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991.
Let G be a fnite group and P a subgroup of order 3. In this paper we proved some results about the soluble subgroups generated by three conjugates of P and we use these results to produce some properties of the group G. 相似文献
992.
马鸿文 《中国科学B辑(英文版)》1989,(10)
A set of 201 experimental data on solubility of sulfur in silicate melts was collectedfrom literature to formulate the changes of sulfur solubility as a function of bulk compo-sition of the melts and pressure, temperature, and the fugacity of oxygen and sulfur. Aregular solution model and a polynomial function have been put forward, from which sol-ubility of sulfur in natural silicate magmas can be estimated. Synthetic application of twomethods makes it possible to evaluate activity of FeS in a silicate melt, which will be po-tentially valuable for predicting immiscibility of sulfide liquid in magmatic processes. 相似文献
993.
In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Lett. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A1П, v = 3) with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment. 相似文献
994.
二阶导数荧光分光光度法同时测定色氨酸和酪氨酸 总被引:1,自引:0,他引:1
本文描述了用二阶导数荧光光度法同时测定色氨酸和酪氨酸.在pH 7.4的条件下,用221 nm作为激发波长,记录色氨酸和酪氨酸的发射光谱,并进行二阶导数处理.色氨酸在318 nm处,酪氨酸在283 nm处,二阶导数峰高与浓度成线性关系.色氨酸工作曲线的线性回归方程为c=0.000 7H-0.004,r=0.996 4,线性范围为0.004到0.200 μg.mL-1.酪氨酸工作曲线的线性回归方程为c=0.001 2H-0.004 0,r=0.997 1.线性范围为0.002到0.250 μg.mL-1.实验了pH、温度和干扰离子对测定的影响,测定了苹果中的色氨酸和酪氨酸的含量,回收率分别为(92.0~104.0)%和(98.70~102.0)%,相对标准偏差分别为3.5%和2.8%. 相似文献
995.
The excitation spectra in the wavelength range of 19—40 nm for highly ionized sulphur ions were measured by using the beam-foil
method at the Heavy lon Research Facility in Lanzhou. In this experiment, more than 30 spectral lines were observed, which
belonged to the transitions of the excitation energy levels for highly ionized SX—SXV ions, and 5 new lines were determined.
The experimental results were compared with those from other experiments and theoretical calculations. 相似文献
996.
Takayoshi Kimura Sekai Iwama Satoko Kido Mohammad Abdullah Khan 《The Journal of chemical thermodynamics》2009,41(10):1170-1177
Enthalpies of mixing and the densities of ethanol solution of R- and S-enantiomers of camphor, 10-camphorsulfonamide, 10-camphorsulfonic acid, camphorquinone, and 10-camphorsulfonyl chloride have been measured for a wide range of mole fractions of heterochiral components at 298.15 K. Enthalpies of mixing were exothermic for all concentrations and heterochiral solutions were more stable than each of the homochiral solutions. Enthalpic stabilization of mixing of heterochiral solutions was increased with a decreasing concentration of all the camphor derivatives measured. The sequence of enthalpic stabilization on mixing was 10-camphorsulfonyl chloride, 10-camphorsulfonic acid, 10-camphorsulfonamide, camphor, and camphorquinone. Apparent molar volumes were determined and excess volumes of mixing of heterochiral solutions were small and negative. Enthalpic stabilizations were found to be dependent on dipole–dipole interaction between solutes and solvents. 相似文献
997.
998.
Synthesis and Characterization of A Novel Cholesteric Liquid Crystalline Containing Carboxyl Group 总被引:1,自引:0,他引:1
JingMA YingNanXUAN YongHUANG 《中国化学快报》2005,16(1):127-130
A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoxl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR.CNMR,HNMR,POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour. 相似文献
1000.