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Li M Lan Y Ako AM Wernsdorfer W Anson CE Buth G Powell AK Wang Z Gao S 《Inorganic chemistry》2010,49(24):11587-11594
We present the syntheses, crystal structures, and magnetochemical characterizations for a family of isostructural [Mn(4)Ln(4)] compounds (Ln = Sm, Gd, Tb, Dy, Ho, Er, and Y). They were prepared from the reactions of formic acid, propionic acid, N-n-butyl-diethanolamine, manganese perchlorate, and lanthanide nitrates under the addition of triethylamine in MeOH. The compounds possess an intriguing hetero-octanuclear wheel structure with four Mn(III) and four Ln(III) ions alternatively arranged in a saddle-like ring, where formate ions act as key carboxylate bridges. In the lattice, the molecules stack into columns in a quasi-hexagonal arrangement. Direct current (dc) magnetic susceptibility measurements indicated the depopulation of the Stark components at low temperature and/or very weak antiferromagnetic interactions between magnetic centers. The zero-field alternating current (ac) susceptibility studies revealed that the compounds containing Sm, Tb, and Dy showed frequency-dependent out-of-phase signals, indicating they are single-molecule magnets (SMMs). Magnetization versus applied dc field sweeps on a single crystal of the Dy compound down to 40 mK exhibited hysteresis depending on temperatures and field sweeping rates, further confirming that the Dy compound is a SMM. The magnetization dynamics of the Sm and Y compounds investigated under dc fields revealed that the relaxation of the Sm compound is considered to be dominated by the two-phonon (Orbach) process while the Y compound displays a multiple relaxation process. 相似文献
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A de Bettencourt-Dias S Bauer S Viswanathan BC Maull AM Ako 《Dalton transactions (Cambridge, England : 2003)》2012,41(36):11212-11218
A new ligand family based on picoline, bipyridine and terpyridine containing a nitro moiety has been synthesized and its coordination and sensitization ability for lanthanide ions has been studied. Three new complexes were characterized by X-ray single crystal diffraction and all three show uncommon coordination of the nitro moiety to the lanthanide ion. , a terpyridine-nitro derivative with Tb(NO(3))(3), crystallizes in the orthorhombic space group Pbca with a = 15.125(3), b = 13.776(3), c = 18.716(4) ?, and V = 3899.8(13) ?(3) and is isostructural with its Eu(iii) analog () with cell parameters a = 15.1341(4), b = 13.7070(4), c = 18.8277(5) ?. , a tripodal amine with a nitro-derivatized pyridine with Eu(CF(3)SO(3))(3), crystallizes in the triclinic space group P1[combining macron] with a = 11.067(2), b = 11.633(2), c = 12.772(3) ?, α = 110.94(3), β = 97.49(3), γ = 91.42(3)° and V = 1518.1(5) ?(3). Finally, ligand , a bipyridine-nitro derivative, crystallizes in the orthorhombic space group P2(1)/n with a = 3.7128(3), b = 11.7806(8), c = 19.9856(14) ?, β = 92.925(2)° and V = 873.01(11) ?(3). All four ligands show sensitization of Eu(iii) and Tb(iii) luminescence. 相似文献
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Munshi G Mustafa Sudhir Raniwala T Awes B Rai RS Bhalerao JG Contreras RV Gavai SK Ghosh P Jaikumar GC Mishra AP Mishra H Mishra B Mohanty J Nayak J-Y Ollitrault SC Phatak L Ramello R Ray PK Sahu AM Srivastava DK Srivastava VK Tiwari 《Pramana》2006,67(5):961-981
This is the report of Heavy Ion Physics and Quark-Gluon Plasma at WHEPP-09 which was part of Working Group-4. Discussion and
work on some aspects of quark-gluon plasma believed to have created in heavy-ion collisions and in early Universe are reported. 相似文献
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A detailed study is undertaken to analyze the non-steady interaction of plane progressive pressure pulses with an isotropic, homogeneous, fluid-filled and submerged spherical elastic shell of arbitrary wall thickness within the scope of linear acoustics. The formulation is based on the general three dimensional equations of linear elasticity and the wave equation for the internal and external acoustic domains. The Laplace transform with respect to the time coordinate is invoked, and the classical method of separation of variables is used to obtain the transformed solutions in the form of partial-wave expansions in terms of Legendre polynomials. The inversion of Laplace transforms have been carried out numerically using Durbin’s approach based on Fourier series expansion. Special convergence enhancement techniques are invoked to completely eradicate spurious oscillations (Gibbs’ phenomenon), and obtain uniformly convergent solutions. Detailed numerical results for the transient and vibratory responses of water-submerged steel shells of selected wall thickness parameters with various internal fluid loadings under an exponential wave excitation are presented. Many of the interesting dynamic features in the transient shell–shock interaction such as shock transparency, shell-radiated negative pressure waves, formation of triple points, and focusing of the reflected waves are examined using appropriate 2D images of the internal pressure field. Also, the temporal behavior of the specularly-reflected, the lowest symmetric S0- and antisymmetric A0-Lamb waves, as well as appearance of the Franz’s creeping waves are discussed through proper visualization of the external scattered field. Likelihood of cavitation is addressed and regions proned to cavitation are identified. Moreover, the effects of internal fluid impedance in addition to shell wall thickness on the dynamic stress concentrations induced within the shell are analyzed. Limiting cases are considered and fair agreements with well-known solutions are established. 相似文献
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Hagen Kaemmerer Dr. Valeriu Mereacre Dr. Ayuk M. Ako Dr. Samir Mameri Dr. Christopher E. Anson Dr. Rodolphe Clérac Prof. Annie K. Powell 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(61):15096-15102
In an assisted self-assembly approach starting from the [Mn6O2(piv)10(4-Me-py)2(pivH)2] cluster a family of Mn−Ln compounds (Ln=Pr−Yb) was synthesised. The reaction of [Mn6O2(piv)10(4-Me-py)2(pivH)2] ( 1 ) with N-methyldiethanolamine (mdeaH2) and Ln(NO3)3 ⋅ 6H2O in MeCN generally yields two main structure types: for Ln=Tb−Yb a previously reported Mn5Ln4 motif is obtained, whereas for Ln=Pr−Eu a series of Mn7Ln3 clusters is obtained. Within this series the GdIII analogue represents a special case because it shows both structural types as well as a third Mn2Ln2 inverse butterfly motif. Variation in reaction conditions allows access to different structure types across the whole series. This prompts further studies into the reaction mechanism of this cluster assisted self-assembly approach. For the Mn7Ln3 analogues reported here variable-temperature magnetic susceptibility measurements suggest that antiferromagnetic interactions between the spin carriers are dominant. Compounds incorporating Ln=NdIII( 2 ), SmIII( 3 ) and GdIII ( 5 ) display SMM behaviour. The slow relaxation of the magnetisation for these compounds was confirmed by ac measurements above 1.8 K. 相似文献
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