全文获取类型
收费全文 | 166篇 |
免费 | 11篇 |
国内免费 | 3篇 |
专业分类
化学 | 149篇 |
晶体学 | 3篇 |
力学 | 5篇 |
数学 | 8篇 |
物理学 | 15篇 |
出版年
2023年 | 1篇 |
2022年 | 23篇 |
2021年 | 13篇 |
2020年 | 11篇 |
2019年 | 8篇 |
2018年 | 11篇 |
2017年 | 10篇 |
2016年 | 8篇 |
2015年 | 8篇 |
2014年 | 5篇 |
2013年 | 8篇 |
2012年 | 19篇 |
2011年 | 6篇 |
2010年 | 5篇 |
2009年 | 5篇 |
2008年 | 4篇 |
2007年 | 3篇 |
2006年 | 1篇 |
2005年 | 1篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 1篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有180条查询结果,搜索用时 15 毫秒
101.
Three different long‐chain branch (LCB) formation mechanisms for ethylene polymerization with metallocenes in solution polymerization semi‐batch and continuous stirred‐tank reactors are modeled to predict the microstructure of the resulting polymer. The three mechanisms are terminal branching, C–H bond activation, and intramolecular random incorporation. Selected polymerization parameters are varied to observe how each mechanism affects polymer microstructure. Increasing the ethylene concentration during semi‐batch polymerization reduces the LCB frequency of polymers made with the terminal branching and intramolecular mechanisms, but has no effect on those made with the C–H bond activation mechanism, which disagrees with most previous data published in the literature. The intramolecular mechanism predicts that LCB frequencies hardly depend on polymerization time or ethylene conversion, which also disagrees with the published experimental data for these systems. For continuous polymerization reactors, experimental data relating polydispersity to LCB frequency can be well described with the terminal branching mechanism, but both C–H bond activation and intramolecular models fail to describe this experimental relationship. Therefore, detailed simulations confirm that the terminal branching mechanism is indeed the most likely mechanism for LCB formation when ethylene is polymerized with single‐site coordination catalysts such as metallocenes in solution polymerization reactors. 相似文献
102.
103.
104.
Amayreh Mousa Alsharaa Abdulnaser Khaled Alhooshani Abdulrahman Al-Arfaj 《International journal of environmental analytical chemistry》2015,95(8):744-753
In this study a method of flow-assisted automated solid-phase microextraction (FA-SPME) was developed for the determination of organic pollutants in aqueous samples. A CTC Combi-PAL autosampler coupled with gas chromatography–mass spectrometry (GC–MS) was used to automate the entire extraction process. In this method, the SPME fibre was exposed to 100 mL of sample in a direct immersion mode for 10 min. After exposure, the fibre was desorbed at the injection port of GC–MS. To demonstrate the applicability of FA-SPME, chloroethers were selected as model compounds. Good linear correlation was found over a concentration range of 0.5–100 µg/L. The detection limits of the method were determined between 0.02 and 0.05 µg/L with the coefficients of determination (R2) from 0.9980 to 0.9996. The relative standard deviations (RSDs) of the FA-SPME for three sequential FA-SPME analyses were determined to be in the range between 1.2% and 6.2% (n = 3). The applicability of the method was assessed by means of recovery studies and satisfactory values for all compounds were obtained. This optimised method was used in the analysis of water and human urine samples to show the matrix effect on FA-SPME. This FA-SPME/GC–MS is substantially faster and suitable for the routine continuous flow-mode environmental monitoring applications. 相似文献
105.
Leila Tajik Abdulrahman Bahrami Alireza Ghiasvand Farshid Ghorbani Shahna 《Chemical Papers》2017,71(10):1829-1838
Excessive and uncontrolled exposures of the workers to benzene, toluene, ethylbenzene and xylene (BTEX) have currently raised great concerns among industrial hygienist all over the world. Therefore, the effective monitoring of such exposures is assumed to be of prime importance. A cold fiber solid-phase microextraction device based on a cooling capsule as a cooling unit and CO2 as a coolant was applied to quantitatively analyze BTEX in aqueous samples. A gas chromatography with flame ionization detection was recruited to analyze the target analytes, which had been identified according to their retention times. Several factors such as coating temperature, extraction time and temperature, sample volume and sodium content were optimized. Two modes of extraction, i.e., headspace (HS) and headspace cold fiber (HS-CF) in SPME, were investigated and compared under optimized conditions. The results revealed that HS-CF-SPME has the most appropriate outcome for the extraction of BTEX from aqueous samples. Under the optimized conditions, the calibration curves were linear within the range of 0.2–500 ng ml?1 and the detection limits were between 0.02 and 0.07 ng ml?1.The intraday relative standard deviations was lower than about 10%. The method was successfully applied to the determination of BTEX in urine samples with good recovery. 相似文献
106.
