Structural and textural features of TiO<Subscript>2</Subscript>/SAPO-34 nanocomposite prepared by the sol–gel method

This paper focuses on the synthesis of nanocomposite materials, TiO₂/SAPO-34, using the sol–gel method, which involves preparing a mixture between as-synthesized or calcined SAPO-34 zeolite and TiO₂ gel under hydrothermal crystallization and then calcining it at 400 °C for the formation of the TiO₂ anatase phase. The structural and textural features of the obtained materials were determined by various physico-chemical techniques such as thermogravimetric analysis, X-ray diffraction, scanning electronic microscopy, nitrogen sorption at 77 K, energy dispersive X-ray analysis and ultraviolet–visible spectrometry. The DRX results showed that calcination at 400 °C of the mixture between the calcined SAPO-34 and TiO₂ gel led to the collapse of the original framework of zeolite, but formed the anatase TiO₂ in a nano-spherical morphology; however, the use of as-synthesized SAPO-34 supports provides a mixture phase between SAPO-34 and TiO₂ anatase after calcination. The photocatalytic properties of the SAPO-34/TiO₂ and TiO₂-type materials were tested for the removal of methylene blue (MB) dye. The MB degradation proved to increase as a function of contact time, catalyst mass and the initial concentration of MB.     

In vitro effect of wheat bran (Triticum aestivum) extract on calcium oxalate urolithiasis crystallization

Urolithiasis can lead to the loss of renal function in some cases. In this study, we tested the inhibiting effect of wheat bran (Triticum aestivum L) extract on calcium oxalate crystallization in a turbidimetric model, by FTIR spectroscopy, and polarized microscopy. The results show that this plant extract has a major inhibitory effect on calcium oxalate crystallization.     

Key Role of Intramolecular Metal Chelation and Hydrogen Bonding in the Cobalt‐Mediated Radical Polymerization of N‐Vinyl Amides

This work reveals the preponderance of an intramolecular metal chelation phenomenon in a controlled radical polymerization system involving the reversible trapping of the radical chains by a cobalt complex bis(acetylacetonato)cobalt(II). The cobalt‐mediated radical polymerization (CMRP) of a series of N‐vinyl amides was considered with the aim of studying the effect of the cobalt chelation by the amide moiety of the last monomer unit of the chain. The latter reinforces the cobalt? polymer bond in the order N‐vinylpyrrolidone<N‐vinyl caprolactam<N‐methyl‐N‐vinyl acetamide, and is responsible for the optimal control of the polymerizations observed for the last two monomers. Such a double linkage between the controlling agent and the polymer, through a covalent bond and a dative bond, is unique in the field of controlled radical polymerization and represents a powerful opportunity to fine tune the equilibrium between latent and free radicals. Possible hydrogen bond formation is also taken into account in the case of N‐vinyl acetamide and N‐vinyl formamide. These results are essential for understanding the factors influencing Co? C bond strength in general, and the CMRP mechanism in particular, but also for developing a powerful platform for the synthesis of new precision poly(N‐vinyl amide) materials, which are an important class of polymers that sustain numerous applications today.     

Effects of hydrolysis conditions on the morphology,crystallinity, and thermal stability of cellulose nanocrystals extracted from kenaf bast fibers

Cellulose nanocrystals (CNC) were first isolated from kenaf bast fibers and then characterized. The raw fibers were subjected to alkali treatment and bleaching treatment and subsequent hydrolysis with sulfuric acid. The influence of the reaction time on the morphology, crystallinity, and thermal stability of CNC was investigated. Fourier transform infrared spectroscopy showed that lignin and hemicellulose were almost entirely removed during the alkali and bleaching treatments. The morphology and dimensions of the fibers and acid-released CNC were characterized by field emission scanning electron microscopy and transmission electron microscopy. X-Ray diffraction analysis revealed that the crystallinity first increases upon hydrolysis and then decreases after long durations of hydrolysis. The optimal extraction time was found to be around 40 min during hydrolysis at 45 °C with 65% sulfuric acid. The thermal stability was found to decrease as the hydrolysis time increased. The electrophoretic mobility of the CNC suspensions was measured using the zeta potential, and it ranged from −8.7 to −95.3 mV.     

A shape optimization approach for a class of free boundary problems of Bernoulli type

We are interested in an optimal shape design formulation for a class of free boundary problems of Bernoulli type. We show the existence of the optimal solution of this problem by proving continuity of the solution of the state problem with respect to the domain. The main tools in establishing such a continuity are a result concerning uniform continuity of the trace operator with respect to the domain and a recent result on the uniform Poincaré inequality for variable domains.     

Chitosan bio-based organic-inorganic hybrid aerogel microspheres

Recently, organic-inorganic hybrid materials have attracted tremendous attention thanks to their outstanding properties, their efficiency, versatility and their promising applications in a broad range of areas at the interface of chemistry and biology. This article deals with a new family of surface-reactive organic-inorganic hybrid materials built from chitosan microspheres. The gelation of chitosan (a renewable amino carbohydrate obtained by deacetylation of chitin) by pH inversion affords highly dispersed fibrillar networks shaped as self-standing microspheres. Nanocasting of sol-gel processable monomeric alkoxides inside these natural hydrocolloids and their subsequent CO(2) supercritical drying provide high-surface-area organic-inorganic hybrid materials. Examples including chitosan-SiO(2), chitosan-TiO(2), chitosan-redox-clusters and chitosan-clay-aerogel microspheres are described and discussed on the basis of their textural and structural properties, thermal and chemical stability and their performance in catalysis and adsorption.     

