全文获取类型
收费全文 | 536764篇 |
免费 | 4754篇 |
国内免费 | 1290篇 |
专业分类
化学 | 271155篇 |
晶体学 | 7711篇 |
力学 | 26772篇 |
综合类 | 17篇 |
数学 | 69940篇 |
物理学 | 167213篇 |
出版年
2021年 | 5027篇 |
2020年 | 5477篇 |
2019年 | 6221篇 |
2018年 | 8888篇 |
2017年 | 9119篇 |
2016年 | 11882篇 |
2015年 | 6339篇 |
2014年 | 10569篇 |
2013年 | 23660篇 |
2012年 | 18915篇 |
2011年 | 22112篇 |
2010年 | 16584篇 |
2009年 | 16482篇 |
2008年 | 20691篇 |
2007年 | 20542篇 |
2006年 | 18645篇 |
2005年 | 18752篇 |
2004年 | 17695篇 |
2003年 | 15151篇 |
2002年 | 13896篇 |
2001年 | 14734篇 |
2000年 | 11346篇 |
1999年 | 8762篇 |
1998年 | 7605篇 |
1997年 | 7470篇 |
1996年 | 6928篇 |
1995年 | 6257篇 |
1994年 | 6264篇 |
1993年 | 6017篇 |
1992年 | 6375篇 |
1991年 | 6865篇 |
1990年 | 6577篇 |
1989年 | 6486篇 |
1988年 | 6321篇 |
1987年 | 6132篇 |
1986年 | 5871篇 |
1985年 | 7408篇 |
1984年 | 7769篇 |
1983年 | 6532篇 |
1982年 | 6817篇 |
1981年 | 6326篇 |
1980年 | 6004篇 |
1979年 | 6505篇 |
1978年 | 6741篇 |
1977年 | 6629篇 |
1976年 | 6587篇 |
1975年 | 6302篇 |
1974年 | 6130篇 |
1973年 | 6424篇 |
1972年 | 4706篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
121.
122.
123.
Close‐Packed Two‐Dimensional Silver Nanoparticle Arrays: Quadrupolar and Dipolar Surface Plasmon Resonance Coupling 下载免费PDF全文
Sukang Yun Soonchang Hong Jesus A. I. Acapulco Jr. Ho Young Jang Songyi Ham Kyungeun Lee Prof. Seong Kyu Kim Prof. Sungho Park 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(16):6165-6172
Silver nanoparticles (NPs) ranging in size from 40 to 100 nm were prepared in high yield by using an improved seed‐mediated method. The homogeneous Ag NPs were used as building blocks for 2D assembled Ag NP arrays by using an oil/water interface. A close‐packed 2D array of Ag NPs was fabricated by using packing molecules (3‐mercaptopropyltrimethoxysilane) to control the interparticle spacing. The homogeneous 2D Ag NP array exhibited a strong quadrupolar cooperative plasmon mode resonance and a dipolar red‐shift relative to individual Ag NPs suspended in solution. A well‐arranged 2D Ag NP array was embedded in polydimethylsiloxane film and, with biaxial stretching to control the interparticle distance, concomitant variations of the quadrupolar and dipolar couplings were observed. As the interparticle distance increased, the intensity of the quadrupolar cooperative plasmon mode resonance decreased and dipolar coupling completely disappeared. The local electric field of the 2D Ag NP array was calculated by using finite difference time domain simulation and qualitatively showed agreement with the experimental measurements. 相似文献
124.
125.
A. Lashgari S. Ghammamy R. Ramirez-Tagle G. Salgado-Moran 《Journal of Structural Chemistry》2015,56(8):1505-1513
Two new compounds of fluorine: (C2H5)4N[I2F] and (C2H5)4N[Br2F], have been easily synthesized in a nearly quantitative by a direct reaction of (C2H5)4NF, I2 and Br2. The products were isolated and characterized by elemental analysis and spectroscopic methods such as: Fourier transform infrared spectroscopy (FTIR) and ultraviolet-visible spectroscopy (UV-Vis). These compounds have been studied computationally with the Scalar ZORA relativistic level of theory using the ADF program package. The molecular parameters, and vibrational spectra were calculated. The excitation energies were found by timedependent perturbation density functional theory (TD-DFT). Molecule optimization, frequencies and excitation energies were calculated with standard Slatertype-orbital (STO) basis sets with triple-zeta quality double plus polarization functions (TZ2P) for all atoms. The FTIR, UV-Vis spectra and assignment of principal transitions and total density of state (TDOS) were extracted using the GaussSum 2.2 program. The comparison between experimental and calculated values showes that the experimental results correlate well with the predicted data. 相似文献
126.
Development of biocompatible porous supports is a promising strategy in the field of tissue engineering for the repair and regeneration of bone tissues with severe damage. Graphene oxide aerogels (GOAs) are excellent candidates for the manufacture of these systems due to their porosity, ability to imitate bone structure, and mechanical resistance, and according to their surface chemical reactivity, they can facilitate osseointegration, osteogenesis, osteoinduction and osteoconduction. In this review, synthesis of GOAs from the most primary source is described, and recent studies on the use of these functionalized carbonaceous foams as scaffolding for bone tissue regeneration are presented. 相似文献
127.
Khusnutdinov R. I. Shchadneva N. A. Mayakova Yu. Yu. Aminov R. I. 《Russian Journal of Organic Chemistry》2021,57(6):950-953
Russian Journal of Organic Chemistry - Binder-free iron- and nickel-containing micro-, meso-, and macroporous zeolites FeHY and NiHY were found to effectively catalyze Knoevenagel condensation of... 相似文献
128.
Elasasy M. E. A. Elnaggar D. H. Hafez N. A. Abdel Azab M. E. Amr A. E. Omran M. M. Mohamed A. M. 《Russian Journal of General Chemistry》2021,91(5):915-925
Russian Journal of General Chemistry - Some new fluoro-heterocyclic compounds containing thiazole and pyridine moities have been synthesized and studied for their antiproliferative activity.... 相似文献
129.
In this research article, we describe the synthesis and characterization of mononuclear and dinuclear Cu complexes bound by a family of tridentate redox-active ligands with tunable H-bonding donors. The mononuclear Cu-anion complexes were oxidized to the corresponding “high-valent” intermediates by oxidation of the redox-active ligand. These species were capable of oxidizing phenols with weak O−H bonds via H-atom abstraction. Thermodynamic analysis of the H-atom abstractions, which included reduction potential measurements, pKa determination and kinetic studies, revealed that modification of the anion coordinated to the Cu and changes in the H-bonding donor did not lead to major differences in the reactivity of the “high-valent” CuY complexes (Y: hydroxide, phenolate and acetate), which indicated that the tridentate ligand scaffold acts as the H+ and e− acceptor. 相似文献
130.
Colloid Journal - An Erratum to this paper has been published: https://doi.org/10.1134/S1061933X21330024 相似文献