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11.
Gönül Yenilmez Çiftçi Elif ?enkuytuEsra Tanr?verdi Eçik Adem K?l?çFatma Yuksel 《Polyhedron》2011,30(13):2227-2236
New 1,3-propanediaminocyclotriphosphazene derivatives (7-17) were synthesized from the reactions of spiro-1,3-propanediaminocyclotriphosphazene, N3P3Cl4[NH(CH2)3NH] (1) with the cyclopropanemethylamine (2), cyclohexylamine (3), pyrrolidine (4) cyclohexanol (5), cyclopropylmethanol (6). The structures of the novel compounds (7-17) were characterized by elemental analysis, mass spectrometry, 1H and 31P NMR spectroscopy. The molecular structures of 8, 12 and 13 were determined by X-ray crystallography. The structures of all these three compounds are in the monoclinic crystal system; compounds 8 and 12 have the P21/c space group while compound 13 has the P21/n space group. The ring conformation of the cyclotriphosphazene and other external rings were investigated based on the X-ray crystal structures. 相似文献
12.
Beşli S Coles SJ Davies DB Hursthouse MB Ibişoglu H Kiliç A Shaw RA 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(19):4915-4920
X-ray crystallographic evidence shows that nucleophilic substitution reactions of two different types of cyclophosphazene derivatives with relatively rigid nine-membered ansa rings leads to the first demonstration of retention of configuration in these molecular systems. 相似文献
13.
Miguel A. T. Walter Aline A. Q. Abdu Luís Fernando Figueira da Silva Joo Luiz F. Azevedo 《国际流体数值方法杂志》2005,49(9):999-1014
The compressible gas flows of interest to aerospace applications often involve situations where shock and expansion waves are present. Decreasing the characteristic dimension of the computational cells in the vicinity of shock waves improves the quality of the computed flows. This reduction in size may be accomplished by the use of mesh adaption procedures. In this paper an analysis is presented of an adaptive mesh scheme developed for an unstructured mesh finite volume upwind computer code. This scheme is tailored to refine or coarsen the computational mesh where gradients of the flow properties are respectively high or low. The refinement and coarsening procedures are applied to the classical gas dynamic problems of the stabilization of shock waves by solid bodies. In particular, situations where oblique shock waves interact with an expansion fan and where bow shocks arise around solid bodies are considered. The effectiveness of the scheme in reducing the computational time, while increasing the solution accuracy, is assessed. It is shown that the refinement procedure alone leads to a number of computational cells which is 20% larger than when alternate passes of refinement and coarsening are used. Accordingly, a reduction of computational time of the same order of magnitude is obtained. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
14.
This paper studies the Zakharov-Kuznetsov equation in (1+3) dimensions with an arbitrary power law nonlinearity. The method
of Lie symmetry analysis is used to carry out the integration of the Zakharov-Kuznetsov equation. The solutions obtained are
cnoidal waves, periodic solutions, singular periodic solutions, and solitary wave solutions. Subsequently, the extended tanh-function
method and the G′/G method are used to integrate the Zakharov-Kuznetsov equation. Finally, the nontopological soliton solution is obtained by
the aid of ansatz method. There are numerical simulations throughout the paper to support the analytical development. 相似文献
15.
Ayhan Oral Mehmet Atilla Tasdelen Adem Levent Demirel Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2009,47(20):5328-5335
Poly(cyclohexene oxide) (PCHO)/clay nanocomposites were prepared by in situ photoinitiated activated monomer cationic polymerization. The polymerization of cyclohexene oxide through the interlayer galleries of the clay can provide distribution of the clay layers in the polymer matrix homogenously and results in the formation of PCHO/clay nanocomposites. The exfoliated structures were characterized by X‐ray diffraction spectroscopy, thermogravimetric analysis, transmission electron microscopy, and atomic force microscopy. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5328–5335, 2009 相似文献
16.
This article records basic topological, as well as homological properties of the space of homomorphisms Hom(π,G) where π is a finitely generated discrete group, and G is a Lie group, possibly non-compact. If π is a free abelian group of rank equal to n, then Hom(π, G) is the space of ordered n–tuples of commuting elements in G. If G = SU(2), a complete calculation of the cohomology of these spaces is given for n = 2, 3. An explicit stable splitting of these spaces is also obtained, as a special case of a more general splitting.
Alejandro Adem was partially supported by the NSF and NSERC. Frederick R. Cohen was partially supported by the NSF, grant
number 0340575. 相似文献
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18.
Churchard AJ Banach E Borgschulte A Caputo R Chen JC Clary D Fijalkowski KJ Geerlings H Genova RV Grochala W Jaroń T Juanes-Marcos JC Kasemo B Kroes GJ Ljubić I Naujoks N Nørskov JK Olsen RA Pendolino F Remhof A Románszki L Tekin A Vegge T Zäch M Züttel A 《Physical chemistry chemical physics : PCCP》2011,13(38):16955-16972
The widespread adoption of hydrogen as an energy carrier could bring significant benefits, but only if a number of currently intractable problems can be overcome. Not the least of these is the problem of storage, particularly when aimed at use onboard light-vehicles. The aim of this overview is to look in depth at a number of areas linked by the recently concluded HYDROGEN research network, representing an intentionally multi-faceted selection with the goal of advancing the field on a number of fronts simultaneously. For the general reader we provide a concise outline of the main approaches to storing hydrogen before moving on to detailed reviews of recent research in the solid chemical storage of hydrogen, and so provide an entry point for the interested reader on these diverse topics. The subjects covered include: the mechanisms of Ti catalysis in alanates; the kinetics of the borohydrides and the resulting limitations; novel transition metal catalysts for use with complex hydrides; less common borohydrides; protic-hydridic stores; metal ammines and novel approaches to nano-confined metal hydrides. 相似文献
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