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排序方式: 共有450条查询结果,搜索用时 15 毫秒
341.
N. Alizadeh M. A. Zanjanchi H. Sharghi R. Khalifeh M. Shamsipur 《Journal of the Iranian Chemical Society》2008,5(4):610-616
Charge-transfer complexation of iodine with a new benzo-substituted macrocyclic diamide 5,6,7,8,9,10-hexahydro-2H-1,13,4,7,10-benzodioxatriazacyclopentadecine-3,11(4H,12H)-dione (L) with iodine was studied spectrophotometrically in chloroform, dichloromethane and their 1:1 (v/v) mixture. The observed time dependence of the charge-transfer band and subsequent formation of I3 - ion are related to the slow formation of the initially formed 1:1 L.I2 outer complex to an inner electron donor-acceptor (EDA) complex, followed by fast reaction of the inner complex with iodine to form a triiodide ion, as follows: L + I2 → L.I2 (outer complex), fast L.I2 (outer complex) → (L.I+)I- (inner complex), slow (L.I+)I- (inner complex) + I2 → (L.I+)I3 -, fast The pseudo-first-order rate constants for the transformation process were evaluated in different solvent systems. The stability constants of the resulting EDAr complexes were also evaluated and the solvent effect on their stability is discussed. The resulting complexes were isolated and characterized by FTIR and 1H NMR spectroscopy. 相似文献
342.
Shahdousti P Aghamohammadi M Alizadeh N 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(4):1195-1200
The charge-transfer (CT) complexes of methamphetamine (MPA) as a n-donor with several acceptors including bromocresolgreen (BCG), bromocresolpurple (BCP), chlorophenolred (CPR), picric acid (PIC), and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) have been studied spectrophotometrically in chloroform solutions in order to obtain some information about their stoichiometry and stability of complexation. The oscillator strengths, transition dipole moments and resonance energy of the complex in the ground state for all complexes have been calculated. Vertical ionization potential of MPA and electron affinity of acceptors were determined by ab initio calculation. The acceptors were also used to utilize a simple and sensitive extraction-spectrophotometric method for the determination of MPA. The method is based on the formation of 1:1 ion-pair association complexes of MPA with BCG, BCP and PIC in chloroform medium. Beer's plots were obeyed in a general concentration range of 0.24-22 microg ml(-1) for the investigated drug with different acceptors. The proposed methods were applied successfully for the determination of MAP in pure and abuse drug with good accuracy and precision. 相似文献
343.
In the presence of 1-phenyl-5-mercaptotetrazole as a nucleophile, electrochemical oxidations of 1,2- and 1,4-dihydroxybenzenes have been investigated in aqueous solution using cyclic voltammetry and controlled-potential coulometry. The voltammetric results indicate that an electrooxidative/Michael-type sequential reaction occurs between the mercaptide anion and the electrochemically generated benzoquinones leading to the corresponding polyfunctional tetrazolic thioethers. The mechanism of electrochemical reaction is proved as an EC pathway using controlled-potential coulometry. In addition, the electrosyntheses of tetrazolic thioethers have been successfully performed in ambient conditions in an undivided cell using an environmentally friendly method with high atom economy. 相似文献
344.
Mohammad H. Alizadeh Hossein Eshtiagh-Hosseini Masoud Mirzaei Ali R. Salimi Hossein Razavi 《Structural chemistry》2008,19(1):155-164
A new hybrid material based on polyoxomolybdate, [C2H6N2O–H]3[(PO4)Mo12O36] · 3H2O (1), has been synthesized and characterized by elemental analysis, infrared and mass spectroscopy, proton nuclear magnetic resonance and single-crystal X-ray diffraction. Compound 1 crystallizes in the hexagonal system, space group R-3, a = 19.0833(6) Å, c = 20.8672(13) Å, V = 581.1(5) Å3, Z = 6, R1 = 0.0202, wR2 = 0.0508. The methyluronium moiety and 12-molybdophosphate anion are held together in a network through hydrogen-bonding and electrostatic interactions. Each methylurea molecule, which is protonated, is stabilized via present strong hydrogen bonding with water molecules in the unit cell. Since this strong hydrogen bonding can play an important role in the formation of unique novelty of titled supramolecular network, we have carried out theoretical calculations on geometrical parameters, stabilization energies, and atomic charges based on natural bond orbital (NBO) analyses and then have compared with those of the neutral methylurea molecule. Our calculations have been done with the B3LYP method of density functional theory (DFT). 相似文献
345.
Abdolnaser Azadbakht Sanaz Alizadeh Zahra Aliakbar Ahovan Zahra Khosrowpour Mohammad Majidi Saeedreza Pakzad Shahrokh Shojaei Narendra Pal Singh Chauhan Marzieh Jafari Mazaher Gholipourmalekabadi 《Macromolecular bioscience》2023,23(2):2200386
Attempts are being made to develop an ideal wound dressing with excellent biomechanical and biological properties. Here, a thermos-responsive hydrogel is fabricated using chitosan (CTS) with various concentrations (1%, 2.5%, and 5% w/v) of solubilized placental extracellular matrix (ECM) and 20% β-glycerophosphate to optimize a smart wound dressing hydrogel with improved biological behavior. The thermo-responsive CTS (TCTS) alone or loaded with ECMs (ECM-TCTS) demonstrate uniform morphology using SEM. TCTS and ECM1%-TCTS and ECM2.5%-TCTS show a gelation time of 5 min at 37 °C, while no gel formation is observed at 4 and 25 °C. ECM5%-TCTS forms gel at both 25 and 37 °C. The degradation and swelling ratios increase as the ECM content of the hydrogel increase. All the constructs show excellent biocompatibility in vitro and in vivo, however, the hydrogels with a higher concentration of ECM demonstrate better cell adhesion for fibroblast cells and induce expression of angiogenic factors (VEGF and VEGFR) from HUVEC. Only the ECM5%-TCTS has antibacterial activity against Acinetobacter baumannii ATCC 19606. The data obtained from the current study suggest the ECM2.5%-TCTS as an optimized smart biomimetic wound dressing with improved angiogenic properties now promises to proceed with pre-clinical and clinical investigations. 相似文献
346.