Saeed Ahmad Mohammed Fettouhi Thierry Roisnel Mshari A. Alotaibi Abdulrahman I. Alharthi Muhammad Riaz Malik 《Journal of Coordination Chemistry》2017,70(21):3692-3701
Cadmium(II) complexes, catena-poly[bis(thiocyanato-κN)bis(N-methylthiourea)cadmium(II)], [Cd(Metu)2(NCS)2]n (1) and dicyanidobis(N-methylthiourea)cadmium(II), [Cd(Metu)2(CN)2] (2) were prepared and their structures were determined by single crystal X-ray analysis. In 1, the cadmium(II) ion is bound to four sulfur atoms of bridging Metu ligands and two nitrogen atoms of thiocyanate adopting a distorted octahedral environment. In 2, the geometry around cadmium is distorted tetrahedral attained by two cyanide ions and two methylthiourea molecules bound through the sulfur atoms. The crystal structures of both complexes show intra and intermolecular hydrogen bonding interactions. The complexes were also characterized by IR and NMR spectroscopy and the spectroscopic data were discussed in terms of the nature of bonding. 相似文献
107.
Beenish Khanzada Nosheen Akhtar Mohammad K. Okla Saud A. Alamri Abdulrahman Al-Hashimi Muhammad Waleed Baig Samina Rubnawaz Hamada AbdElgawad Abdurahman H. Hirad Ihsan-Ul Haq Bushra Mirza 《Molecules (Basel, Switzerland)》2021,26(23)
A worldwide increase in the incidence of fungal infections, emergence of new fungal strains, and antifungal resistance to commercially available antibiotics indicate the need to investigate new treatment options for fungal diseases. Therefore, the interest in exploring the antifungal activity of medicinal plants has now been increased to discover phyto-therapeutics in replacement to conventional antifungal drugs. The study was conducted to explore and identify the mechanism of action of antifungal agents of edible plants, including Cinnamomum zeylanicum, Cinnamomum tamala, Amomum subulatum, Trigonella foenumgraecum, Mentha piperita, Coriandrum sativum, Lactuca sativa, and Brassica oleraceae var. italica. The antifungal potential was assessed via the disc diffusion method and, subsequently, the extracts were assessed for phytochemicals and total antioxidant activity. Potent polyphenols were detected using high-performance liquid chromatography (HPLC) and antifungal mechanism of action was evaluated in silico. Cinnamomum zeylanicum exhibited antifungal activity against all the tested strains while all plant extracts showed antifungal activity against Fusarium solani. Rutin, kaempferol, and quercetin were identified as common polyphenols. In silico studies showed that rutin displayed the greatest affinity with binding pocket of fungal 14-alpha demethylase and nucleoside diphosphokinase with the binding affinity (Kd, −9.4 and −8.9, respectively), as compared to terbinafine. Results indicated that Cinnamomum zeylanicum and Cinnamomum tamala exert their antifungal effect possibly due to kaempferol and rutin, respectively, or possibly by inhibition of nucleoside diphosphokinase (NDK) and 14-alpha demethylase (CYP51), while Amomum subulatum and Trigonella foenum graecum might exhibit antifungal potential due to quercetin. Overall, the study demonstrates that plant-derived products have a high potential to control fungal infections. 相似文献
108.
109.
Abdulrahman H. Bajodah 《Nonlinear dynamics》2008,53(4):321-343
A new approach for feedback linearization of attitude dynamics for rigid gas jet-actuated spacecraft control is introduced.