Fuzzy control of original UPOs of unknown discrete chaotic systems

This paper presents a fuzzy algorithm for controlling original unstable periodic orbits of unknown discrete chaotic systems. In the modeling phase, only input–output data pairs provided from the true system are required. The fuzzy model is developed using Gaussian membership functions and consequent functions where the Levenberg–Marquardt computational algorithm is employed for the model parameters calculation. In the controller design phase, the L₂-stability criterion is used, which forms the basis of the main design principle. Simulation results are given to illustrate the effectiveness and control performance of the proposed method.     

Break-Up of Aerosol Agglomerates in Highly Turbulent Gas Flow

Agglomerate aerosols in a turbulent flow may be subjected to very high turbulent shear rates which through the generation of lift and drag can overcome the adhesive forces binding the constituents of an agglomerate together and cause it to break-up. This paper presents an analysis of the experimental measurements of the breakup of agglomerates between 0.1?C10???m in size, in a turbulent pipe flow followed by an expansion zone with a Reynolds numbers in the range 10⁵ to 10⁷. The analysis shows that even in wall bounded turbulence, the high turbulent shear stresses associated with the small scales of turbulence in the core can be the main source of breakup preceding any break-up that may occur by impaction at the wall. More importantly from these results, a computationally fast and efficient solution is obtained for the General Dynamic Equation (GDE) for agglomerate transport and breakup in highly turbulent flow. Furthermore the solution for the evolution of the aerosol size distribution is consistent with the experimental results. In the turbulent pipe flow section, the agglomerates are exposed continuously to turbulent shear stresses and experience more longer term breakup than in the expansion zone (following the pipe flow) where the exposure time is much less and break-up occurs instantaneously under the action of very high local turbulent shear stresses. The validity of certain approximations made in the model is considered. In particular, the inertia of the agglomerates characterised by a Stokes Number from 0.001 for the smallest particles up to 10 for 10???m particles and the fluctuations of the turbulent shear stresses are important physical phenomena which are not accounted for in the model.     

Time-resolved velocity and concentration measurements in variable-viscosity turbulent jet flow

This paper addresses the ability to reliably measure the fluctuating velocity field in variable-viscosity flows (herein, a propane–air mixture), using hot-wire anemometry. Because the latter is sensitive to both velocity and concentration fluctuations, the instantaneous concentration field also needs to be inferred experimentally. To overcome this difficulty, we show that the hot-wire response becomes insensitive to the concentration of the field, when a small amount of neon is added to the air. In this way, velocity measurements can be made independently of the concentration field. Although not necessary to velocity measurements, Rayleigh light-scattering technique is also used to infer the local (fluctuating) concentration, and, therefore, the viscosity of the fluid. Velocity and concentration measurements are performed in a turbulent propane jet discharging into an air–neon co-flow, for which the density and viscosity ratios are 1.52 and 1/5.5, respectively. The Reynolds number (based on injection diameter and velocity) is 15400. These measurements are first validated: the axial decay of the mean velocity and concentration, as well as the lateral mean and RMS profiles of velocity and concentration, is in full agreement with the existing literature. The variable-viscosity flow along the axis of the round jet is then characterized and compared with a turbulent air jet discharging into still air, for which the Reynolds number (based on injection diameter and velocity) is 5400. Both flows have the same initial jet momentum. As mixing with the viscous co-flow is enhanced with increasing downstream position, the viscosity of the fluid increases rapidly for the case of the propane jet. In comparison with the air jet, the propane jet exhibits: (1) a lower local Reynolds number based on the Taylor microscale (by a factor of four); (2) a reduced range of scales present in the flow; (3) the isotropic form of the mean energy dissipation rate is first more enhanced and then drastically diminishes and (4) a progressively increasing local Schmidt number (from 1.36 to 7.5) for increasing downstream positions. Therefore, the scalar spectra exhibit an increasingly prominent Batchelor regime with a ~ k ^?1 scaling law. The experimental technique developed herein provides a reliable method for the study of variable-viscosity flows.     

Synthesis of Onion‐Peel Nanodendritic Structures with Sequential Functional Phosphorus Diversity

The preparation of novel families of phosphorus‐based macromolecular architectures called “onion peel” phosphorus nanodendritic systems is reported. This construct is based on the versatility of methods of synthesis using several building blocks and on the capability of these systems to undergo regioselective reactions within the cascade structure. Sustainable metal‐free routes such as the Staudinger reaction or Schiff‐base condensation, involving only water and nitrogen as byproducts, allow access to several dendritic macromolecules bearing up to seven different phosphorus units in their backbone, each of them featuring specific reactivity. The presence of the highly aurophilic P?N?P?S fragment enables selective ligation of Au^I within the dendritic framework.