammen mit einer Modellverbindung3 spektrophotometrisch in alkoholischer gepufferter Lösung bestimmt. Diese Werte wurden mit verschiedenen Sets von -Werten korreliert. Das polarographische Verhalten der Stammverbindung2 a und deren Nitroderivat2 g wurde im Detail untersucht. Die Daten zeigen, daß2 a über einen Zweielektronenprozeß zur entsprechenden Hydrazo-Verbindung reduziert wird, die durch Wasserstoffbrücken stabilisiert ist.

     

Reactions with heterocyclic diazonium salts. Synthesis of several new azolylhydrazones

Several new stable azolylhydrazones could be synthesized via coupling of diazotised cycliuc amidines with active methylene reagents. The obtained compounds were utilised for synthesis of several, otherwise not readily accessible fused azoles.     

Lagrangian formulation of the Schrödinger equation

We recast the Schrödinger equation in a new Lagrangian formulation. The equation is —i?dψ (x,t)/dt = Lψ (x,t), whereL is the Lagrangian operator. Expressions forL and ford/dt — ⊥ are derived in terms of coordinate and momentum operators.     

Blue emission from cysteine ester passivated cadmium sulfide nanoclusters

A one-pot synthesis is reported of water-soluble cadmium sulfide nanoclusters capped with cysteine ester, with an average size of 2.0 nm and fluorescing in the blue region, establishing the possibility of using these as fluorescent biological probes.     

NiFe2O4 as a magnetically recoverable nanocatalyst for odourless C–S bond formation via the cleavage of C–O bond in the presence of S8 under mild and green conditions

We present green methodologies for one‐pot and odourless syntheses of unsymmetric and symmetric diaryl sulfides via C─O bond activation using NiFe₂O₄ magnetic nanoparticles as a reusable heterogeneous nanocatalyst. The synthesis of unsymmetric sulfides is performed using the cross‐coupling reaction of phenolic esters such as acetates, triflates and tosylates with arylboronic acid/S₈ or triphenyltin chloride/S₈ as thiolating agents in the presence of base and NiFe₂O₄ magnetic nanoparticles as a catalyst in poly(ethylene glycol) as solvent at 60–85°C. Also, the synthesis of symmetric diaryl sulfides from phenolic compounds using S₈ as the sulfur source and NiFe₂O₄ as catalyst in dimethylformamide at 120°C is described. Using these protocols, the syntheses of various unsymmetric and symmetric sulfides become easier than using the available protocols due to the use of a magnetically reusable bimetallic nanocatalyst and avoiding the use of thiols and aryl halides.     

Chemical Constituents of Beilschmiedia maingayi

Chemistry of Natural Compounds -     

Synthesis and Antiplasmodial Activity of Bisindolylcyclobutenediones

Malaria is one of the most dangerous infectious diseases. Because the causative Plasmodium parasites have developed resistances against virtually all established antimalarial drugs, novel antiplasmodial agents are required. In order to target plasmodial kinases, novel N-unsubstituted bisindolylcyclobutenediones were designed as analogs to the kinase inhibitory bisindolylmaleimides. Molecular docking experiments produced favorable poses of the unsubstituted bisindolylcyclobutenedione in the ATP binding pocket of various plasmodial protein kinases. The synthesis of the title compounds was accomplished by sequential Friedel-Crafts acylation procedures. In vitro screening of the new compounds against transgenic NF54-luc P. falciparum parasites revealed a set of derivatives with submicromolar activity, of which some displayed a reasonable selectivity profile against a human cell line. Although the molecular docking studies suggested the plasmodial protein kinase PfGSK-3 as the putative biological target, the title compounds failed to inhibit the isolated enzyme in vitro. As selective submicromolar antiplasmodial agents, the N-unsubstituted bisindolylcyclobutenediones are promising starting structures in the search for antimalarial drugs, albeit for a rational development, the biological target addressed by these compounds has yet to be identified.     

Spray algorithm without interface construction

This research is aimed to create a new and robust family of convective schemes to capture the interface between the dispersed and the carrier phases in a spray without the need to build up the interface boundary. The selection of the Weighted Average Flux (WAF) scheme is due to this scheme being designed to deal with random flux scheme which is second-order accurate in space and time. The convective flux in each cell face utilizes the WAF scheme blended with Switching Technique for Advection and Capturing of Surfaces (STACS) scheme for high resolution flux limiters. In the next step, the high resolution scheme is blended with the WAF scheme to provide the sharpness and boundedness of the interface by using switching strategy. In this work, the Eulerian–Eulerian framework of non-reactive turbulent spray is set in terms of theoretical proposed methodology namely spray moments of drop size distribution, presented by Beck and Watkins [1]. The computational spray model avoids the need to segregate the local droplet number distribution into parcels of identical droplets. The proposed scheme is tested on capturing the spray edges in modelling hollow cone sprays without need to reconstruct two-phase interface. A test is made on simple comparison between TVD scheme and WAF scheme using the same flux limiter on convective flow hollow cone spray. Results show the WAF scheme gives a better prediction than TVD scheme. The only way to check the accuracy of the presented models is by evaluating the spray sheet thickness.