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排序方式: 共有196条查询结果,搜索用时 31 毫秒
101.
SONG Yang WANG Jin-cheng XU Hui DU Zhen-wu ZHANG Gui-zhen SELIM Hamid Abdu LI Guang-sheng WANG Qing GAO Zhong-li 《高等学校化学研究》2013,29(2):263-269
As the strongest electronegative element, fluorine can stimulate the production of superoxide radicals in cells. In view of the important roles of kidneys in bone metabolism, the authors analyzed the quantitative pathomorphological characteristics of renal damage and the potential cellular apoptosis and oxidative stress mechanisms in rats treated with excessive fluoride. Wistar rats were exposed to 50 mg F-(110.5 mg NaF)/L, 100 mg F-(221.0 mg NaF)/L and 150 mg F-(331.5 mg NaF)/L in drinking water for 70 and 140 d, respectively. Microscope with image analysis was used to quantitate pathomorphological changes in renal tissues of the rats. Reactive oxygen species(ROS), the cell cycle and apoptosis of renal cells were measured by flow cytometry and TUNEL technique(terminal deoxynucleotidyl transferase dUTP nick end labeling), respectively. The ion concentrations in serum and renal functional parameters were detected by automatic biochemical analyzer. Quantitative analysis results demonstrate the expanded Bowman’s space of glomerulus and obvious dilatation of renal tubule. TUNEL technique revealed that NBT/BCIP (nitro blue tetrazolium/5-bromo-4-chloro-3′-indolylphosphate, p-toluidine salt)-staining positive apoptotic cells selectively located in medullocortical junction areas. The data suggest that renal damage in chronic fluorostic rats is associated with the cellular apoptosis and oxidative stress. 相似文献
102.
Alejandro Adem Jianzhong Pan 《Transactions of the American Mathematical Society》2006,358(9):3969-3983
In this paper we compute the integral cohomology of certain semi-direct products of the form , arising from a linear action on the -torus, where is a finite group. The main application is the complete calculation of torsion gerbes for six-dimensional examples arising in string theory.
103.
Alan R. Katritzky Abdu E. Abdel-Rahman David E. Leahy Otto A. Schwarz 《Tetrahedron》1983,39(24):4133-4142
The title compounds can be lithiated at the inter-ring carbon atom to give carbanions which react with a variety of electrophiles. Lithiation can also be directed to the 5-position of the ring. 相似文献
104.
Alan R. Katritzky Otto A. Schwarz Abdu E. Abdel Rahman David E. Leahy 《Journal of heterocyclic chemistry》1984,21(6):1673-1677
The synthesis is described of fluorescent and coloured pyrylium and pyridinium salts, including water-soluble derivatives, designed to serve as marker reagents for primary amines. 相似文献
105.
We use equivariant methods to define and study the orbifold K-theory of an orbifold X. Adapting techniques from equivariant K-theory, we construct a Chern character and exhibit a multiplicative decomposition
for K
*
orb
(X)⊗ℚ, in particular showing that it is additively isomorphic to the orbifold cohomology of X. A number of examples are provided. We then use the theory of projective representations to define the notion of twisted
orbifold K–theory in the presence of discrete torsion. An explicit expression for this is obtained in the case of a global
quotient.
Received: 21 August 2001 / Accepted: 27 January 2003
Published online: 13 May 2003
RID="*"
ID="*" Both authors were partially supported by the NSF
RID="*"
ID="*" Both authors were partially supported by the NSF
Communicated by R.H. Dijkgraaf 相似文献
106.
Abdullah KEPCEOLU Yasemin GÜNDODU Adem SARILMAZ Mustafa ERS
Z Faruk
ZEL Hamdi ükür KILI 《Turkish Journal of Chemistry》2021,45(2):485
In this study, rhenium/rhenium oxide nanoparticles (Re / ReO3 NPs) have been produced for the first time in ultrapure water by using Femtosecond Pulsed Laser Ablation in Liquid (fsPLAL) method. X-Ray Diffraction (XRD) measurements and results obtained for NPs show the existence of well-crystallized peaks and preferred phases. Re NPs have hexagonal structure while ReO3 NPs have the perovskite-like cubic crystal structures. The Re / ReO3 ratio is also determined to be 53 / 47 with ~ 20 nm crystallite size, while pure ReO3 crystallite sizes were measured to be ~ 25 nm. The TEM results have shown that the produced particles have a spherical shape, and particle sizes changes between ~ 20 nm and ~ 60 nm. The crystallite size is similar due to XRD results. Obtained nanoparticles exhibit promising applications for photonic devices with broad bandgap values which have measured to be 4.71 eV for Re / ReO3 NPs mixture and 4.36 eV for pure ReO3 NPs. 相似文献
107.
