Edge plasmon polaritons on a half-plane

The effect of electromagnetic retardation on the spectrum of edge plasmons in a semi-infinite two-dimensional electron system is considered. The problem is reduced to complicated integral equations for the potentials, which are solved upon a major simplification of the kernel. The spatial distribution of the potentials, charges, and currents is analyzed. It is shown that edge plasmon polaritons in the high-conductivity two-dimensional system are characterized by a high Q factor at all frequencies, including those lower than the reciprocal electron relaxation time τ^-1.     

Geometric,Spectroscopic, and Magnetic Characteristics of [Tris(1,10-phenanthroline)manganese](2+) 1,2;1′,2′-<Emphasis Type="Italic">trans</Emphasis>-Bis[nonahydro-<Emphasis Type="Italic">closo</Emphasis>-decaborate](2−) Bis(dimethylformamide)

[Tris(1,10-phenanthroline)manganese](2+) 1,2;1′,2′-trans-bis[nonahydro-closo-decaborate](2?) bis(dimethylformamide) containing the complex anion [MnPhen₃]²⁺ with the paramagnetic central Mn atom and the [B₂₀H₁₈]^2? anion formed by fusion of two closo clusters B₁₀H₉ was synthesized and characterized by single crystal X-ray diffraction and by IR, X-ray photoelectron, and Raman spectroscopy.     

Reaction of divinyl selenide with secondary phosphine chalcogenides

Under the conditions of free-radical initiation (AIBN, UV irradiation), divinyl selenide regioselectively reacts with secondary phosphine sulfides and phosphine selenides to afford, depending on the ratio of the reagents, mono- or diadducts mainly of the anti-Markownikoff structure. The conditions which allow obtaining the diadducts in up to 97% yield are found. By the example of 2-{[2-(diphenethylphosphoroselenoyl) ethyl]selanyl}ethyl(diphenethyl)phosphine selenide the diadducts were shown to react with aqueous hydrogen peroxide at 53–56°C to give vinyl(diphenethyl)phosphine oxide in 76% yield.     

Excitonic effects in two-dimensional vibrational spectra of liquid formamide

The linear and two-dimensional infrared (2DIR) responses of the amide I vibrational mode in liquid formamide are investigated experimentally and theoretically using molecular dynamics simulations. The recent method based on the numerical integration of the Schr?dinger equation is employed to calculate the 2DIR spectra. Special attention is devoted to the interplay of the structural dynamics and the excitonic nature of the amide I modes in determining the optical response of the studied system. In particular, combining experimental data, simulated spectra and analysis of the simulated atomic trajectory in terms of a transition dipole coupling model, we provide a convincing explanation of the peculiar features of the 2DIR spectra, which show a substantial increase of the antidiagonal bandwidth with increasing frequency. We point out that, at variance with liquid water, the 2DIR spectral profile of formamide is determined more by the excitonic nature of the vibrational states than by the fast structural dynamics responsible for the frequency fluctuations.     

X-Ray and X-ray Photoelectron Spectroscopy Studies of the Electronic Structure of Borane Derivatives

This paper reviews the results of electronic structure studies of a number of typical members of borane series by X-ray and X-ray photoelectron spectroscopy using quantum chemical calculations. Fragment analysis of the molecular orbital structure is given. The nature of chemical interaction in boron cluster compounds is studied on models: simple molecules NH₃, BH₃, and BF₃ and their adducts NH₃BH₃ and NH₃BF₃. The electronic structure of B₁₀H₁₂L₂ type compounds with Lewis bases L = NH₃, (CH₃)₂S, (C₆H₅)₃P is analyzed. The complexes are considered in terms of the concept of donor–acceptor interactions between the fragments. The donor–acceptor bond has contributions from both occupied and vacant acceptor orbitals. X-ray photoelectron data on the charged states of atoms in the compounds are overviewed. Electron distribution in complex compounds with transition metals [(1,2-B₉C₂H₁₁)₂M]^–, M = Fe^III, Co^III, Ni^III, and Ni^IV and chain type polycobaltocarborane anions {[(3)-1,2-B₉C₂H₁₁]₂Co _n [(3,6)-1,2-B₈C₂H₁₀]_n-1} ^n– , n = 2-7, is considered.     

Resonance absorption of terahertz radiation in nanoperforated graphene

Recent measurements of the conductivity of nanoperforated graphene are interpreted in terms of edges states existing near the edge of each nanohole. The perimetric quantization of edge states should result in the formation of a quasi-equidistant ladder of quasistationary energy levels. Dirac fermions filling this ladder rotate about each nanohole in the direction determined by the valley index. It is shown that the irradiation of this system by circularly polarized terahertz radiation leads to a resonance in absorption in one of the valleys. The magnitude of absorption at the resonance frequency can be controlled by means of gate voltage.     

Kinetics of the formation of a phospholipid multilayer on a silica sol surface

The ordering of a multilayer consisting of DSPC bilayers on a silica sol substrate is studied within the modelindependent approach to the reconstruction of profiles of the electron density from X-ray reflectometry data. It is found that the electroporation of bilayers in the field of anion silica nanoparticles significantly accelerates the process of their saturation with Na⁺ and H₂O, which explains both a relatively small time of formation of the structure of the multilayer of 1–7×10⁵ s and ~13% excess of the electron density in it.     

Coupling of counterpropagating light waves in low-symmetry photorefractive crystals

Coupling of two counterpropagating coherent light waves in tin hypothiodiphosphate (Sn₂P₂S₆, SPS) is usually strongly inhibited because of severe space charge limitations. Analysis of two-beam coupling gain is performed for different orientations of the grating vector in this monoclinic crystal that takes into account the anisotropy of dielectric permittivity. Gain enhancements are predicted and demonstrated experimentally for several nontraditional orientations of counterpropagating waves.     

The Use of Galvanic Displacement for Synthesizing Pt/Carbide (Mo2C,ZrC, NbC) Catalysts Highly Active in the Hydrogen Evolution Reaction

Russian Journal of Electrochemistry - The composite materials involving platinum nanoparticles on the surface of carbides of Mo, Zr, and Nb are synthesized by the currentless redox reaction between...