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891.
An analysis of events in the tunneling junction shows that the interaction of one-electron processes in a many-electron system may be a source of scale-invariant low-frequency fluctuations of conductivity (the interaction consists in that the quantum probability of an electron transition depends on fast random changes in the environment in the course of the transition, including the changes caused by analogous transitions). The theory relates flicker fluctuations in the tunneling conductivity to the discrete character of the spectrum of electron states and explains the nonlinearity of the noise-current characteristic observed in nanocomposites. 相似文献
892.
893.
Chemical bonding in isolated molecules and crystals of zwitterionic pentacoordinate silicon chelates
The electronic structures of a number of zwitterionic pentacoordinate silicon chelates were investigated using the results of X-ray diffraction studies and quantum-chemical calculatoins by the MPW1PW91/6-311G(d) method. The topological analysis of the electron density distribution function and the study in the framework of the natural bond orbital partitioning scheme showed that the character of chemical bonding in the axial fragments of the molecules under consideration changes from dative to three-center, four-electron as the silicon atom assumes a trigonal-bipyramidal coordination. 相似文献
894.
The electrodynamic properties of granular high-temperature superconducting media are studied. Relations for the surface resistance and impedance of a high-temperature superconducting medium are derived. The temperature and frequency dependence of the phase velocity and group velocity and depth of penetration of the electromagnetic field into the Josephson medium are calculated. The possibility of using high-temperature superconducting films as high-efficiency shields is shown. The shielding properties are improved appreciably with increase in the critical current density of the high-temperature superconducting film. The shield thickness is several microns or several fractions of a micron for a critical current density of >107 A/m2. The results obtained can be used in designing superhigh-frequency shields, microstrip lines, and other devices based on high-temperature superconducting Josephson media. 相似文献
895.
Timinskas A. Cheshunene A. Kurtinaitene M. Skominas V. 《Russian Journal of Applied Chemistry》2002,75(6):911-914
Conditions under which anodized aluminum is treated first in a dilute solution of phosphoric acid and then in a fluoroborate immersion solution in order to deposit a multilayer system of cobalt and copper in the pores in the oxide were studied. 相似文献
896.
A.R. DegheidyM.T. Attia M. Sallah 《Journal of Quantitative Spectroscopy & Radiative Transfer》2002,74(3):285-297
The time-independent radiative transfer problem in a scattering and absorbing planar random medium with general boundary conditions and internal energy source is considered. The medium is assumed to consist of two randomly mixed immiscible fluids, with the mixing statistics described as a two-state homogeneous Markov process. The problem is solved in terms of the solution of the corresponding free-source problem with simple boundary conditions which is solved using Pomraning-Eddington approximation in the deterministic case. A formalism, developed to treat radiative transfer in statistical mixtures, is used to obtain the ensemble-averaged solution. The average partial heat fluxes are calculated in terms of the albedoes of the source-free problem. Results are obtained for isotropic and anisotropic scattering for specular and diffused reflecting boundaries. 相似文献
897.
We prove that the diffusion semigroups generated by the second order differential ultraspherical (Gegenbauer) operator are pseudomeasure operators. 相似文献
898.
A method for stabilizing frequency based on using the soliton state of the Bose-Einstein condensate of alkali metal atoms as an atomic source was suggested. The critical total number of lithium condensate particles at which the existence of a quasi-one-dimensional soliton in the condensate was possible and the lifetime of such a soliton were estimated. The attainable accuracy of measuring reference transition frequencies in the suggested standard was shown to be substantially higher than with the known quantum frequency standards. 相似文献
899.
F. F. Maia Jr. J. A. K. Freire G. A. Farias V. N. Freire E. F. da Silva Jr. 《Applied Surface Science》2002,190(1-4):247-251
The excitonic properties of a ZnSe/ZnSxSe1−x strained quantum well (QW) are calculated taking into account interface effects. Numerical results obtained with ZnS0.18Se0.82/ZnSe QWs show that graded interfaces can be responsible for a strong broadening of excitonic spectra. 相似文献
900.