Suzan Abuelhassan Etify A.-G. Bakhite Abdu E. Abdel-Rahman Ahmed F. M. El-Mahdy 《Journal of heterocyclic chemistry》2021,58(9):1784-1801
3-Cyano-5-ethoxycarbonyl-6-methyl-4-(2′-thienyl)-pyridine-2(1H)-thione ( 1 ) is synthesized and reacted with chloroacetamide or chloroacetonitrile to give 3-amino-5-ethoxycarbonyl-6-methyl-4(2′-thienyl)-thieno[2,3-b]pyridine-2-carboxamide 3a or its 2-carbonitrile analog 3b , respectively. Cyclocondensation of 3a with triethylorthoformate produced the corresponding pyridothienopyrimidineone 4 , which on heating with phosphorus oxychloride gave 4-chloropyrimidine derivative 5 . Compound 5 was used as key intermediate for synthesizing compounds 6 , 9 , 10 , 11 , and 12 upon treatment with some nucleophilic reagents such as thiourea, 5-phenyl-s-triazole-3(1H)-thione, piperidine, morpholine, or hydrazine hydrate, respectively. Reaction of pyridothienopyrimidinethione 6 with N-(4-tolyl)-2-chloroacetamide or ethyl bromoacetate afforded the corresponding S-substituted methylsulfanylpyrimidines 7 or 8 . The condensation of 3b with triethylorthoformate gave azomethine derivative 13 , which was reacted with hydrazine hydrate to give ethyl 3-amino-3,4-dihydro-4-imino-7-methyl-9-(2′-thienyl)pyrido[3′,2′:4,5]thieno[3,2-d]pyrimidine-8-carboxylate ( 14 ). Compounds 12 and 14 were used as precursors for synthesizing other new thienylpyridothienopyrimidines as well as isomeric thienyl-s-triazolopyridothieno- pyrimidines. All synthesized compounds were characterized by elemental and spectral analyses such as IR, 1H NMR, and 13C NMR. In addition, majority of synthesized compounds were tested for their antifungal activity against five strains of fungi. Moreover, compounds 3a , 5 , 6 , 8 , and 22 were screened for their anticancer activity against HEPG-2 and MCF-7 cell lines. 相似文献
108.
Coles SJ Davies DB Eaton RJ Hursthouse MB Kiliç A Shaw RA Uslu A 《Dalton transactions (Cambridge, England : 2003)》2007,(20):2040-2047
Derivatives of the tri-spirane pentaerythritoxy-cyclophosphazene compound, 1, have been used to investigate the stereogenic properties of spiranes combined with four equivalent conventional centres of chirality. In compound 1 the two inner rings are carbocyclic and symmetrical and the two outer rings are cyclotriphosphazenes substituted in different positions to provide the conventional centres of chirality. The case of combining spiranes with four equivalent centres of chirality has been investigated by the reaction of 1 with dimethylamine in a 1 : 8 molar ratio to give four diastereoisomeric products, in which the two cyclophosphazene rings are non-geminally di-substituted in either cis or trans configurations; viz. the cis-cis (2a), cis-trans (2b) and two trans-trans substituted dimethylamine derivatives 2c and 2d. The structure and stereogenic properties of compound 2a (C2 symmetry) have been characterized previously by both X-ray crystallography and 31P NMR spectroscopy on addition of a chiral solvating agent (CSA) and the structures and stereogenic properties of compounds 2b (C1) and 2d (C2) have been similarly characterized in this work. The structure of compound 2c has been characterised by X-ray crystallography and found to be meso with the relatively rare S4 symmetry. The four diastereoisomeric products 2a-2d represent all the possible stereochemical isomers of a spirane combined with four equivalent conventional centres of chirality. 相似文献
109.
1,3-Disubstituted-2,3-dihydro-1H-naphth[1,2-e][1,3]oxazines were prepared through the ring-closure reactions of the aminobenzylnaphthols with substituted aryl- and heteroarylaldehydes. 相似文献
110.
Allylic onium salts with different hetero‐atoms and various substituent groups at the allylic double bond have been shown to be very efficient initiators for cationic polymerization. When attacked by a radical, they become radical cations, which are highly unstable species, and undergo fragmentation into smaller radical cations called onium radical cations. The reaction mechanism involves radical formation, addition and fragmentation. In our previous work, radical initiators generated in the same way and under the same conditions are studied experimentally for their ability to affect the polymerization efficiency. Here, the factors affecting the polymerization efficiency are discussed theoretically using semi‐empirical quantum mechanical techniques. The type of radical species, substituent group at the allylic side, the heteroatom at the onium side and the onium group itself are analyzed separately. For this purpose, the geometries of different onium radical cations to be fragmented are optimized and the strength of the C–heteroatom bond to be broken and the size of the radical cations after fragmentation are considered. 相似文献