全文获取类型
收费全文 | 871196篇 |
免费 | 30979篇 |
国内免费 | 19174篇 |
专业分类
化学 | 438902篇 |
晶体学 | 12503篇 |
力学 | 48105篇 |
综合类 | 42篇 |
数学 | 128503篇 |
物理学 | 293294篇 |
出版年
2021年 | 7887篇 |
2020年 | 8689篇 |
2019年 | 10286篇 |
2018年 | 13397篇 |
2017年 | 14357篇 |
2016年 | 19357篇 |
2015年 | 11954篇 |
2014年 | 18325篇 |
2013年 | 41081篇 |
2012年 | 32411篇 |
2011年 | 38771篇 |
2010年 | 30695篇 |
2009年 | 31011篇 |
2008年 | 35042篇 |
2007年 | 34125篇 |
2006年 | 31490篇 |
2005年 | 28487篇 |
2004年 | 27544篇 |
2003年 | 24432篇 |
2002年 | 24188篇 |
2001年 | 25835篇 |
2000年 | 19999篇 |
1999年 | 16123篇 |
1998年 | 13950篇 |
1997年 | 13432篇 |
1996年 | 13053篇 |
1995年 | 11937篇 |
1994年 | 12118篇 |
1993年 | 11915篇 |
1992年 | 12015篇 |
1991年 | 12276篇 |
1990年 | 11622篇 |
1989年 | 11470篇 |
1988年 | 11014篇 |
1987年 | 10465篇 |
1986年 | 9953篇 |
1985年 | 12286篇 |
1984年 | 12863篇 |
1983年 | 10601篇 |
1982年 | 11176篇 |
1981年 | 10503篇 |
1980年 | 10083篇 |
1979年 | 10719篇 |
1978年 | 10960篇 |
1977年 | 10879篇 |
1976年 | 11042篇 |
1975年 | 10197篇 |
1974年 | 10025篇 |
1973年 | 10309篇 |
1972年 | 7775篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
921.
S. Meenakshi B.K. Godwal I. Orgzall S. Tkachev 《Journal of Physics and Chemistry of Solids》2006,67(8):1660-1667
We report the results of an X-ray diffraction study of CdAl2Se4 and of Raman studies of HgAl2Se4 and ZnAl2Se4 at room temperature, and of CdAl2S4 and CdAl2Se4 at 80 K at high pressure. The ambient pressure phase of CdAl2Se4 is stable up to a pressure of 9.1 GPa above which a phase transition to a disordered rock salt phase is observed. A fit of the volume pressure data to a Birch-Murnaghan type equation of state yields a bulk modulus of 52.1 GPa. The relative volume change at the phase transition at ∼9 GPa is about 10%. The analysis of the Raman data of HgAl2Se4 and ZnAl2Se4 reveals a general trend observed for different defect chalcopyrite materials. The line widths of the Raman peaks change at intermediate pressures between 4 and 6 GPa as an indication of the pressure induced two stage order-disorder transition observed in these materials. In addition, we include results of a low temperature Raman study of CdAl2S4 and CdAl2Se4, which shows a very weak temperature dependence of the Raman-active phonon modes. 相似文献
922.
A. V. Bobylev 《Journal of statistical physics》2006,124(2-4):371-399
It is well-known that the classical Chapman-Enskog procedure does not work at the level of Burnett equations (the next step after the Navier-Stokes equations). Roughly speaking, the reason is that the solutions of higher equations of hydrodynamics (Burnett's, etc.) become unstable with respect to short-wave perturbations. This problem was recently attacked by several authors who proposed different ways to deal with it. We present in this paper one of possible alternatives. First we deduce a criterion for hyperbolicity of Burnett equations for the general molecular model and show that this criterion is not fulfilled in most typical cases. Then we discuss in more detail the problem of truncation of the Chapman-Enskog expansion and show that the way of truncation is not unique. The general idea of changes of coordinates (based on analogy with the theory of dynamical systems) leads finally to nonlinear Hyperbolic Burnett Equations (HBEs) without using any information beyond the classical Burnett equations. It is proved that HBEs satisfy the linearized H-theorem. The linear version of the problem is studied in more detail, the complete Chapman-Enskog expansion is given for the linear case. A simplified proof of the Slemrod identity for Burnett coefficients is also given. 相似文献
923.
Analytical expressions are obtained that describe the changes in the degree of coherence and in the thickness of the coherence layers occurring upon propagation of a dispersed broadband laser beam. It is found that the greater the tilting of the coherence layers with respect to the phase fronts, the more rapidly the spatial coherence is violated with increasing distance. A comparison with the case of an undispersed beam is performed. It is shown that, as the beam propagates, the decrease in the degree of coherence is accompanied by the appearance of spatial fluctuations of this parameter. The degree of mutual coherence of intersecting dispersed beams with parallel correlated coherence layers, which determines the efficiency of their coherent interaction, is investigated. The existence of spatial fluctuations of the degree of mutual coherence is established. 相似文献
924.
