Intermolecular interactions of polymethacrylic acid with N-alkyl-1,3-propanediamine

The relation between Coulomb and hydrophobic interactions in the development of associative processes is established on the basis of the concentration dependences of pH for binary solutions of anionic polyelectrolyte-polymethacrylic acid and cationic surfactant-N-alkyl-1,3-propanediamine. It is demonstrated that the criterion for determining the predominant contribution from either Coulomb or hydrophobic interactions is the maximum for the dependence of the pH difference between individual solutions of N-alkyl-1,3-propanediamine and binary solutions of polymethacrylic acid and N-alkyl-1,3-propanediamine on the logarithm of the product of their concentrations.     

The low frequency vibrations of hydrogen bonded adipic acid crystals

The low frequency vibrational spectrum of crystalline adipic acid has been investigated in the range 20–450 cm⁻¹ at room and low temperatures. The experimental results are compared to ab initio results on a model asymmetric unit. It is shown that the doublet and quartet structures observed for several bands are due to Davydov splitting and Fermi resonance effects.     

Working group report: Heavy-ion physics and quark-gluon plasma

This is the report of Heavy Ion Physics and Quark-Gluon Plasma at WHEPP-09 which was part of Working Group-4. Discussion and work on some aspects of quark-gluon plasma believed to have created in heavy-ion collisions and in early Universe are reported.     

Correlation between the energy of SiGe nanoislands and their shape and size

The total energy of self-assembled SiGe nanoislands on a silicon substrate is investigated theoretically as a function of their geometric and physical parameters. It is demonstrated that the growth temperature and the silicon content in nanoislands affect the minimum of their energy. The results of numerical calculations for nanoislands are compared with experimental data obtained by atomic-force microscopy.     

The effect of poly(methacrylic acid) on electrosurface properties of titanium dioxide in aqueous suspensions

The electrosurface properties and aggregation stability of aqueous titanium-dioxide suspensions are studied in wide ranges of medium pH values and poly(methacrylic acid) concentrations. Using the 2pK model, the ionization constants of surface hydroxyl groups of titanium dioxide are found and it is established that the adsorption of poly(methacrylic acid) macromolecules substantially decreases the fraction of neutral (uncharged) hydroxyl groups and affects the ratio between the positively and negatively charged surface hydroxyl groups.     

A generalization of the Poisson integral formula for the functions harmonic and biharmonic in a ball

We construct an analytic solution to the problem of extension to the unit N-dimensional ball of the potential on its values on an interior sphere. The formula generalizes the conventional Poisson formula. Bavrin’s results obtained for the two-dimensional case by methods of function theory are transferred to the N-dimensional case (N ≥ 3). We also exhibit a solution to a similar extension problem for some operator expressions depending on a potential known on an interior sphere. A connection is established between solutions to the moment problem on a segment and on a semiaxis.     

Astrophysical S-factors from asymptotic normalization coefficients

S-factors for direct capture reactions can be found at astrophysical energies from asymptotic normalization coefficients which provide the normalization of the tail of the overlap function. For example the overlap for ⁸B → ⁷Be+p defines the S-factor for ⁷Be (p, γ)⁸B. Peripheral transfer reactions offer a technique to determine these asymptotic normalization coefficients. As a test of the technique, the ¹⁶O(³He, d)¹⁷F reaction has been used to determine asymptotic normalization coefficients for transitions to the ground and first excited states of ¹⁷F. The S-factors for ¹⁶O(p, γ)¹⁷F calculated from these ¹⁷F → ¹⁶O+p asymptotic normalization coefficients are found to be in very good agreement with recent measurements. Following the same technique, the ¹⁰B(⁷Be, ⁸B)⁹Be and ¹⁴N(⁷Be, ⁸B)¹³C reactions have been used to measure the asymptotic normalization coefficient for ⁷Be(p, γ)⁸B. This result provides an indirect determination of S ₁₇(0).     

Gas-phase deprotonation of arylalkylamines. A collision-induced dissociation study

The collision-induced dissociation (CID) of deprotonated arylalkylamines of general formula R(1)C(6)H(4)CHR(2)CH(2)NR(3)(2) (where R(1) = H, OH, F or NO(2); R(2) = H or OH; R(3) = H or CH(3)) generated by negative chemical ionization with H(2)O and D(2)O as ionizing reagents, is discussed. The negative chemical ionization mass spectra show that, in the absence of a hydroxy group in the aromatic ring, deprotonation takes place at the benzylic position whereas the proton is lost from the OH group when present. The nitro compound forms only M(-.) ions. The CID spectra of the deprotonated molecules show that fragmentations are strongly dependent on the structural features of the molecules, namely the presence or absence of substituents in the aromatic ring or aliphatic chain. Copyright 1999 John Wiley & Sons, Ltd.     

Isolation of NO(3)(-)-N as 1-phenylazo-2-naphthol (Sudan-1) for measurement of delta(15)N

The conversion of nitrate (NO(3)(-)) to 1-phenylazo-2-naphthol (Sudan-1) has been examined as a method for natural abundance measurement of delta(15)N of NO(3)(-). The reaction results in dilution of NO(3)(-)-N with only one reagent-derived N and the product is readily concentrated from dilute samples by reverse phase chromatography. There is systematic isotopic fractionation during the reaction, but this can be allowed for by analysing known NO(3)(-) standards along with each sample set. Sudan-1 prepared from surface water samples containing approximately 50 &mgr;g NO(3)(-)-N can be analysed by automated continuous flow isotope ratio mass spectrometry with a precision of 0.2 per thousand (one standard deviation) and the accuracy is not affected by interference from other nitrogenous species in the sample or reagents. Copyright 1999 John Wiley & Sons, Ltd.