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31.
32.
Dr. Allan Jay P. Cardenas Bojana Ginovska Dr. Neeraj Kumar Dr. Jianbo Hou Dr. Simone Raugei Dr. Monte L. Helm Dr. Aaron M. Appel Dr. R. Morris Bullock Dr. Molly O'Hagan 《Angewandte Chemie (International ed. in English)》2016,55(43):13509-13513
The fastest synthetic molecular catalysts for H2 production and oxidation emulate components of the active site of hydrogenases. The critical role of controlled structural dynamics is recognized for many enzymes, including hydrogenases, but is largely neglected in designing synthetic catalysts. Our results demonstrate the impact of controlling structural dynamics on H2 production rates for [Ni(PPh2NC6H4R2)2]2+ catalysts (R=n‐hexyl, n‐decyl, n‐tetradecyl, n‐octadecyl, phenyl, or cyclohexyl). The turnover frequencies correlate inversely with the rates of chair–boat ring inversion of the ligand, since this dynamic process governs protonation at either catalytically productive or non‐productive sites. These results demonstrate that the dynamic processes involved in proton delivery can be controlled through modification of the outer coordination sphere, in a manner similar to the role of the protein architecture in many enzymes. As a design parameter, controlling structural dynamics can increase H2 production rates by three orders of magnitude with a minimal increase in overpotential. 相似文献
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34.
G. Cardenas‐Jiron D. Leal B. Matsuhiro I. O. Osorio‐Roman 《Journal of Raman spectroscopy : JRS》2011,42(4):870-878
The tetrasaccharide of 1 → 4β‐D‐mannopyranuronate (MM) and the alternating tetrasaccharide of 1 → 4 b‐D‐mannopyranuronate and 1 → 4α‐L‐gulopyranuronate (MG) were analyzed based on density functional theory (DFT) by employing the Gaussian 03 W package. The molecular geometries were fully optimized by using the Becke's three‐parameter hybrid exchange functional combined with Lee–Yang–Parr correlation functional (B3LYP) and using a 6‐31G(d,p) basis set. The calculated IR spectrum of MM presents a band at 1093 cm−1 for C C stretching vibration, which is in good agreement with the experimental observation (1096 cm−1) for the polymannuronate fraction obtained by partial hydrolysis of sodium alginate extracted from the hybrid brown seaweed Lessonia–Macrocystis. The calculated value at 826 cm−1for MM is in close agreement with the experimental value and confirms that this band is characteristic of polymannuronate blocks. Most of the bands in the IR spectrum are also present in the observed Raman spectrum of the polymannuronate fraction. The experimental IR spectrum of heteropolymeric fraction obtained by partial hydrolysis of sodium alginate shows absorbances similar to those calculated for the model tetrasaccharide (MG). Surface‐enhanced Raman scattering (SERS) allows differentiation between the homopolymeric and heteropolymeric fractions of sodium alginate. The SERS spectrum of the heteropolymeric fraction shows an enhanced signal at 731 cm−1which is present in the calculated Raman spectrum of the tetrasaccharide MG at 729 cm−1. This band is assigned to the ring‐breathing deformation of the β‐D‐mannopyranuronate and α‐L‐gulopyranuronate residues. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
35.
Wienkers M Ramos J Jemal H Cardenas C Wiget P Nelson A Free S Wu J Roach R Vulcan M Waynant K Fort K Vladimirova A Sun J Hunt SE Rudkevich DM Starnes SD 《Organic letters》2012,14(6):1370-1373
We present a fortuitous discovery of enhanced shape-selective recognition of anion guests that stems from a complexation-induced conformational change in porphyrin hosts upon anion binding. Porphyrin hosts reported here exist in a conformation that is not favorable to guest binding. Anions that bind strongly are those that can induce a conformational change in the host to allow guest binding. Furthermore, guests that mimic the shape of the newly formed pocket bind the strongest. 相似文献
36.
A procedure is explained to determined the amount of several pairs of diametrical loads applied to the outside boundary of
a ring when stresses at selected points of the inside or outside boundaries are known. Coefficients of influence are used,
following an approach similar to the one presented in a previous paper. Examples of application are given and the possible
increase in precision is shown when the number of points of measurements is larger than the number of loads to be determined. 相似文献
37.
J. N. Cardenas K. F. O'Driscoll 《Journal of polymer science. Part A, Polymer chemistry》1976,14(4):883-897
The concept of polymer entanglements has been applied in conjunction with classical free-radical kinetics to describe vinyl polymerizations carried to high conversion. A kinetic model has been developed on the assumption that two populations of radicals exist in a high-conversion polymerization system: those radicals whose chain lengths are long enough to become entangled with neighboring molecules and have, therefore, a restricted mobility; and those shorter radicals whose mobilities are not strongly affected by diffusional effects. It has also been assumed that the kinetic rate constant for the termination step between entangled radicals is inversely proportional to the mean entanglement density. The model contains only two parameters in addition to the kinetic rate constants required to describe low-conversion polymerizations. One of these parameters can be determined, at least in principle, from measurements of solution properties of the polymer-monomer mixtures. The model so developed has been tested against experimental data obtained from the literature on the bulk polymerization of methyl methacrylate. The agreement between predicted and experimental monomer conversions and molecular weight averages is found to be satisfactory. 相似文献
38.
O. Tapia R. Cardenas J. Anders J. Krechl M. Campillo F. Colonna-Cesari 《International journal of quantum chemistry》1991,39(6):767-786
Electronic aspects of the catalytic mechanism of liver alcohol dehydrogenase (LADH) are studied with the help of ab initio analytical gradient SCF MO methods. Three points are considered: (i) role of the catalytic zinc; (ii) geometry and electronic structure of the transition state for the hydride transfer reactions; and (iii) factors affecting the energy gap for the hydride transfer step, namely, substrate binding to zinc, reaction field, and serine 48 effects on the potential energy profile. The coordination sphere of the catalytic zinc has been modeled with an ammonia molecule and two SH? groups; complexes with CH3O?, CH3OH, and CH2O have been studied; a (6, 2, 2, 2, 1/6, 2, 1/3, 2) basis set has been used for Zn++; a (5, 2, 1, 1/3, 2) was used for oxygen, carbon, and sulfur; and a (3, 1) was used for hydrogen atoms. The hydride step was studied with two model systems: pyridinium cation/1,4-dihydropyridine coupled to the CH3O?/CH2O reaction, and cyclopropenyl cation/cyclopropene coupled to the CH3O?/CH2O system. For the latter, the role of Ser48 has been studied at the supermolecule level. The calculation on the hydride transfer step has been done at a 4–31G basis set level. The results obtained shed new light on the sources of catalytic activity of liver alcohol dehydrogenases. 相似文献
39.
J. N. Cardenas K. F. O'Driscoll 《Journal of polymer science. Part A, Polymer chemistry》1977,15(8):1883-1888
Kinetic equations are presented which describe the course of a free-radical polymerization carried to high conversion when chain transfer to monomer or to other low molecular weight agents is important. Calculations are presented which show that the influence of chain transfer to monomer can greatly affect the rate of polymerization and the molecular weight averages when a polymerization is subject to autoacceleration because of the gel effect. 相似文献
40.