Optimal component replacement decisions using vibration monitoring and the proportional-hazards model

This paper describes a case study in which the Weibull proportional-hazards model is used to determine the optimal replacement policy for a critical item which is subject to vibration monitoring. Such an approach has been used to date in the context of monitoring through oil debris analysis, and this approach is extended in this paper to the vibration monitoring context. The Weibull proportional-hazards model is reviewed along with the software EXAKT used for optimization. In particular the case considers condition-based maintenance for circulating pumps in a coal wash plant that is part of the SASOL petrochemical company. The condition-based maintenance policy recommended in this study is based on histories collected over a period of 2 years, and is compared with current practice. The policy is validated using data that arose from subsequent operation of the plant.     

Observation of uncorrelated microscopic motion in a strongly interacting adsorbate system

Modeling of intermolecular forces is a central theme in the physical sciences. The prototypical heterogeneous catalysis system, CO/Pt(111), is an extensively studied example where strong pairwise repulsive forces between the CO molecules have been used to explain the observed structure and dynamics. No direct measurements of these forces were available; yet, they offered a natural way of explaining various macroscopic observations assuming a separable adsorbate-substrate interaction and pairwise adsorbate-adsorbate interactions. In the present study, we measure intermolecular forces by following CO motion on a microscopic scale. The uncorrelated dynamics we observe throughout the coverage range of the measurements excludes the existence of the strong pairwise forces previously suggested. The increase in the rate of uncorrelated motion is explained by a nonlocal modification of the adsorbate-substrate interaction, reflecting a many-body system that cannot be described by the standard separable interaction approach.     

Analysis and refinement of the Cu(001) c(2 x 2)CO-He potential using (3)He selective adsorption resonances

Measurements of (3)He scattering from the Cu(001)c(2 x 2)CO surface using (3)He spin-echo spectroscopy show a number of selective adsorption resonance features. The features cannot be reproduced by close coupled scattering calculations based on the existing Cu(001)c(2 x 2)CO-He interaction potential. An empirical potential is created by adjusting the shape, depth, and width of the existing potential to improve agreement with the experimental data.     

The computation of some molecular weights

A method is described for deducing the molecular weight of a compound, the mass spectrom of which does not extend as far as the molecular weight, It is based upon the combination of fragment ions and restricted to limits determined by an approximate estimate of that weight.     

Self-esterification of fulvic acid model compounds in methanolic solvents as observed by electrospray ionization mass spectrometry

The self-esterification of two fulvic acid model compounds in methanolic solvents was studied by electrospray ionization mass spectrometry (ESI-MS). The strongly acidic tetrahydrofurantetracarboxylic acid rapidly self-esterified to form mono- and dimethyl esters when stored in methanol, even at reduced temperatures. The weakly acidic analogue, cyclopentanetetracarboxylic acid, reacted minimally under the same conditions. The use of 50:50 methanol/water as a solvent reduced self-esterification of the strong acid. However, the presence of water promoted the formation of multiply charged ions in the ESI mass spectra. The use of water and 50:50 acetonitrile/water as solvents eliminated self-esterification but the mass spectra still contained multiply charged ions. This study implies that the use of methanolic solvents with humic substances may compromise analytical data through the formation of methyl esters.