Arshia Alizadeh Panahi Afshin Javadi Mohammad Reza Afshar Mogaddam 《Journal of separation science》2023,46(10):2200893
In the present work, a combination of microwave-assisted extraction with magnetic ionic liquid–based dispersive liquid–liquid microextraction was developed for the extraction of chloramine–T from fish samples. In this method, the sample was mixed with a hydrochloric acid solution and exposed to microwave irradiations. By doing so, chloramine–T was converted to p–toluenesulfonamide and extracted from the sample into an aqueous phase. Then, a mixture of acetonitrile (as a dispersive solvent) and magnetic ionic liquid (as an extraction solvent) was rapidly injected into the obtained solution. In the following, the magnetic solvent droplets including the extracted analytes were isolated from the aqueous solution in the presence of an external magnetic field and after diluting with acetonitrile injected into high-performance liquid chromatography equipped with a diode array detector. Under the optimum extraction conditions, high extraction recovery (78%), low limits of detection (7.2 ng/g) and quantification (23.9 ng/g), good repeatability (relative standard deviations ≤5.8 and 6.8% for intra– and inter-day precisions, respectively), and wide linear range (23.9–1000 ng/g) were obtained. Finally, various fish samples marketed in Tabriz city (East Azarbaijan, Iran) were analyzed with the suggested method. 相似文献
347.
Rasool Alizadeh Asghar B. Rahimi Nader Karimi Ahmad Alizadeh 《Transport in Porous Media》2017,120(3):579-604
This paper extends the existing studies of heat convection by an external flow impinging upon a flat porous insert to that on a circular cylinder inside a porous medium. The surface of the cylinder is subject to constant temperature and can include uniform or non-uniform transpiration. These cylindrical configurations are introduced in the analyses of stagnation-point flows in porous media for the first time. The equations governing steady transport of momentum and thermal energy in porous media are reduced to simpler nonlinear differential equations and subsequently solved numerically. This reveals the dimensionless velocity and temperature fields of the stagnation-point flow, as well as the Nusselt number and shear stress on the surface of the cylinder. The results show that transpiration on the surface of the cylinder and Reynolds number of the external flow dominate the fluid dynamics and heat transfer problems. In particular, non-uniform transpiration is shown to significantly affect the thermal and hydrodynamic responses of the system in the circumferential direction. However, the permeability and porosity of the porous medium are found to have relatively smaller influences. 相似文献
348.
Enhanced spectrofluorimetric determination of aflatoxin B1 in wheat by second-order standard addition method 总被引:1,自引:0,他引:1
Determination of aflatoxin B1 (AFB1) in wheat has been accomplished by enhanced spectrofluorimetry in combination with second-order standard addition method (EF-SOSAM). The adopted strategy combined the use of parallel factor analysis (PARAFAC) for extraction of the pure analyte signal and the standard addition method, for a determination in the presence of matrix effect caused by wheat matrix. The method is based on the enhanced fluorescence of AFB1 by beta-cyclodextrin in 10% (w/w) methanol-water solution. After sample treatment and without any extended cleanup steps and derivatization process, four standard additions were performed for each sample. A specific PARAFAC model was built from three-way arrays formed by excitation-emission spectra and 5 measurements (sample plus 4 additions). The scores related to AFB1 were used for a linear regression in the standard addition method. Two naturally contaminated wheat and spiked wheat samples containing AFB1 in the range 0-18 microg kg(-1) were analyzed by EF-SOSAM and compared with HPLC results. EF-SOSAM analysis of spiked wheat samples gave a good correlation with spiked values (R(2)>0.990). The limit of detection of method was 0.9 microg kg(-1) for the determination of AFB1 in wheat samples. 相似文献
349.
N. Alizadeh S. Ershad H. Naeimi H. Sharghi M. Shamsipur 《Fresenius' Journal of Analytical Chemistry》1999,365(6):511-515
A PVC membrane electrode for copper(II) ions based on a recently synthesized naphthol-derivative Schiff’s base as membrane
carrier was prepared. The sensor exhibits a Nernstian response for Cu2+ ions over a wide concentration range (5.0 × 10–6–5.0 × 10–2 mol/L) with a detection limit of 3.1 × 10–6 mol/L (0.2 μg/mL). It has a very short response time of about 5 s and can be used for ?3 months without any divergence in
potential. The proposed electrode revealed good selectivities over a wide variety of other cations including alkali, alkaline
earth, transition and heavy metal ions and could be used in a pH range of 4.0–7.0. It was successfully applied to the direct
determination and potentiometric titration of copper ion.
Received: 23 February 1999 / Revised: 4 May 1999 / Accepted: 5 May 1999 相似文献
350.
Abdolali Alizadeh 《Helvetica chimica acta》2005,88(10):2777-2780
The reactive 1 : 1 intermediate produced in the reaction between triphenylphosphine and diisopropyl azodicarboxylate has been trapped by isocyanates or isothiocyanates to yield 1,2,4‐triazole derivatives 2 (Scheme 1). The structures of the highly functionalized compounds 2 were corroborated spectroscopically (IR, 1H‐ and 13C‐NMR, EI‐MS) and by elemental analyses. A mechanism for this type of cyclization is proposed (Scheme 2). 相似文献