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A. A. Pasynskii A. I. Blokhin Yu. V. Torubaev Zh. V. Dobrokhotova 《Russian Journal of Coordination Chemistry》2011,37(12):879-886
Reactions of CpMn(CO)(NO)SnCl3 (I) with sodium benzenethiolate and sodium benzenesele-nolate gave orange crystals of the complexes CpMn(CO)(NO)Sn(EPh)3, where E = S (II) or Se (III). Treatment of complex II with photochemically generated W(CO)5(THF) yielded the adduct CpMn(CO)(NO)Sn(SPh)3 · W(CO)5 (IV). A similar treatment of complex III resulted in the formation of the ditungsten complex W2(CO)4(SePh)6 (V) with transfer of all chalcogenate groups from tin to tungsten. In reactions of complexes II and III with a Pt0 complex with phosphine and acetylene, (PPh3)2Pt(Ph2C2), the chalcogenate groups are transferred from tin. Only the known Pt(II) complexes (PPh3)2Pt(EPh)2), where E= S (VI) or Se (VII). Molecular structures IV and V were characterized by X-ray diffraction. It has been found that the Mn-Sn bond in complex IV (2.5479(9) Å) is nearly the same length as that found earlier for complex II (2.5328(17) Å) and is substantially shorter than the sum of the covalent radii of Mn and Sn (2.78 Å). The Sn-S bond is noticeably lengthened (2.5217(11) Å) only for the S atom bound to tungsten (W-S, 2.5696(12) Å), while the other Sn-S bonds (2.4413(12) and 2.4291(12) Å) are virtually the same as in complex II (on average, 2.441 Å). Complex V contains the direct W-W bond (2.8153(16) Å) supplemented with four benzeneselenolate bridges in which the W-Se bonds (on average, 2.642(2) Å) are longer than the two terminal W-SePh bonds (2.571(2) Å). All the W-Se bonds are much shorter than the sum of the covalent radii of W and Se (2.82 Å). 相似文献
146.
S. S. Shapovalov A. V. Gordienko A. A. Pasynskii Yu. V. Torubaev I. V. Skabitskii G. G. Aleksandrov 《Russian Journal of Coordination Chemistry》2011,37(6):447-451
A reaction of [(η5-C6H7)Fe(CO)3]BF4 with KI in acetone gave brown crystals of the complex [(η5-C6H7)Fe(CO)2]I (I), which was treated with SnCl2 in THF to form orange crystals of the complex [(η5-C6H7)Fe(CO)2]SnCl3 (II). A reaction of complex II with potassium cymantrenecarboxylate ((CO)3MnC5H4COOK, or CymCOOK) in THF yielded yellow crystals of the complex [(η5-C6H7)Fe(CO)2]Sn(CymCOO)3 (III). Structures I–III were identified using X-ray diffraction. The fragment (η5-C6H7)Fe(CO)2 in complexes I–III remains virtually unchanged. The Fe-I bonds in complex I (2.6407(3) Å) and the Fe-Sn bonds in complexes II and III (2.4854(3) and 2.4787(4) Å, respectively) are appreciably shorter than the sum of the covalent radii of the corresponding elements, probably because of an additional dative interaction of the d electrons of iron with the vacant d orbitals of iodine or tin. 相似文献
147.
S. S. Shapovalov A. A. Pasynskii I. V. Skabitskii A. S. Sidorenkov T. A. Krishtop V. V. Minin 《Russian Journal of Coordination Chemistry》2013,39(12):822-828
Heating of the compounds (RC5H4)Fe(CO)2TePh (R = H (I) and Me (II)) in heptane afforded the dinuclear complexes [(RC5H4)Fe(CO)TePh]2 (III and IV, respectively). By oxidation with Fc+PF 6 ? , these complexes were transformed into the paramagnetic cationic complexes [(RC5H4)Fe(CO)TePh]2PF6 (V and VI, respectively). Structures III–V and [(C5H5)Fe(CO)SPh]2PF6 (VII) were characterized by X-ray diffraction. 相似文献
148.
has been studied by using a complete active space MCSCF wave function generated by distributing eight electrons among eight orbitals. 相似文献