The approach is aimed at providing global feedback linearization of the spacecraft dynamics while realizing a prescribed linear
attitude deviation dynamics. The methodology is based on nonuniqueness representation of underdetermined linear algebraic
equations solution via nullspace parametrization using generalized inversion. The procedure is to prespecify a stable second-order
linear time-invariant differential equation in a norm measure of the spacecraft attitude variables deviations from their desired
values. The evaluation of this equation along the trajectories defined by the spacecraft equations of motion yields a linear
relation in the control variables. These control variables can be solved by utilizing the Moore–Penrose generalized inverse
of the involved controls coefficient row vector. The resulting control law consists of auxiliary and particular parts, residing in the nullspace of the controls
coefficient and the range space of its generalized inverse, respectively. The free null-control vector in the auxiliary part is projected onto the controls coefficient nullspace by a nullprojection matrix, and is designed to
yield exponentially stable spacecraft internal dynamics, and singularly perturbed feedback linearization of the spacecraft attitude dynamics. The feedback control design utilizes the concept of damped generalized inverse to limit the growth of the Moore–Penrose generalized inverse, in addition to the concepts of singularly perturbed controls coefficient nullprojection and damped controls coefficient nullprojection to disencumber the nullprojection matrix from its rank deficiency, and to enhance the closed loop control system performance.
The methodology yields desired linear attitude deviation dynamics realization with globally uniformly ultimately bounded trajectory
tracking errors, and reveals a tradeoff between trajectory tracking accuracy and damped generalized inverse stability. The
paper bridges a gap between the nonlinear control problem applied to spacecraft dynamics and some of the basic generalized
inversion-related analytical dynamics principles. 相似文献
110.
孙健 王加升 冯秀娟 Yoshinori Yamamoto Abdulrahman I. Almansour Natarajan Arumugam Raju Suresh Kumar 包明 《催化学报》2018,39(7):1258-1262
CO2是廉价的C1源,同时具有无毒、储量丰富的优点, 符合绿色化学发展要求. 利用 CO2构筑新的 C–C 键是化学固定CO2的重要方法. Β,γ-不饱和酯类结构单元是许多生物活性分子的重要组成部分, 经由双π-烯丙基钯中间体与 CO2反应, 合成新的β,γ-不饱和酯类化合物, 具有重要意义. CO2与有机硼化合物的羧化反应已有报道, 有机硼化合物具有低毒、对水不敏感等优点. 但是已报道的羧化 Suzuki 偶联反应存在诸多缺点: (1) 需要使用含膦或者氮杂环卡宾配体的催化剂, 而这些催化剂的制备过程使前期实验步骤变得冗长, 同时反应液的酸化后处理过程也会造成环境污染; (2) 有机硼试剂的官能团兼容范围窄, 限制了底物范围的拓展. 本课题组以原位生成的纳米钯粒子为催化剂, 在 CO2存在的温和条件下, 高效实现了苄氯与烯丙基硼酸频哪醇酯的羧化 Suzuki 偶联反应. 反应过程中无其它配体加入, 反应结束后不需要酸化或酯化的后处理过程. 该反应将具有广泛的官能团兼容性.本文以 TBAB 稳定的纳米钯粒子为催化剂, 在温和条件下, 实现了氯甲基芳香化合物、烯丙基硼酸频哪醇酯和 CO2的三组分羧化 Suzuki 偶联反应. 最佳反应条件为: Pd(acac)2(5 mol%)、TBAB (0.7 mmol, 1.4 equiv.)、KF (1 mmol, 2.0 equiv.)、苄基卤代物 (0.5 mmol)、烯丙基硼酸频哪醇酯 (0.6 mmol, 1.2 equiv.)、CO2(2.0 Mpa)、溶剂 THF (5 mL), 50 oC 反应 24 h. 在最佳反应条件下, 苯环、萘环以及杂芳环的氯甲基化合物均可发生该羧化反应. 苯环上取代基的位置对产物的收率有影响. 当使用 1-溴甲基萘作为底物时反应也能够发生, 收率与 1-氯甲基萘作为底物时的收率相当. 与已报道有机硼试剂的羧化反应相比, 该反应体系无需加入配体, 原位生成了纳米钯粒子, 避免了催化剂或者配体的复杂制备过程. 该反应中, 氟离子的存在是必要的, 对烯丙基硼酸频哪醇酯具有活化作用. 相似文献