全文获取类型
收费全文 | 211篇 |
免费 | 12篇 |
国内免费 | 4篇 |
专业分类
化学 | 163篇 |
晶体学 | 3篇 |
力学 | 6篇 |
数学 | 25篇 |
物理学 | 30篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 8篇 |
2020年 | 7篇 |
2019年 | 8篇 |
2018年 | 9篇 |
2017年 | 7篇 |
2016年 | 15篇 |
2015年 | 11篇 |
2014年 | 15篇 |
2013年 | 16篇 |
2012年 | 27篇 |
2011年 | 15篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 17篇 |
2007年 | 6篇 |
2006年 | 7篇 |
2005年 | 8篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2001年 | 2篇 |
1999年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
排序方式: 共有227条查询结果,搜索用时 0 毫秒
41.
Khodabakhsh Niknam Dariush Saberi Mohsen Sadegheyan Abdollah Deris 《Tetrahedron letters》2010,51(4):692-694
Silica-bonded S-sulfonic acid (SBSSA) is employed as a recyclable catalyst for the condensation reaction of aromatic aldehydes with 3-methyl-l-phenyl-5-pyrazolone. This condensation reaction was performed in ethanol under refluxing conditions giving 4,4′-alkylmethylene-bis(3-methyl-5-pyrazolones) in 75-90% yields. 相似文献
42.
An efficient heterogeneous Pd catalytic system has been developed, based on immobilization of Pd nanoparticles (PNPs) on a silica-bonded N-propylpiperazine (SBNPP) substrate. The SBNPP substrate effectively stabilizes the PNPs and improves their stability against aggregation. The catalytic activity of this catalyst was investigated in the cyanation of aryl halides with K4[Fe(CN)6 ] as the cyanide source. The catalyst could be recycled several times without appreciable loss of catalytic activity. 相似文献
43.
44.
Abdollah Alhevaz 《代数通讯》2017,45(3):919-923
Ever since the introduction, skew inverse Laurent series rings have kept growing in importance, as researchers characterized their properties (such as Noetherianness, Armendarizness, McCoyness, etc.) in terms of intrinsic properties of the base ring and studied their relations with other fields of mathematics, as for example quantum mechanics theory. The goal of our paper is to study the primeness and semiprimeness of general skew inverse Laurent series rings R((x?1;σ,δ)), where R is an associative ring equipped with an automorphism σ and a σ-derivation δ. 相似文献
45.
46.
Seyyed Mojtaba Mousavi Seyyed Alireza Hashemi Masoomeh Yari Kalashgrani Ahmad Gholami Yousef Mazaheri Mohsen Riazi Darwin Kurniawan Mohammad Arjmand O. Madkhali Mahmood D. Aljabri Mohammed M. Rahman Wei-Hung Chiang 《Chemical record (New York, N.Y.)》2024,24(1):e202200266
The ever-growing demand of human society for clean and reliable energy sources spurred a substantial academic interest in exploring the potential of biological resources for developing energy generation and storage systems. As a result, alternative energy sources are needed in populous developing countries to compensate for energy deficits in an environmentally sustainable manner. This review aims to evaluate and summarize the recent progress in bio-based polymer composites (PCs) for energy generation and storage. The articulated review provides an overview of energy storage systems, e. g., supercapacitors and batteries, and discusses the future possibilities of various solar cells (SCs), using both past research progress and possible future developments as a basis for discussion. These studies examine systematic and sequential advances in different generations of SCs. Developing novel PCs that are efficient, stable, and cost-effective is of utmost importance. In addition, the current state of high-performance equipment for each of the technologies is evaluated in detail. We also discuss the prospects, future trends, and opportunities regarding using bioresources for energy generation and storage, as well as the development of low-cost and efficient PCs for SCs. 相似文献
47.
48.
Abdollah Sarani Nathalie De GeyterRino Morent Christophe Leys 《Applied Surface Science》2011,257(20):8737-8741
In this paper, an atmospheric pressure plasma jet sustained in pure argon and an argon/water vapour mixture has been used to modify the surface of polypropylene (PP) films. The gas temperature of the plasma jet was found to be 625 K in an active zone between the electrodes and was found to increase in the afterglow. Based on these results, the PP films are placed as close as possible to the edge of the capillary in order to avoid thermal damage to the polymer. XPS results on the untreated and modified PP samples revealed incorporation of a significant amount of oxygen on the polymer surface, however, this oxygen inclusion is more pronounced for the argon/water vapour jet due to the higher radicals density in the jet afterglow. One can therefore conclude that adding water vapour to an argon plasma jet can be a convenient way to increase the efficiency of plasma surface modification. 相似文献
49.
Sensitive Electrochemical Prostate Specific Antigen Aptasensor: Effect of Carboxylic Acid Functionalized Carbon Nanotube and Glutaraldehyde Linker 下载免费PDF全文
The performance of carboxylic acid functionalized carbon nanotubes (CNTs(COOH)), chitosan (Chit), carbon nanotubes‐chitosan (CNTs‐Chit and CNTs(COOH)‐Chit) for immobilizing of amino‐functionalized ssDNA and fabrication of electrochemical prostate specific antigen (PSA) aptasensor were studied in detail using X‐ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT‐IR) and electrochemical impedance spectroscopy (EIS). The assemblies of capture probe are formed on the surface via two approaches: EDC/NHS chemistry and glutaraldehyde linker. Cyclic voltammetry (CV), differential pulse voltammetry (DPV) and EIS techniques were used to investigate the analytical performance of the PSA aptasensor. Under optimum conditions the sensitivity of 0.0026 µA/(ng/ml) and a limit of detection of 0.75 ng/ml (22 pM) were obtained for PSA detection. This protocol offers a new means for sensitive detection of PSA with some advantages in terms of simplicity, selectivity, ease of use and regenerability. 相似文献
50.
Electronic, structural, electrochemical, and spectroscopic properties of all ground-state neutral and singly ionized chlorine-substituted pyrroles and hexa(3-chloropyrrole) oligomer are studied using the density functional theory B3LYP method with the 6-31G(d,p) basis set. The effects of the number and position of the substituents on the electrochemical properties of the pyrrole ring have been studied and analyzed both quantitatively and qualitatively. By using the optimized structures obtained for these molecules and their cations, IR and NMR spectra have been predicted. The results of this study, including spin and charge distributions, show that, among all of these compounds, 3-chloropyrrole has the most suitable conditions for electropolymerization. 相似文献