全文获取类型
收费全文 | 11467篇 |
免费 | 2005篇 |
国内免费 | 2580篇 |
专业分类
化学 | 8858篇 |
晶体学 | 179篇 |
力学 | 709篇 |
综合类 | 169篇 |
数学 | 1473篇 |
物理学 | 4664篇 |
出版年
2024年 | 38篇 |
2023年 | 262篇 |
2022年 | 479篇 |
2021年 | 499篇 |
2020年 | 539篇 |
2019年 | 519篇 |
2018年 | 417篇 |
2017年 | 471篇 |
2016年 | 612篇 |
2015年 | 662篇 |
2014年 | 712篇 |
2013年 | 957篇 |
2012年 | 874篇 |
2011年 | 972篇 |
2010年 | 750篇 |
2009年 | 733篇 |
2008年 | 837篇 |
2007年 | 697篇 |
2006年 | 638篇 |
2005年 | 621篇 |
2004年 | 496篇 |
2003年 | 407篇 |
2002年 | 439篇 |
2001年 | 362篇 |
2000年 | 317篇 |
1999年 | 264篇 |
1998年 | 198篇 |
1997年 | 144篇 |
1996年 | 161篇 |
1995年 | 119篇 |
1994年 | 151篇 |
1993年 | 118篇 |
1992年 | 92篇 |
1991年 | 108篇 |
1990年 | 98篇 |
1989年 | 47篇 |
1988年 | 43篇 |
1987年 | 34篇 |
1986年 | 38篇 |
1985年 | 39篇 |
1984年 | 15篇 |
1983年 | 23篇 |
1982年 | 12篇 |
1981年 | 11篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1978年 | 3篇 |
1964年 | 2篇 |
1957年 | 3篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
21.
In this paper, a successive supersymmetric rank‐1 decomposition of a real higher‐order supersymmetric tensor is considered. To obtain such a decomposition, we design a greedy method based on iteratively computing the best supersymmetric rank‐1 approximation of the residual tensors. We further show that a supersymmetric canonical decomposition could be obtained when the method is applied to an orthogonally diagonalizable supersymmetric tensor, and in particular, when the order is 2, this method generates the eigenvalue decomposition for symmetric matrices. Details of the algorithm designed and the numerical results are reported in this paper. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
22.
A uniqueness theorem for two distinct non-constant meromorphic functions that share three values of finite weights is proved, which generalizes two previous results by H.X. Yi, and X.M. Li and H.X. Yi. As applications of it, many known results by H.X. Yi and P. Li, etc. could be improved. Furthermore, with the concept of finite-weight sharing, extensions on Osgood-Yang's conjecture and Mues' conjecture, and a generalization of some prevenient results by M. Ozawa and H. Ueda, ect. could be obtained. 相似文献
23.
24.
荧光光谱法研究蛋白质构象的电磁-温度协同效应 总被引:1,自引:1,他引:0
长期以来电磁生物效应受到人们普遍关注,近年来从各个角度进行了相关研究。电磁-温度协同效应是当前的热点。本研究通过电磁场及温度协同对蛋白质影响的研究,发现蛋白质在电磁场作用下的不可逆变性,而且这种变性也遵循Arrhenius规律,并进一步得出电磁-温度协同作用的蛋白质变性模型。本文从分子反应动力学的角度解释了电磁-温度协同效应,并对非热效应作了一定的探讨。 相似文献
25.
枸橼酸莫沙必利的合成 总被引:1,自引:0,他引:1
分别以邻羟基对氨基苯甲醇钠,对氟苯甲醛,邻苯二甲酰亚胺为起始原料,制得3个中间体,用其中2个中间体经偶合,环化后与第3个中间体反应,再经成盐制得产品,其摩尔总收率为31.5%。 相似文献
26.
Hui-Ling Li De-Jiang Qi Qing-Quan Jiang Shu-Zheng Yang 《International Journal of Theoretical Physics》2006,45(12):2428-2436
An extension of the Parikh-Wilczek's semi-classical quantum tunneling method, the tunneling radiation of the charged particle from a torus-like black hole is investigated. Difference from the uncharged mass-less particle, the geodesics of the charged massive particle tunneling from the black hole is not light-like, but determined by the phase velocity. The derived result shows that the tunneling rate depends on the emitted particle's energy and electric charge, and takes the same functional form as uncharged particle. It proves also that the exact emission spectrum is not strictly pure thermal, but is consistent with the underlying unitary theory.
PACS Numbers: 04.70.Dy, 97.60.Lf, 05.30.Ch. 相似文献
27.
ONOO-活性氧的荧光光谱分析进展 总被引:1,自引:0,他引:1
系统介绍了ONOO^-活性氧的化学性质,并对其参与的主要化学反应进行了分类和总结.同时,比较了近年来用于ONOO^-检测的方法,并重点论述了荧光光谱分析方法尤其是酶催化动力学荧光分析法在检测ONOO^-活性氧方面的优势和最新的研究进展. 相似文献
28.
Liqun Qi 《Operations Research Letters》1997,20(5):223-228
We show that strong differentiability at solutions is not necessary for superlinear convergence of quasi-Newton methods for solving nonsmooth equations. We improve the superlinear convergence result of Ip and Kyparisis for general quasi-Newton methods as well as the Broyden method. For a special example, the Newton method is divergent but the Broyden method is superlinearly convergent. 相似文献
29.
A Novel and Efficient Catalytic System for Aerobic Oxidative Coupling of 2-Naphthol Derivatives 总被引:2,自引:0,他引:2
LiCHEN JingBoLAN ZhiHuaMAO XiaoQiYU RuGangXIE 《中国化学快报》2004,15(8):903-906
The paper reported a novel and efficient aerobic oxidative coupling reaction of 2-naphthol derivatives catalyzed by CuCu (Ⅰ or Ⅱ)N-alkylimidazole complexes in excellent yields. The crystal structure of CuCu(Ⅱ)N-methylimidazole complex to be determined by X-Ray. 相似文献
30.
Qi Sheng Liu Lian Dong Liu Jing Min Shi 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(1):m58-m60
In the title centrosymmetric binuclear complex, [Cd2(C17H11N3O)4(H2O)2](ClO4)4, the CdII ion assumes a distorted octahedral geometry. There are π–π stacking interactions between the pyridine and 1,10‐phenanthroline ring systems of adjacent ligands at the same CdII centre. Intermolecular hydrogen bonds between the coordinated aqua ligand and the O atom of a keto group connect adjacent complex cations into extended chains. Hydrogen bonds also exist between the complex cations and the perchlorate anions. Compared with the fluorescence spectrum of the organic ligand, the complex displays strong fluorescent emission and an ipsochromic shift of the emission peaks, which may be attributed to the structural character. 相似文献