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81.
Wafaa M. Abdou Mounir A. I. Salem Ashraf A. Sediek 《Monatshefte für Chemie / Chemical Monthly》2003,11(4):1373-1385
Triketoindan-2-oxime reacted readily with ethoxycarbonylmethylene triphenylphosphorane to give mainly the corresponding spiro-pyrrole (38%) along with the fused 1-hydroxydihydropyrrole (14%), whereas the spiro-dimer (29%) was obtained from the reaction of the oxime with methoxycarbonylmethylenetriphenyl phosphorane in addition to the corresponding 1-hydroxydihydropyrrole (31%). Conversely, Wittig products, mono-olefin (52%) and diolefin (<7%) along with the reduced substrate (10%), were observed when the oxime was treated with a cyano ylide. The reactions of the oxime with allyl- and vinyl phosphonium salts proceeded under phase-transfer catalysis to afford fused oxazole (46%) and spiro[2]oxazole (17%), while with the latter the fused 1-hydroxypyrrole (55%) was produced. 相似文献
82.
83.
Thiazolylcyanothioacetanilides react with α‐haloketones and haloesters to give the corresponding thiophene or thiazole derivatives according to the reaction conditions. Pyrazolo[1,5‐a]pyrimidines and pyrazolo[5,1‐c]triazines were synthesized by reaction of 3‐amino‐4‐(4′‐arylthiazol‐2′‐yl)‐5‐phenylaminopyrazole with different reagents. Structures of the new compounds were confirmed by elemental analyses, spectral data, and alternative methods of synthesis whenever possible. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 508–516, 1999 相似文献
84.
Wafaa M. Abdou Ashraf A. Sediek Maha D. Khidre 《Monatshefte für Chemie / Chemical Monthly》2008,139(6):617-623
Treatment of triketoindan-2-oxime with α-phosphonyl carbanions in sodium ethanolate solution at reflux temperature led to
a number of the corresponding substituted spiroisooxazole-, fused 1,3-oxazole, and 1,4-oxazine phosphor esters in moderate
to high yields. Mechanisms for the formation of five- and six-membered rings are provided. A comparison of Wittig-Horner and Wittig reagent counterparts in reactions with the oxime is discussed. The various biological properties of selected examples of
the synthesized products were studied.
Correspondence: Wafaa M. Abdou, Chemical Industries Division, National Research Center, Elbohouth St., D-12622 Dokki, Cairo,
Egypt. 相似文献
85.
Babacar Toumbou Daniel Y. Le Roux Abdou Sène 《Journal of Differential Equations》2008,244(8):2020-2040
We present an existence theorem of a two-dimensional sedimentation model coupling a shallow water system with a sediment transport equation. The shallow water system includes Coriolis and friction terms. A Galerkin method is used to obtain a finite-dimensional problem which is solved using a Brouwer fixed point theorem. We prove that the limits of the resulting solution sequences satisfy the model equations. 相似文献
86.
Hydrochloric acid solutions (0.05–1.18m) containing p-nitroaniline (8×10–5M) as indicator base have H
o
values which increase with increase of ethylene carbonate (EC) content in the solvent mixture for a fixed molality of the acid. This behavior confirms similar results obtained in AN-H2O, MCS-H2O, DMSO-H2O and NMF-H2O systems. This trend indicates that the solvent basicity increases by successive addition of the organic solvent. The partition of the proton between water and EC has been calculated using Sadek's theory. It is clear that [H3O+] decreases gradually with increase of EC content. The change in the dissociation constant of p-nitroanilinium ion,
decreases sharply with increasing dielectric constant. The free energy change of transfer, G
t
o
, has been attributed to an electrostatic, G
t(el)
o
, and a nonelectrostatic, electrostatic, G
t(non)
o
component. It has been found that G
t(non)
o
is negative. 相似文献
87.
Hanan E. Abdou Ahmed A. Mohamed José M. López-de-Luzuriaga John P. FacklerJr. 《Journal of Cluster Science》2004,15(4):397-411
The syntheses and characterization of gold(I) naphthyl, pentafluorophenyl, and trifluoromethylphenyl amidinate complexes are reported. The tetranuclear clusters are obtained from the reaction of Au(tetrahydrothiophene)Cl with the potassium salt of the corresponding amidinate in a THF solvent. The crystal structures of the gold(I) naphthyl, 2, and pentafluorophenyl, 3, amidinates show a short Au···Au distance of ~3. 0 Å typical of compounds having an aurophilic interaction. The gold atoms are arranged in a square (Au···Au···Au = 87°–92°) in the pentafluorophenyl derivative and in a parallelogram (Au···Au···Au = 68°–110°) in the naphthyl amidinate complexes. The naphthyl and trifluoromethylphenyl complexes are visibly luminescent in the solid state at liquid nitrogen temperature displaying asymmetric emission bands at 538 and 473 nm, respectively. The luminescent lifetimes of these species are in the millisecond range indicating phosphorescent processes. 相似文献
88.
Abdou Youssef 《PAMM》2007,7(1):1010501-1010502
As digital libraries of mathematical and scientific contents become available, it is essential to have math-aware search systems. The search systems must understand math symbols and structures, and allow users to enter queries that involve not only text keywords but also mathematical expressions and fragments of expressions. In addition, the search results must be presented in a way that enables the user to find the desired information rapidly. This short paper gives a quick overview of the state of the art of math search, and focuses on the math search system that the author has developed for the Digital Library of Mathematical Functions (DLMF) project of the National Institute of Standards and Technology. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
89.
H. A. Shaban A. A. Shaltout M. Abdou E. A. Al Ashker M. Elgohary 《Journal of Applied Spectroscopy》2011,77(6):771-777
Cu, Zn, and Se were successfully determined in a few microliters (<100 μl) of biological samples using discrete injection
atomic absorption spectrometry. Different factors were investigated in order to obtain a biological sample volume which is
valid for analysis. Among them are the effect of microsampling volume variations (starting from 40 to 200 μl), nebulization
efficiency, detection limits, precision, and finally the calibration and sensitivity of the proposed method. It was found
that 60 μl of the biological sample was adequate for the quantitative analysis with reasonable precision. The advantages of
the proposed method are not only rapidity, simplicity, sensitivity, and good precision, but also, contrary to conventional
flame atomic absorption spectrometry, the capability of analyzing microvolumes of samples. 相似文献
90.
Joseph M. Abdou 《International Journal of Game Theory》2012,41(4):775-789
We study the stability and the stability index of the meet game form defined on a meet semilattice. Given any active coalition structure, we show that the stability index relative to the equilibrium, to the beta core and to the exact core is a function of the Nakamura number, the depth of the semilattice and its gap function. 相似文献