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41.
Abdel Moneim El-Ghanam 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):1075-1083
3-Chloro-2-phenyl-6-p-tolyl and 3-chloro-2,6-di-p-tolyl-4H-thiopyran-4-ones have been synthesized in moderate yieldes from the reaction of 3-chloro-tetrahydrothiopyran-4-ones with phosphorus pentachloride. Their thiones, oximes, and hydrazones have been also prepared. Treatment of thiones with malononitrile gave the corresponding 3-chloro-4-thiopyrylidenemalononitriles which gave 3-chloro-spirothiopyran derivatives of pyrazole, isoxazole, 1,3-thiazines when treated with hydrazine hydrate, hydroxylamine hydrochloride, thiourea and thiosemicarbazide, respectively. While treatment of 3-chloro-thiopyrylidene-malononitriles with acetylacetone gave the corresponding 3-chloro-spirothiopyran derivatives of pyran. 相似文献
42.
Ali A. Abdel Hafez Ibrahim M. A. Awad Khairy M. Hassan 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4):219-225
Abstract Some new derivatives containing both 8-hydroxyquinoline and sulphonylamino β-lactams and thiazolidinones have been prepared. These compounds were synthesized from the corresponding 8-hydroxyquinoline sulphonylhydrazide (1) by converting it to hydrazones (2). The latter hydrazones (2) were easily transformed to β-lactams (3) and thiazolidinones (4) by cyclocondensation reaction with chloroacetyl chloride and/or mercaptoacetic acid. Some metal chelates with Fe3+. Co2++, Ni2+, Cu2+ and Cd2+ have been prepared for some of the compounds and screened in vitro for their biological activity. 相似文献
43.
Tarek A. Salama Saad S. Elmorsy Abdel‐Galel M. Khalil Margret M. Girges Abdel‐Aziz S. El‐Ahl 《合成通讯》2013,43(8):1313-1319
A combination of tetrachlorosilane and potassium cyanide (in situ trichlorosilyl cyanide) was found to work efficiently for hydrocyanation of ketones to afford the corresponding cyanohydrins in high yield under mild conditions. 相似文献
44.
Ternary Ni–Mo–P thin films have been electrodeposited from citrate‐based electrolyte onto graphite substrates for application as anode catalysts for ethanol electrooxidation. The operating deposition parameters were optimized to produce Ni–Mo–P alloy films of outstanding catalytic activity. The phase structure of the deposits was evaluated employing X‐ray diffraction technique. Morphology and chemical composition of the deposited alloy films were studied using scanning electron microscopy and energy‐dispersive X‐ray analysis, respectively. The results demonstrated that the rate of Ni–Mo–P deposition increases with increasing the ammonium molybdate concentration in the plating electrolyte up to 10 g l?1. Also, the amount of Mo in the deposits increases with increasing the ammonium molybdate concentration up to 7.5 g l?1, and the maximum Mo content in the film was 9.1 at.%. The catalytic activity of Ni–Mo–P/C alloy films has been evaluated towards electrooxidation of ethanol in 1.0 M NaOH solution by using cyclic voltammetry and chronoamperometry. The catalytic performance of the prepared anodes as a function of the amount of Mo was studied. The results showed an increase in the oxidation peak current density of ethanol with increasing the Mo at.% in the deposited alloy films. Additionally, Ni–Mo–P/C electrodes displayed significantly improved catalytic activity and stability towards electrooxidation of ethanol compared with that of Ni–P/C electrode. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
45.
Mohamed H. Taha Samir A. Abdel Maksoud Mohsen M. Ali Ahmed M. A. El Naggar Asmaa S. Morshedy Amir A. Elzoghby 《International journal of environmental analytical chemistry》2013,93(12):1211-1234
ABSTRACTThis study reports the removal of organic matters from phosphoric acid using waste-produced bio-charcoal structures. Particularly, the freshly made bio-char species via pyrolysis and two sub-driven acids activated charcoals were applied during the removal process. The treated charcoal with hydrochloric and nitric acids had attained a higher adsorption rate for organic matters than that of the non-treated one. Removal percentages of 70% and 60% were, respectively, attained by acid-modified chars. The kinetics of the adsorption process was fitted via pseudo-first/second-order and Morris–Weber models. The thermodynamic parameters of the presented sorption process indicate that organic matter removal has been endothermic, physical and spontaneous. 相似文献
46.
El Sayed H. El Ashry Laila F. Awad H. M. Abdel Hamid Atta I. Atta 《Journal of carbohydrate chemistry》2013,32(7):745-753
Microwave irradiation (MWI) has accelerated the synthesis of S‐(2,3,4,6‐tetra‐O‐acetyl‐β‐D‐glucopyranosyl)thiouronium bromide (2a), whose reaction with 2,3,4,6‐tetra‐O‐acetyl‐α‐D‐glucopyranosyl bromide (1a) in the presence of Et3N afforded stereoselectively the acetylated β,β‐1‐thiotrehalose 4a. Similarly, the respective D‐galactopyranosyl 4b and 2‐acetylamino‐2‐deoxy‐D‐glucopyranosyl 4c analog as well as 4,4′‐di‐O‐(2,3,4,6‐tetra‐O‐acetyl‐β‐D‐galactopyranosyl) 4d and 4,4′‐di‐O‐(2,3,4,6‐tetra‐O‐acetyl‐α‐D‐glucopyranosyl) 4e derivatives of 2,2′,3,3′,6,6′‐hexa‐O‐acetyl β,β‐1‐thiotrehalose were prepared. 相似文献
47.
