全文获取类型
收费全文 | 846篇 |
免费 | 62篇 |
国内免费 | 3篇 |
专业分类
化学 | 697篇 |
晶体学 | 11篇 |
力学 | 23篇 |
数学 | 67篇 |
物理学 | 113篇 |
出版年
2022年 | 22篇 |
2021年 | 20篇 |
2020年 | 26篇 |
2019年 | 65篇 |
2018年 | 29篇 |
2017年 | 18篇 |
2016年 | 41篇 |
2015年 | 26篇 |
2014年 | 31篇 |
2013年 | 87篇 |
2012年 | 68篇 |
2011年 | 45篇 |
2010年 | 35篇 |
2009年 | 25篇 |
2008年 | 18篇 |
2007年 | 27篇 |
2006年 | 27篇 |
2005年 | 24篇 |
2004年 | 31篇 |
2003年 | 26篇 |
2002年 | 34篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1997年 | 5篇 |
1996年 | 8篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 5篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 3篇 |
1979年 | 5篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1973年 | 5篇 |
1972年 | 2篇 |
1961年 | 2篇 |
1960年 | 2篇 |
1959年 | 2篇 |
排序方式: 共有911条查询结果,搜索用时 203 毫秒
71.
W.S. Abdel Halim 《Applied Surface Science》2007,253(22):8974-8980
The adsorption of carbon monoxide at the defect-free (1 0 0), (1 1 0) and (2 1 0) five-atomic layer slab of the three oxides: MgO, CaO, and SrO has been investigated using the periodic Hartree-Fock level of ab initio theory, together with the 1 × 1 supercell model. All the calculated CO/oxide interaction energies exhibit exothermic character. The HF interaction energies increase monotonically in the order MgO < CaO < SrO. The surface morphology of adsorbate/substrate interaction is confirmed by considering relaxation energies, Mulliken population analysis, charge density contours, and electrostatic potential maps. 相似文献
72.
The effects of surface tension and adsorption on the electrohydrodynamic Kelvin-Helmholtz instability are studied. The system is stressed by a normal electric field such that it allows for the presence of surface charges at the interface. The method used is that of multiple scales. The nonlinear Schrödinger equation describing the behavior of the disturbed system is derived. The stability of the perturbed system is discussed both analytically and numerically and the stability diagrams are obtained. At the critical point, a generalized formulation of the evolution equation is developed, which leads to the nonlinear Klein-Gordon equation. The various stability criteria are derived from this equation. 相似文献
73.
74.
B. A. Kader 《Fluid Dynamics》1977,12(2):307-310
The question of determining the law of damping for the turbulent diffusion coefficient at a smooth wall according to data on mass and heat transfer for Pr 1 is discussed. It is proved that the hypothesis that this law is determined by the first member of the Taylor series expansion of , namely, / = yn
+ is valid in the Pr range from 103 to 105 only under the assumption that the subsequent terms in the expansion have smaller coefficients. A statistical analysis of electrochemical and other experiments devoted to this problem shows that apparently n = 3, but singularities in the experimental results do not permit making a final conclusion. Requirements on a conclusive experiment are formulated on the basis of the analysis made.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 172–175, March–April, 1977. 相似文献
75.
Exploiting the 1,2,3‐Triazole Moiety to Generate Carbazole Molecular Architectures through Click Approach
下载免费PDF全文
![点击此处可从《Journal of heterocyclic chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Mohamed A. Ameen Kamal M. El‐Shaieb Asmaa H. Mohamed Fathy F. Abdel‐Latif 《Journal of heterocyclic chemistry》2015,52(6):1718-1722
Reaction of 3,6‐dichlorocarbazole with propargyl bromide in the presence of a basic medium gave an N‐propargylated carbazole. The latter compound was converted into molecular architectures containing 1,2,3‐triazole moiety through Cu(I)‐catalyzed 1,3‐cycloaddition reaction with different azides. Similarly, 2‐azidomethyl benzothiazole was cliched with N‐Boc‐protected N´‐propargyl glutamate to give the biomolecule 2‐triazolylmethyl product. 相似文献
76.
Aziz N. Abdel 《Fluid Dynamics》1993,28(5):736-738
The phenomenon of thermal relaxation of the gas bubbles in a fluid behind a shock front is analyzed. The approach to solving the problem of heat transfer between a gas bubble and a fluid developed by the author is used to obtain a solution describing the initial stage of bubble collapse behind the shock front.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 5, pp. 187–189, September–October, 1993. 相似文献
77.
