Inverse Problem for a Mathematical Model of Adsorption Dynamics

A mixed problem is considered for a system of partial differential equations modeling the process of adsorption dynamics. An existence and uniqueness theorem is proved for this problem, and the solution properties are investigated. The inverse problem is posed, involving the determination of the system coefficient given additional information about the solution. A uniqueness theorem is proved for the solution of the inverse problem.__________Translated from Prikladnaya Matematika i Informatika, No. 16, pp. 5 – 14, 2004.     

Generalized lattice model of liquid state and its relation to Ginzburg–Landau theory

Basic principles of the generalized lattice model of multicomponent condensed systems are formulated. Short-range parts of interatomic interactions are taken into account by means of the geometric constraints method. Long-range parts of the interactions are taken into account in mean field approximation. The expression for Helmholtz free energy is obtained. A system of integral equations for the equilibrium distributions of components is derived. The asymptotic properties of its solutions are investigated. Moment expansion of interatomic interactions and localization of integral terms in free energy is obtained. A Ginzburg–Landau-like functional of free energy is derived.     

Effect of ethylene glycol on the formation of extended crystals of M1/3Co2/3C2O4 · 2H2O (M = Zn, Mn) oxalates and their thermolysis products

The effect of ethylene glycol (EG) on the formation of whiskers and fibers of complex oxides with the general formula MCo₂O₄ upon the thermolysis of M_1/3Co_2/3C₂O₄ (M = Zn, Mn) oxalates has been studied. New compounds (solvates) are formed when powdered oxalates are heated with EG. In the solvates, EG molecules substitute for water molecules according to the reaction M_1/3Co_2/3C₂O₄ · 2H₂O + HOCH₂CH₂OH = M_1/3Co_2/3C₂O₄(HOCH₂CH₂OH) + 2H₂O. The solvates have been characterized using X-ray powder diffraction, microscopy, IR spectroscopy, thermogravimetry, and chemical analysis. The shape, structure, and particle size of the thermolysis products of EG-modified oxalates have been determined using scanning electron microscopy.     

A topological analysis of electron density and chemical bonding in cyclophosphazenes PnNnX2n (X = H, F, Cl; n = 2, 3, 4)

The restricted Hartree-Fock method was used to determine the cycle size effects on the geometric parameters of several inorganic templates, cyclophosphazenes P_nN_nX_2n (X = H, F, Cl; n = 2, 3, 4). A topological analysis of local electronic properties at the electron density critical points of bonds allowed us to quantitatively characterize the chemical bond in cyclophosphazenes and its dependence on the cycle size and substituents at phosphorus. The calculated distributions of the electron density Laplacian and electron pair localization functions revealed the special features of the electronic structure of the nitrogen and phosphorus atoms. These results explain the nature of noncovalent interactions between the P atoms of one cyclophosphazene molecule and the N atoms of the other.     

Representations of Positive Projections II

In this paper we obtain a number of Maharam-type slice integral representations, with respect to scalar measures, for positive projections in Dedekind complete vector lattices and f-algebras. AMS Classification: 47B65, 46A40, 06F25     

Stress Distribution in an Infinite Elastic Body with a Locally Curved Fiber in a Geometrically Nonlinear Statement

Within the framework of a piecewise homogeneous body model, with the use of three-dimensional geometrically nonlinear exact equations of elasticity theory, a method for determining the stress—strain state in unidirectional fibrous composites with locally curved fibers is developed for the case where the interaction between the fibers is neglected. All the investigations are carried out for an infinite elastic body containing a single locally curved fiber. Numerical results illustrating the effect of geometrical nonlinearity on the distribution of the self-balanced normal and shear stresses acting on the interface and arising as a result of local curving of the fiber are presented.__________Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 41, No. 4, pp. 433–448, July–August, 2005.