Electroless Ni–P and Ni–P–TiCN composite coatings have been deposited successfully on Al substrates. Scanning electron microscopy (SEM) and energy dispersive X‐ray (EDX) techniques were applied to study the surface morphology and the chemical composition of the deposited films. Moreover, X‐ray diffraction (XRD) proved that Ni–P and Ni–P–TiCN deposits have amorphous structures. The properties of Ni–P–TiCN/Al composite films such as hardness, corrosion resistance and electrocatalytic activity were examined and compared with that of Ni–P/Al film. The results of hardness measurements reveal that the presence of TiCN particles with Ni–P matrix improves its hardness. Additionally, the performance against corrosion was examined using Tafel lines and electrochemical impedance spectroscopy techniques in both of 0.6 M NaCl and a mixture of 0.5 M H2SO4 with 2 ppm HF solutions. The results indicate that the incorporation of high dispersed TiCN particles into Ni–P matrix led to a positive shift of the corrosion potential and an increase in the corrosion resistance for all aluminum substrates after their coating with Ni–P–TiCN. In addition, Ni–P–TiCN/Al electrodes showed a higher electrochemical catalytic activity and stability toward methanol oxidation in 0.5 M NaOH solution compared with that of Ni–P/Al. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
48.
El-Azim M. H. M. Abd Assay M. G. Farid W. Hamid A. M. Abdel 《Russian Journal of Organic Chemistry》2022,58(4):597-603
Russian Journal of Organic Chemistry - A thiourea derivative, 4-chloro-N-[(4-chlorophenyl)carbamothioyl]benzamide, was oxidized with iodine in acetic acid to give the corresponding disulfide,... 相似文献
49.
Mahmoud Emam Doaa R. Abdel-Haleem Maha M. Salem Lina Jamil M. Abdel-Hafez Rasha R. Abdel Latif Shaimaa Mahmoud Farag Mansour Sobeh Mohamed A. El Raey 《Molecules (Basel, Switzerland)》2021,26(6)
Infections associated with the emergence of multidrug resistance and mosquito-borne diseases have resulted in serious crises associated with high mortality and left behind a huge socioeconomic burden. The chemical investigation of Lavandula coronopifolia aerial parts extract using HPLC–MS/MS led to the tentative identification of 46 compounds belonging to phenolic acids, flavonoids and their glycosides, and biflavonoids. The extract displayed larvicidal activity against Culex pipiens larvae (LC50 = 29.08 µg/mL at 72 h). It significantly inhibited cytochrome P-450 monooxygenase (CYP450), acetylcholinesterase (AChE), and carboxylesterase (CarE) enzymes with the comparable pattern to the control group, which could explain the mode of larvae toxification. The extract also inhibited the biofilm formation of Pseudomonas aeruginosa by 17–38% at different Minimum Inhibitory Concentrations (MICs) (0.5–0.125 mg/mL) while the activity was doubled when combined with ciprofloxacin (ratio = 1:1 v:v). In conclusion, the wild plant, L. coronopifolia, can be considered a promising natural source against resistant bacteria and infectious carriers. 相似文献
50.
Sherif R. Abdel-All Zeinab T. Abdel Shakour Dalia M. N. Abouhussein Enji Reda Thoraya F. Sallam Hala M. El-Hefnawy Azza R. Abdel-Monem 《Molecules (Basel, Switzerland)》2021,26(2)
The incorporation of cisplatin (CP) as a cytotoxic antineoplastic agent in most chemotherapeutic protocols is a challenge due to its toxic effect on testicular tissues. Natural compounds present a promising trend in research, so a new nutraceutical formulation (NCF) was designed to diminish CP spermatotoxicity. A combination of three nutraceutical materials, 250 mg Spirulina platensis powder (SP), 25 mg Tribulus terrestris L. extract (TT), and 100 mg fish oil (FO) were formulated in self-nanoemulsifying self-nanosuspension (SNESNS). SP was loaded into the optimized self-nanoemulsifying system (30% FO, 50% span 80/cremophor EL and 20% isopropanol) and mixed with TT aqueous solution to form SNESNS. For the SP, phytochemical profiling revealed the presence of valuable amounts of fatty acids (FAs), amino acids, flavonoids, polyphenols, vitamins, and minerals. Transmission electron microscopy (TEM) and particle size analysis confirmed the formation of nanoemulsion-based nanosuspension upon dilution. Method validation of the phytochemical constituents in NCF has been developed. Furthermore, NCF was biologically evaluated on male Wistar rats and revealed the improvement of spermatozoa, histopathological features, and biochemical markers over the CP and each ingredient group. Our findings suggest the potential of NCF with SNESNS as a delivery system against CP-induced testicular toxicity in male rats. 相似文献