Synthesis,Reactions, Characterization and Biological Evaluation of 2,3′‐Bipyridine Derivatives (III)
下载免费PDF全文
![点击此处可从《Journal of heterocyclic chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Fawzy A. Attaby Azza M. Abdel‐Fattah Labeeb M. Shaif Mohamed M. Elsayed 《Journal of heterocyclic chemistry》2014,51(4):927-936
1‐Pyridin‐3‐yl‐3‐(2‐thienyl of 2‐furyl)prop‐2‐en‐1‐ones 1a , 1b reacted with 2‐cyanoethanethioamide 2 to afford the corresponding 4‐(thiophen‐2‐yl or furan‐2‐yl)‐6‐sulfanyl‐2,3′‐bipyridine‐5‐carbonitriles 3a , 3b . The synthetic potentiality of compounds 3a , 3b were investigated in the present study via their reactions with several active halogen containing compounds 4a , 4b , 4c , 4d , 4e , 4f , 4g , 4h , 5 , 5a , 5b . Our aim here is the synthesis of 4‐(2‐thienyl or 2‐furyl)‐6‐pyridin‐3‐ylthieno[2,3‐b]pyridin‐3‐amines 6a , 6b , 6c , 6d , 6e , 6g , 6h , 6i , 6j , 6k , 6l , 6m , 6n ,via 6‐(alkyl‐thio)‐4‐(2‐thienyl or 2‐furyl)‐2,3′‐bipyridine‐5‐carbonitriles 5a , 5b , 5c , 5d , 5e , 5i , 5j , 5k , 5l , 5m . The structures of all newly synthesized heterocyclic compounds were elucidated by considering the data of IR, 1H‐NMR, mass spectra, as well as that of elemental analyses. Anti‐cancer, anti‐Alzheimer, and anti‐COX‐2 activities were investigated for all the newly synthesized heterocyclic compounds. 相似文献
78.
Synthesis of Novel Modified Guanidines: Reaction of Dicyandiamide with Amino Acids,Amides, and Amines in Aqueous Medium
下载免费PDF全文
![点击此处可从《Journal of heterocyclic chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ahmed M. Soliman Shaaban K. Mohamed Mahmoud. Abd El Aleem. Ali. Ali. El‐Remaily H. Abdel‐Ghany 《Journal of heterocyclic chemistry》2014,51(5):1322-1326
Reaction of dicyandiamide with series of amino acids afforded guanidinyl pyrazolones 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 , respectively. Although reaction of dicyandiamide with urea, acetamide, bezamide, allantion, p‐aminobenzoic acid, sulphanilic acid, and adenine gave biguanides 20 , 21 , 22 , 23 , 24 , 25 , 26 , respectively. All compounds have been characterized on the basis of IR and 1H‐NMR. 相似文献
79.
Ahmed M. M. Soliman Mahmoud. Abd El‐Aleem. Ali. Ali. El‐Remaily Adel. A. Sultan Hossam. Abdel‐Ghany 《Journal of heterocyclic chemistry》2014,51(5):1476-1481
5‐Amino‐3‐anilino‐1H‐pyrazole‐4‐carbonitrile 1 was alkylated with various halo reagents under phase transfer conditions to give the corresponding imidazopyrazole derivatives 2a , 2b , 2c , 3 , 4 , 5 , 6 . Pyrazolo[1,5‐a] pyrimidine derivatives 11 , 12 , 13 , 14 were prepared by treating compound 1 with different dicarbonyl reagents, namely, diethymalonate, ethyl 3‐oxo‐3‐phenylpropanoate, pentane‐2,4‐dione or ethyl 3‐oxobutanoate. 相似文献
80.
The aim of the present study was to determine the content of capsaicin and dihydrocapsaicin in Capsicum samples collected from city markets in Riyadh (Saudi Arabia), calculate their pungency in Scoville heat units (SHU) and evaluate the average daily intake of capsaicin for the population of Riyadh. The investigated samples consisted of hot chillies, red chillies, green chillies, green peppers, red peppers and yellow peppers. Extraction of capsaicinoids was done using ethanol as solvent, while high performance liquid chromatography (HPLC) was used for separation, identification and quantitation of the components. The limit of detection (LOD) of the method was 0.09 and 0.10 μg/g for capsaicin and dihydrocapsaicin, respectively, while the limit of quantification (LOQ) was 0.30 and 0.36 μg/g for capsaicin and dihydrocapsaicin, respectively. Hot chillies showed the highest concentration of capsaicin (4249.0 ± 190.3 μg/g) and the highest pungency level (67984.60 SHU), whereas green peppers had the lowest detected concentration (1.0 ± 0.9 μg/g); green peppers, red peppers and yellow peppers were non pungent. The mean consumption of peppers for Riyadh city population was determined to be 15.5 g/person/day while the daily capsaicin intake was 7.584 mg/person/day. 相似文献