Anionic iron(II) alkoxides as initiators for the controlled ring‐opening polymerization of lactide

Hetero‐bimetallic Fe(II) alkoxide/aryloxides were evaluated as initiators for the ring‐opening polymerization of rac‐lactide. [(THF)NaFe(O^tBu)₃]₂ ( 1 ) and [(THF)₄Na₂Fe(2,6‐diisopropylphenolate)₄] ( 2 ) (THF = tetrahydrofuran) both polymerized lactide efficiently at room temperature, with complex 1 affording better control over the molecular weight parameters of the resultant polymer. At conversions below 70%, a linear increase in molecular weight with conversion was observed, indicative of a well‐controlled polymerization process. Complex 2 is the first example of a dianionic Fe(II) alkoxide and has been structurally characterized to reveal a distorted square planar FeO₄ array in which both Na counterions bridge two aryloxide ligands and are further complexed by two THF ligands. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3798–3803, 2003     

Nonvanishing derivatives and normal families

We consider the differential operators Ψ _k , defined by Ψ₁(y) =y and Ψ _k+1(y)=yΨ _k y+d/dz(Ψ _k (y)) fork ∈ ℕ fork∈ ℕ. We show that ifF is meromorphic in ℂ and Ψ _k F has no zeros for somek≥3, and if the residues at the simple poles ofF are not positive integers, thenF has the formF(z)=((k-1)z+a)/(z ²+β z+γ) orF(z)=1/(az+β) where α, β, γ ∈ ℂ. If the residues at the simple poles ofF are bounded away from zero, then this also holds fork=2. We further show that, under suitable additional conditions, a family of meromorphic functionsF is normal if each Ψ _k (F) has no zeros. These conditions are satisfied, in particular, if there exists δ>0 such that Re (Res(F, a)) <−δ for all polea of eachF in the family. Using the fact that Ψ _k (f ^′/f) =f ^(k)/f, we deduce in particular that iff andf ^(k) have no zeros for allf in some familyF of meromorphic functions, wherek≥2, then {f ^′/f :f ∈F} is normal. The first author is supported by the German-Israeli Foundation for Scientific Research and Development G.I.F., G-643-117.6/1999, and INTAS-99-00089. The second author thanks the DAAD for supporting a visit to Kiel in June–July 2002. Both authors thank Günter Frank for helpful discussions.     

Model spectral function and superconductivity in BaxK1−xBiO3 (x=0.5-0.7)

The Eliashberg spectral density function is constructed for the superconducting compound Ba_xK_1−xBiO₃ with x=0.5, 0.6, 0.7. The functions, besides yielding some prominent structures, show widely spreading spectra that inhibit lattice instability by yielding not too large values of λ(<1.32). The resulting spectral functions show similar shape as other results, where available, and also successfully reproduce the observed critical temperature, isotope exponent, gap ratio and several other parameters.     

Electro-optic size effects and effects of nonlinear saturation in PLZT ceramics

Results of studying electro-optic size effects and nonlinear electro-optic effects in ferroelectric PLZT ceramics are presented. It is established that the presence of electro-optic size effects makes microvolume samples of PLZT ceramics promising for designing efficient modulating devices.     

Fundamentals of the direct measurement of sound intensity and practical applications

Sound intensity is a measure of the magnitude and direction of the flow of sound energy. Developments in sound intensity measurement capabilities in the last quarter century have occurred because of several reasons. The main ones include the derivation of the cross-spectral formulation for sound intensity and developments in digital signal processing. This paper begins with a brief historical introduction of sound intensity measurements. Then elementary theory for sound intensity is presented. A section on sound intensity measurements is then included. The next section of the paper discusses sources of measurement error; the major sources of error are described in some detail. The paper continues with a discussion of the main applications of sound intensity measurements: sound power determination, noise source identification, and transmission loss measurements. The paper concludes with a discussion of ISO and ANSI intensity related standards and relevant references.     

Elastic scattering of slow positrons on atoms

The results of calculations of the elastic scattering cross section of positrons on noble gas and alkali atoms are presented. The calculations are performed within the one-electron Hartree-Fock approximation with multielectron correlations in the so-called random phase approximation with exchange taken into account. Virtual positronium formation is taken into account and proved to be very important. Arguments are presented that the positron polarization potential is repulsive for alkali atoms. The results obtained are in a reasonable agreement with experiment and with some previously reported calculations.     

effect of surface modification on the properties of hydrogen-sensitive GaAs-based Schottky diodes

The surface of hydrogen-sensitive GaAs Schottky diodes is modified by nonpolishing etching and by producing quantum wells and quantum dots in the space-charge region of the semiconductor. The sensitivity to hydrogen is found to increase by a factor of 8–37 after the etching and by two or three orders of magnitude after the introduction of quantum wells and dots. It is shown that the increased sensitivity is associated with the lowering of the barrier at the Pd/GaAs interface, the retardation of hydrogen diffusion into GaAs due to the presence of strained quantum-size layers, and an increase in the recombination current. The presence of the recombination component is supported by luminescence from the quantum wells and quantum dots, as well as from the GaAs substrate. The etch composition is shown to be a decisive factor in raising the sensitivity.     

Pion mass splitting and phase structure in twisted mass QCD

In the framework of Wilson chiral perturbation theory [1], we study the effect induced by a twisted Wilson term, as it appears in twisted mass QCD [2] (with two degenerate quarks). In particular we consider the vacuum orientation and the pion masses. The computations are done to NLO both in the mass and in the lattice spacing (i.e. to O(a ²)). There are no restrictions on the relative size of lattice artifacts with respect to the physical mass, thus allowing, in principle, to bridge between the physical regime and the unphysical one, where lattice artifacts tend to dominate. The inclusion of O(a ²) lattice artifacts can account for the splitting of degeneracy of the three pion masses. Moreover O(a ²) terms are necessary to model non-trivial behaviors of the vacuum orientation such as possible Aoki phases. It turns out that these last two phenomena are determined by the same constant.Received: 21 July 2004, Published online: 1 October 2004