Oxalic acid as a simple and efficient organocatalyst for three-component synthesis ofα-amino nitriles

A simple,efficient,and general method has been developed for the synthesis ofα-amino nitriles.Oxalic acid as a BrФnsted acid promotes the addition of TMSCN to various imines(generated in situ).     

Application of Fourier transform infrared (FT-IR) spectroscopy combined with chemometrics for authentication of cod-liver oil

Some vegetable oils such as canola (CaO), corn (CO), soybean (SO), and walnut (WO) oils have similar color with cod liver oil (CLO), therefore, the presence of these oils was difficult to detect using naked eye. For this reason, Fourier transform infrared (FTIR) spectroscopy using horizontal attenuated total reflectance (HATR) as sampling accessory and in the combination with chemometrics was developed for detection and quantification of these vegetable oils as adulterants in CLO. The quantification of vegetable oils was carried out by using multivariate calibrations of partial least squares (PLS) and principle component regression (PCR), while the classification between pure CLO and CLOs adulterated with CaO, CO, SO, and WO was performed using discriminant analysis (DA). PLS with FTIR normal spectra was more suitable compared with PCR for quantification purposes with coefficient of determination (R²) higher than 0.99 and root mean square error of calibration (RMSEC) in the range of 0.04-0.82% (v/v). The PLS model was further used to predict the levels of these vegetable oils in independent samples for validation/prediction purpose. The root mean square error of prediction (RMSEP) values obtained were of 1.75% (v/v) (CaO), 1.39% (v/v) (CO), 1.35% (v/v) (SO), and 1.37% (v/v) (WO), respectively. The classification using DA revealed that the developed method can classify CLO and that mixed with these vegetable oils using 9 principal components.     

Synthesis and characterization of polydimethylsiloxane-cyanopropyltriethoxysilane-derived hybrid coating for stir bar sorptive extraction

New inorganic–organic hybrid materials were synthesized by hydrolysis and condensation of cyanopropyltriethoxysilane (CNPrTEOS) and polydimethylsiloxane (PDMS) in the presence of hydrochloric acid, HCl catalyst and methyl trimethylmethoxysilane as precursor via sol–gel method and coated on glass encased stir bar for use in stir bar sorptive extraction (SBSE). The cyano part provides polar moiety, which may improve the extraction of polar analytes. The physico-chemical properties and extraction ability of PDMS-CNPrTEOS-derived hybrid coatings can be fine tuned via manipulation of solvents (tetrahydrofuran (THF)-based and dichloromethane (DCM)-based) and PDMS-CNPrTEOS molar concentrations during the sol synthesis. Clear, homogeneous PDMS-CNPrTEOS-derived hybrid sols were obtained using THF and DCM at optimized molar ratios. The optimized molar ratios of THF:CNPrTEOS and THF:PDMS were 5:1 and 25:1, respectively. The optimized molar ratios of DCM:CNPrTEOS and DCM:PDMS were 10:1 and 70:1, respectively. FTIR spectrum showed that the intensity of the CN peak increased with increasing content of CNPrTEOS in the PDMS;CNPrTEOS-derived hybrid. The Field Emission Scanning Electron micrographs of prepared coatings revealed smooth, homogenous surfaces and crack-free coatings with film thickness of 200 nm to 2.5 μm attributing to different solvent types. All coatings prepared were thermally stable at temperature higher than 200 °C. The DCM-based PDMS-CNPrTEOS-derived coating shows more advantages in terms of physical characteristics and extraction ability compared to THF-based PDMS-CNPrTEOS-derived coatings due to higher cyano part content and its thicker coating. The PDMS-CNPrTEOS-derived hybrid coatings can be used as extraction sorbent for analysis of non steroidal anti-inflammatory drugs namely ketoprofen and diclofenac sodium in SBSE.     

A parametric study of methane decomposition into carbon nanotubes over 8Co-2Mo/Al2O3 catalyst

The effects of reaction temperature, partial pressure of methane, catalyst weight and gas hourly space velocity (GHSV) on methane decomposition were reported. The decomposition reaction was performed in a vertical fixed-bed reactor over 8Co-2Mo/Al 2 O 3 catalyst. The experimental results show that these four process parameters studied had vital effects on carbon yield. As revealed by the electron microscopy and Raman spectroscopy analyses, the reaction temperature and GHSV governed the average diameter, the diameter distribution and the degree of graphitization of the synthesized carbon nanotubes (CNTs). Also, an evidence is presented to show that higher temperatures and higher GHSV favored the formation of better-graphitized CNTs with larger diameters.     

