Sorption and Catalytic Activity of Adsorbent-Catalyst Based on Montmorillonite Modified with Cr(III) and Cu(II) Mixed Oxides

The sorption properties of mixed adsorbent-catalyst based on high-silica zeolite and montmorillonite modified with mixed oxides of Cr(III) and Cu(II) with respect to organic compounds of various classes were studied, and the optimal dynamic conditions of its operation were determined.     

Plasticity field adjacent to faces of asperities on a rotating roll after initial indentation into a half-space

The plastic deformation field near the horizontal surface of a half space of perfectly plastic material associated with an indenting rotating rigid tooth is studied using slip line theory. The tooth is one of many on a roll surface and indents first into the half-space material and then rotates about the roll center. A slip line field is proposed for the deforming plastic region and a solution scheme is outlined. The emphasis is on determining the shape of the deforming region, especially that of the free surface. The study has a potential application in roughness transfer in metal forming processing.     

About Rotational Transitions and Muon Transfer in Muonic Hydrogen–Helium Systems

Hyperfine Interactions - Rotational J=1→J=0 transitions in muonic molecule, (3Heμd) J ++, in [(3Heμd)++,2e]–D and [(3Heμd)++,e]+–D collisions are considered. The...     

Synthesis and crystal structure of bis(di-n-butyldithiocarbamato)(1,10-phenanthroline)cadmium(II)

A new mixed-ligand complex, Cd(S₂CN(C₄H₉)₂)₂Phen, is synthesized and investigated by thermal, element, and IR analyses and by diffractometry of polycrystals (DRON-3M, CuK_α radiation, Ni filter). The crystal structure was determined on a CAD-4 Enraf-Nonius automatic diffractometer (MoK_α radiation, θ from 1.5 to 25?, 2325 nonzero independent reflections, 190 refined parameters, R = 0.036 for I > 2Σ(I)). Crystal data for C₃₀H₄₄CdN₄S₄ : a = 15.592(3), b = 22.724(5), c = 9.922(2) å, space group Pbcn, V = 3515.5(12) å₃, Z = 4, M = 701.33, d_calc = 1.325 g/cm³. The structure involves monomeric molecules in which the cadmium atom has a distorted octahedral environment.     

CIDEP spin probing of the nanopores in cotton

Time-resolved electron paramagnetic resonance (TREPR) experiments are reported on an α-hydroxy acetophenone in waterg-glycerol and ethanol-ethanediol mixtures over a viscosity range of 1–32 cP. The magnitude and viscosity dependence of the radical pair mechanism polarization is in good agreement with theory. The triplet mechanism polarization is found to increase with decreasing solvent polarity and this is ascribed to an increase in the α-cleavage rate constant. The liquid spectra are used to interpret TREPR spectra of the acetophenone in dry and wet cotton. In dry cotton anti-phase structure is seen and is due to some of the radical pairs being trapped in cages. The triplet and radical pair mechanism polarization shows that the acetophenone adsorbs to the apolar crystallite surface and releases radicals into the polar amorphous regions where they experience a microviscosity of approximately 30 cP. In wet cotton there are no cages and the viscosity is greater than in ethanol alone.     

Magnetic properties of mechanically alloyed Co–Ti powder

An amorphous phase containing traces of non-transformed Co and Ti powders was obtained by mechanical alloying nominal compositions of Co₆₇Ti₃₃ and Co₅₀Ti₅₀ in a high-energy ball-mill. These alloys were prepared from elemental powders of Co and Ti. The heat treatment of Co₆₇Ti₃₃ at 573, 873 and 1173 K crystallized nanoparticles of Co₂Ti and Co₃Ti compounds, while the same treatments conducted on Co₅₀Ti₅₀ resulted in the formation of Co₂Ti and CoTi nanoparticles. The saturation magnetizations reached a maximum value in the amorphous state and they decreased when the temperatures of the heat treatment rose. Demagnetizing interparticle interaction effects were estimated through hysteresis loops and initial magnetization curves using the Fourier technique.     

Magnetic resonance in beta-active nuclei 8Li at the doubled larmor frequency in LiF polycrystals containing dislocations

The nuclear magnetic resonance in beta-active nuclei ⁸Li at the doubled Larmor frequency in LiF polycrystals is studied before and after treating these polycrystals with an external pressure. A quantitative approach is proposed that makes it possible to calculate the parameters of the resonance line-shape function versus the dislocation structure of crystallites. Data suggesting that the samples under investigation that were subjected to a treatment with an external pressure develop dislocations whose Burgers vectors are parallel are obtained.     

Metrics of Homogeneous Spaces Admitting (3.1)-Type Complete Sets

A classification has been obtained for spaces which admit complete sets of motion integrals of the (3.1)-type and are spatially homogeneous. The metrics and Killing vectors have been found in explicit form for all types of these spaces. A classification by Bianchi is given for the spaces obtained.     

On the polarization interaction between two closely spaced conducting spheres in a uniform electrostatic field

An electrostatic interaction between two separate, grounded, uncharged, perfectly conducting spheres of different radii in a uniform electrostatic field is investigated. It is shown that at a small center-to-center distance of the spheres, the force of the polarization interaction between the spheres depends appreciably more weakly on that distance in comparison to the force of the electrostatic interaction of two elementary dipoles as it should be in view of the interaction between two like polarization charges.     

Propagation of mesons in asymmetric nuclear matter in a density-dependent coupling model

We study the propagation of the light mesons σ,ω,ρ, and a₀(980) in dense hadronic matter in an extended derivative scalar coupling model. Within the scheme proposed it is possible to unambiguously define effective density-dependent couplings at the Lagrangian level. We first apply the model to study asymmetric nuclear matter with fixed isospin asymmetry, and then we pay particular attention to hypermatter in β-equilibrium. The equation of state and the potential contribution to the symmetry coefficient arising from the mean-field approximation are investigated. Received: 16 October 2001 / Accepted: 10 January 2002