V. V. Kuznetsov N. V. Morozova V. N. Kudryavtsev 《Russian Journal of Electrochemistry》2006,42(6):665-669
Dependences of the current and the chemical composition of cathodic deposits on the electrolysis time are studied in an ammonia-citrate electrolyte for the deposition of a nickel-molybdenum alloy in potentiostatic conditions. At potentials less negative than ?0.93 V, no nickel-molybdenum alloy deposition occurs and in the course of electrolysis there is observed a decrease in the current, which is connected with the blocking of the electrode surface by the formed molybdenum oxides. In the region of potentials of deposition of a nickel-molybdenum alloy there is realized the following shape of a time dependence of the current. Within the first few seconds of the electrolysis process, the current somewhat decreases. Then there occurs its increase, which is connected with the alloy deposition on the cathode. In the course of electrolysis there occurs a decrease in the molybdenum content in the cathodic deposit. 相似文献
925.
Lagrangian and Eulerian modelling approaches are compared for simulating turbulent dispersion and coalescence of droplets within a spray. Both models predict similar droplet dispersion rates and shifts in droplet size distribution due to coalescence within the spray, over a wide range of droplet and gas flows, and for sprays with different droplet-size distributions at the nozzle exit. The computer time required for simulating coalescence within a steady axisymmetric spray is of a similar order of magnitude regardless of which formulation, Eulerian or Lagrangian, is adopted. However, the Lagrangian formulation is more practical in terms of the range of applicability and ease of implementation. 相似文献
926.
A. V. Semykin I. A. Kazarinov E. A. Khomskaya 《Russian Journal of Electrochemistry》2006,42(6):643-648
The hydrogen ionization process is studied experimentally on an industrial sintered nickel oxide electrode in models of sealed nickel-metal hydride batteries. It is shown that the hydrogen ionization rates that are reached during overcharge by high current densities in conditions of forced gas delivery into the electrode pores (up to 40 mA cm?2) exceed the self-discharge rate of a nickel-hydrogen battery by two orders of magnitude. Up to 70% of hydrogen delivered into the compact assembly block undergoes ionization during forced charge of models of sealed nickel-metal hydride batteries with a closed hydrogen cycle. Two independent methods (potentiostatic and manometric) are used to determine the relationship between rates of hydrogen ionization with the degree of the electrode filling with gas and perform estimation of the process intensity at a unit reaction surface. It is established that, in conditions of forced gas delivery, practically all the hydrogen oxidation current is generated at the surface of the nickel oxide electrode beneath thin films of an electrolyte solution at the rate of 4–5 mA cm?2. It is shown that the hydrogen oxidation rate on a nickel oxide electrode filled in part by gas is independent of the electrode potential, probably because of a tangible contribution made by diffusion limitations to the overall hampering of the process. 相似文献
927.
A. D. Rogers 《Acta Mathematica Hungarica》2006,110(1-2):13-21
Summary A lower bound is established for the strip discrepancy of a broad class of point distributions. The bound implies unbounded
strip discrepancy for equally weighted point distributions under favorable conditions. The methods of proof use notions from
integral geometry. 相似文献
928.
设 $\varphi$ 是单位园盘 $D$ 到自身的解析映射, $X$ 是 $D$ 上解析函数的 Banach 空间, 对 $f\in X$, 定义复合算子$C_\varphi $ : $C_\varphi (f)=f\circ \varphi$. 我们利用从 ${\cal B}^0$到 $E(p,q)$ 和 $E_0(p,q)$ 空间的复合算子研究了空间 $E(p,q)$ 和 $E_0(p,q)$, 给出了一个新的特征. 相似文献
929.
We propose a framework, based on classical mixture theory, to describe the isothermal flow of an incompressible fluid through a deformable inelastic porous solid. The modeling of the behavior of the inelastic solid takes into account changes in the elastic response due to evolution in the microstructure of the material. We apply the model to a compression layer problem. The mathematical problem generated by the model is a free boundary problem. 相似文献
930.
V. Edon M.C. Hugon B. Agius L. Miotti C. Radtke F. Tatsch J.J. Ganem I. Trimaille I.J.R. Baumvol 《Applied Physics A: Materials Science & Processing》2006,83(2):289-293
The influence of processing parameters on the electrical characteristics of RuO2/LaAlO3/Si metal-oxide-semiconductor structures was investigated. In particular, the sputtering regime during deposition of LaAlO3 on Si and the atmosphere used in the post-deposition annealing step were addressed by determining capacitance-voltage and
gate current-voltage characteristics. These results were correlated with compositional information obtained by Rutherford
backscattering spectrometry and nuclear reaction analysis. A post-deposition annealing step in oxygen at 600 °C resulted in
better electrical characteristics of the final structure as compared to the same treatment performed in nitrogen. This result
is explained by oxygen ability to heal oxygen vacancies in the LaAlO3 film, especially at the dielectric/semiconductor interface region. A thermalized sputtering regime during deposition of LaAlO3 on Si leads to capacitors with electrical characteristics superior to those deposited in ballistic regime.
PACS 77.84.Dy; 81.15.Cd; 81.40.Gh; 73.40.Qv; 82.80.Yc 相似文献