Scattering of electromagnetic wave by perfect electromagnetic conductor (PEMC) sphere placed in chiral media

A theoretical investigation has been carried out for electromagnetic waves scattering from a perfect electromagnetic conductor (PEMC) sphere which is placed in chiral media. The formulation of the problem is realized by expanding the incident as well as the scattered electromagnetic fields in terms of left circularly polarized (LCP) and right circularly polarized (RCP) waves. By applying the boundary conditions at the chiral-PEMC interface, eight simultaneous equations are generated, which yield the scattering coefficients associated with the Left and Right electromagnetic waves. The relative contribution of Co-polarized and Cross-polarized components of fields to the calculations of scattering cross-section is presented. The effect of admittance parameter and the effect of chirality parameter in cases of lossless, lossy permittivity and lossy permeability on Co and Cross components of scattering cross sections are observed. The results are also compared with available published literatures which are in good agreement.     

Applications of Raman Spectroscopy in Dentistry: Analysis of Tooth Structure

Abstract: Tooth enamel is the most mineralized tissue in the human body, and in this article the use of Raman spectroscopy for the analysis of tooth structure, a comparison with synthetic apatites, and use in dentistry are described. Spectral peaks that are related to dental hard and soft tissues are discussed, which provide crucial data in understanding the chemical structural properties of dentin and enamel. The Raman spectrum of dentin confirms the presence of crystalline phosphate-based minerals in dentin. Both dentin and enamel consist of two primary components: an inorganic or mineral phase that closely resembles hydroxyapatite and the Raman spectrum of dentin that confirms the presence of crystalline phosphate-based minerals in dentin. Hence, the mineral phase in dentin and enamel may be characterized essentially as nonstoichiometric substituted apatite. The presence of carbonate (A and B type) incorporated in the hydroxyapatite lattice is also confirmed by the presence of spectral bands. The organic phase, which is mainly composed of type I collagen, is confirmed by the spectral bands of amide I and amide II bands, tryptophan, and phenylalanine. Furthermore, these spectral bands associated with organic and inorganic parts of the enamel and dentin are useful in predicting early formation of carries formation.     

Application of Vibrational Spectroscopy in Combination with Chemometrics Techniques for Authentication of Herbal Medicine

Abstract: One of the emerging issues in herbal medicine is its authenticity. The substitution of highly valuable materials in herbal medicine with lower ones is common practice in the herbal medicine industry. This practice can cause serious effects or be harmful to human health; therefore, the authentication of herbal medicine using analytical techniques is necessary. Due to its capability as fingerprint technique, vibrational spectroscopy (infrared and Raman), especially in combination with several chemometrics techniques, is the method of choice for authentication purposes. This review highlights the use of mid-infrared, near-infrared, and Raman spectroscopy for authentication of herbal medicine, either in raw materials or in final products.     

Experiments on New Arrangements of Convex and Concave Corrugated Tubes through a Double-pipe Heat Exchanger

The main scope of this article paper is to experimentally clarify the effects of outer-tube and inner-tube corrugations on thermal and frictional characteristics in a horizontal double-pipe heat exchanger. Nusselt number, friction factor, and thermal performance factor are evaluated for new various arrangements of convex and concave corrugated tubes. Smooth tubes were corrugated by means of a special machine. Findings indicate that the arrangement type of corrugated tubes has a significant effect on the mentioned parameters. The best performance was obtained for a heat exchanger made of a concave corrugated outer tube and a convex corrugated inner tube.     

Charged Higgs Boson Contribution to \overline{\nu}_{e}-e Scattering from Low to Ultrahigh Energy in Higgs Triplet Model

We study the $\overline{\nu}_{e}-e$ scattering from low to ultrahigh energy in the framework of Higgs Triplet Model (HTM). We add the contribution of charged Higgs boson exchange to the total cross section of the scattering. We obtain the upper bound $h_{ee}/M_{H^{\pm}}\lesssim2.8\times10^{-3}~\mbox{GeV}^{-1}$ in this process from low energy experiment. We show that by using the upper bound obtained, the charged Higgs contribution can give enhancements to the total cross section with respect to the SM prediction up to 5.16 % at E≤10¹⁴ eV and maximum at $s\approx M_{H^{\pm}}^{2}$ and would help to determine the feasibility experiments to discriminate between SM and HTM at current available facilities.     

Low-Lying S-States of Two-Electron Systems

The energies of the low-lying bound S-states of some two-electron systems (treating them as three-body systems) like negatively charged hydrogen, neutral helium, positively charged-lithium, beryllium, carbon, oxygen, neon, argon and negatively charged muonium and exotic positronium ions have been calculated employing hyperspherical harmonics expansion method. The matrix elements of two-body interactions involve Raynal–Revai coefficients which are particularly essential for the numerical solution of three-body Schr?dinger equation when the two-body potentials are other from Coulomb or harmonic. The technique has been applied for to two-electron ions ¹H^? (Z = 1) to ⁴⁰Ar¹⁶⁺ (Z = 18), negatively charged-muonium Mu^? and exotic positronium ion Ps^?(e ⁺ e ^? e ^?) considering purely Coulomb interaction. The available computer facility restricted reliable calculations up to 28 partial waves (i.e. K _m  = 28) and energies for higher K _m have been obtained by applying an extrapolation scheme suggested by Schneider.