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121.
Maiorova N. A. Grinberg V. A. Pasynskii A. A. Modestov A. D. Shiryaev A. A. Vysotskii V. V. 《Russian Journal of Coordination Chemistry》2018,44(12):738-744
Russian Journal of Coordination Chemistry - Activities of the synthesized trimetallic catalysts PtRuPd/C and PtRuIr/C supported on highly dispersed carbon soot from solutions of coordination... 相似文献
122.
A. A. Mikhailova A. A. Pasynskii V. A. Grinberg Yu. A. Velikodnyi O. A. Khazova 《Russian Journal of Electrochemistry》2010,46(1):26-33
Electrooxidation of dissolved CO and methanol at platinum-tin electrodes with different phase composition (a two-phase Sn/Pt-catalyst,
Pt-Sn alloy, and Pt3Sn intermetallic compound) is studied. All studied catalysts show higher catalytic activity in the CO oxidation at lower potentials
(0.3–0.5 V against reversible hydrogen electrode (RHE)), as compared with platinum; no catalysis is observed at higher potentials
(0.7 V); moreover, inhibiting is observed in some cases. The catalyst with the most strongly ordered structure (Pt3Sn) demonstrated the highest catalytic activity; however, it appeared being less stable against oxidation at potentials more
positive than 1.0 V. Catalytic effects were practically absent in the CO-adsorbate oxidation process. The sequence of catalyst
activities in the methanol oxidation process differed from that in the CO oxidation; in particular, Pt3Sn appeared being the
least active. The observed difference can be associated with the difference in the CO and methanol adsorption mechanisms.
The effect of the carbonaceous support dispersion on the current-voltage curves is discussed. 相似文献
123.
New complexes of transition metals with organotellurium halide ligands are reported. Iodination of [CpMn(CO)2]2(μ-Ph2Te2) leads to the Te-Te bond cleavage and formation of CpMn(CO)2(PhTeI). Oxidative addition of PhTeBr3 to Fe(CO)5 gives the monomeric complex (CO)3FeBr2(PhTeBr) which is isostructural with the recently reported (CO)3FeI2(PhTeI). Insertion of phenyltellurenyl iodide (PhTeI) into the Fe-I bond of CpFe(CO)2I forms CpFe(CO)2(TeI2Ph). Molecular structures of the reported complexes were determined by single-crystal X-ray diffraction analysis (XRD). A considerable shortening of metal-tellurium distances is observed. 相似文献
124.
V. A. Grinberg N. A. Maiorova A. A. Pasynskii V. V. Emets A. A. Shiryaev V. V. Vysotskii V. K. Gerasimov V. V. Matveev E. A. Nizhnikovskii V. N. Andreev 《Russian Journal of Coordination Chemistry》2017,43(4):206-212
Bi- and trimetallic platinum–ruthenium and platinum–ruthenium–palladium catalysts with specified atomic ratios Pt: Ru = 1: 1 and Pt: Ru: Pd = 1: 1: 0.1, respectively, were synthesized from the coordination compounds of the metals deposited on highly dispersed carbon black. The catalysts were characterized by powder X-ray diffraction, electron dispersive analysis, and transmission electron microscopy. According to voltammetry data, the highest activity in the dimethyl ether (DME) electrooxidation is exhibited by the catalyst Pt0.43Ru0.47Pd0.1/C; hence, it may be considered as a promising anode material for direct DME fuel cells. 相似文献
125.
126.
127.
Pasynskii A. A. Dobrokhotova Zh. V. Torubaev Yu. V. Semenova N. I. Novotortsev V. M. 《Russian Chemical Bulletin》2003,52(1):109-115
The thermal decay of 19 individual carbonyl homo- and heterochalcogenide clusters with different M/X ratios (M = Fe, Mn, Pt, Cr, W, Mo, Re, Ru; X = S, Se, Te) was studied by differential scanning calorimetry and thermogravimetry. The process is stepwise and occurs at relatively low temperatures (100—350 °C). The general fact of incomplete removal of carbon monoxide (due to the formation of carbide and oxide impurities) during thermolysis of narbonyl chalcogenide clusters with the M : X ratio greater than 1 was elucidated. Conversely, when M : X 1 (or at any M/X ratio for clusters containing methylcyclopentadienyl groups), pure metal chalcogenides are formed. 相似文献
128.
A.A. Pasynskii Yu.V. Skripkin I.L. Eremenko V.T. Kalinnikov G.G. Aleksandrov V.G. Andrianov Yu.T. Struchkov 《Journal of organometallic chemistry》1979,165(1):49-56
(C5H5)2NbBH4 reacts with C5H5M(CO)3Me in toluene solution in the presence of Et3N to give binuclear complexes (C5H5)2NbM(CO)3C5H5 where M is Mo or W (IV and V, respectively). The structure of IV has been studied by X-ray diffraction (the crystals are orthorhombic, a 12.748(5), b 16.745(6), c 14.314 ;; Z = 8, space group of Pbca, automatic difractometer Syntex P2I, λ(Mo-Kα, 1382 reflections, R = 0.056, Rw = 0.058). Molecule IV contains a wedge-like sandwich (π-C5H5)2Nb (NbC 2.37–2.48, CC (av) 1.42 ;, angle between ring planes 49°) linked with the (π-C5H5)Mo(CO) fragment by a direct NbMo bond (3.073 ;) and two bridging CO groups, one nonsymmetrically bonded through the carbon atom only (CO 1.17, NbC 2.53, MoC 2.02 ;) and the other σ-bonded to Mo (MoC 1.944 ;) and π-bonded to Nb (CO 1.22, NbC 2.22, NbO 2.26 ;). Three types of carbonyl groups present in IV give rise to strong IR bands at 1870, 1700 and 1560 cm?1 assigned to the terminal, μ-bridging and σ, π-bridging CO groups respectively. Complex IV has a similar structure. The electronic structure of IV and its dissociation across the NbMo bond are discussed. 相似文献
129.
V. M. Trukhan I. L. Eremenko N. S. Ovanesyan A. A. Pasynskii I. A. Petrunenko V. V. Strelets A. A. Shteinmana 《Russian Chemical Bulletin》1996,45(8):1981-1987
Reactions of iron(m) salts with a new bidentate ligand, which is potentially capable of forming binuclear iron complexes upon complexation, were studied. Under various conditions, we succeeded in isolating only the trinuclear cationic complex (FeIII
3(O2CR)6(3-)17+ (1), where RCO2 is 2-(pyrid-2-ylmethoxy)benzoic acid protonated at the pyridyl moiety. The structure of 1 was established by spectral, magnetic, and X-ray structural studies. Cyclic voltammetry in McCN in the temperature range from -35 to 20 °C demonstrated that 1 undergoes successive FeIIIFeII reduction in three one-electron stages, which is indicative of the electronic interaction between iron atoms in the complex.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 2086–2092, August, 1996. 相似文献
130.